Water-soluble biomass heavy metal scavenger and preparation method thereof

A heavy metal scavenger and biomass technology, applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of poor stability, low settling velocity, and weak capture ability of heavy metal scavenger, and achieve good stability, high settling velocity, The effect of improving practical performance

Active Publication Date: 2017-11-10
重庆高新技术产业研究院有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

So far, the prepared heavy metal scavenger still has the disadvantages of weak capture ability, low sedimentation velocity, poor stability, etc., and cannot be popularized and applied in practice.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Soy protein is extracted from soybeans. The average particle size of soybean protein is 1 µm. Add 1 part of soybean protein to 10 parts of water, adjust the pH value with hydrochloric acid to make it acidic, and the pH value is 2.0. After adjusting the pH value Control the temperature at 30°C, dissolve for 2 hours, then add 1 part of glyoxal, carry out cross-linking reaction under mechanical stirring for 3 hours, then add 1 part of sodium hydroxide and 10 parts of carbon disulfide, and react for 2 hours to obtain the desired Water-soluble biomass heavy metal scavenger.

Embodiment 2

[0022] Soy protein is extracted from soybeans. The average particle size of soybean protein is 5 µm. Add 15 parts of soybean protein to 80 parts of water, adjust the pH value with hydrochloric acid to make it acidic, and the pH value is 1.0. After adjusting the pH value When the temperature is controlled at 50°C, dissolve for 1 hour, then add 5 parts of malondialdehyde, carry out cross-linking reaction under mechanical stirring for 6 hours, then add 15 parts of sodium hydroxide and 25 parts of carbon disulfide, and react for 3 hours to obtain the required Water-soluble biomass heavy metal scavenger.

Embodiment 3

[0024] Soy protein is extracted from soybeans. The average particle size of soybean protein is 10µm. Add 30 parts of soybean protein to 150 parts of water, adjust the pH value with hydrochloric acid to make it acidic, and the pH value is 2.0. After adjusting the pH value When the temperature is controlled at 50°C, dissolve for 1 hour, then add 10 parts of glutaraldehyde, carry out cross-linking reaction for 5 hours under mechanical stirring, then add 60 parts of potassium hydroxide and 60 parts of carbon disulfide, and react for 1 hour to obtain the desired Water-soluble biomass heavy metal scavenger.

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PUM

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Abstract

The invention relates to a water soluble biomass heavy metal capture agent and the preparation method of the water soluble biomass heavy metal capture agent. According to the preparation method, 1 to 40 parts of soyabean protein are added into 10 to 300 parts of water; the pH value is regulated to the acid state (the pH is smaller than 3) or the alkaline state (the pH is greater than 8); the temperature is controlled to be 30 to 70 DEG C; dissolving is performed for 1 to 2 hours; then, 1 to 20 parts of cross-linking agents are added; cross-linking reaction is performed for 3 to 8 hours; next, 1 to 80 parts of alkali and 10 to 100 parts of carbon disulfide are added; dithiocar-bamate synthesis reaction is performed for 1 to 3 hours, and the novel water soluble biomass heavy metal capture agent is obtained. The water soluble biomass heavy metal capture agent can realize environmental degradation after being abandoned; the harm of a great amount of non-degradable synthetic macromolecule heavy metals can be relieved; the secondary environment pollution caused by capture agent wastes is avoided; the capture capability is high; the settling velocity is high; the stability is high.

Description

technical field [0001] The invention belongs to the field of heavy metal scavenger, in particular to a water-soluble biomass heavy metal scavenger and a preparation method thereof. Background technique [0002] Heavy metal ion scavenger is an organic compound with chelating functional groups, which can selectively capture, separate and precipitate heavy metals from solutions containing metal ions. The main synthesis route of polymer capture agents is to use synthetic polymers or natural polymers as molecular skeletons, and introduce capture functional groups through chemical reactions. At present, the heavy metal scavengers that are widely used in actual research mainly include xanthate and dithiocarbamate derivatives (DTC), and DTC derivatives are the most widely used. [0003] At present, the main direction of the research and application of heavy metal scavenger is to improve efficiency, reduce chemical consumption, reduce pollution, enhance environmental awareness, stre...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F1/52
Inventor 刘锋
Owner 重庆高新技术产业研究院有限责任公司
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