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A kind of composite sol paint for aluminum alloy surface, its preparation method and coating method

A composite sol, aluminum alloy technology, applied to the surface coating device, anti-corrosion paint, coating and other directions, can solve the problems of poor dispersion, reduced wear resistance, agglomeration, etc., to improve uniformity and wear resistance. sexual effect

Active Publication Date: 2017-12-08
AVIC BEIJING INST OF AERONAUTICAL MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Its disadvantages are: in order to achieve the wear-resistant effect, nano or micro particles are generally directly doped into the composite sol coating. The affinity between nano or micro particles and the composite sol coating is often not high, which will cause problems such as agglomeration and poor dispersion. Affects the uniformity of particle distribution in the final coating, thereby reducing its abrasion resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] 1) Pretreatment of aluminum alloy samples

[0032] The pretreatment of the aluminum alloy samples is carried out according to the provisions of the aviation industry standard HB / Z 233-1993 "Sulfuric Acid Anodizing Process of Aluminum and Aluminum Alloys".

[0033] 2) Sol preparation

[0034] First, add 5ml of anhydrous acetic acid to 300ml of anhydrous methanol at room temperature, then slowly add 400ml of γ-glycidyl etheroxypropyltrimethoxysilane, stir evenly for 1 hour, and obtain an organosiloxane sol. At the same time, 8 ml of anhydrous acetic acid and 80 ml of zirconium propoxide were poured into 100 ml of anhydrous methanol, and stirred evenly for 1 hour to obtain a metal alkoxide sol. Under stirring, the organosiloxane sol and the metal alkoxide sol were mixed, and stirred at room temperature for 2 hours to obtain a mixed sol.

[0035] Then, at room temperature, a solution containing 5% chloroauric acid in anhydrous methanol was prepared.

[0036] Finally, und...

Embodiment 2

[0043] 1) Pretreatment of aluminum alloy samples

[0044] The pretreatment of the aluminum alloy samples is carried out according to the provisions of the aviation industry standard HB / Z 233-1993 "Sulfuric Acid Anodizing Process of Aluminum and Aluminum Alloys".

[0045] 2) Sol preparation

[0046] First, add 5ml of anhydrous acetic acid to 300ml of anhydrous methanol at room temperature, then slowly add 500ml of 3-glycidyl etheroxymethyldiethoxysilane, stir evenly and continue for 1 hour to obtain an organosiloxane sol . At the same time, 5 ml of citric acid and 50 ml of tetrabutyl titanate were poured into 100 ml of anhydrous methanol, and stirred evenly for 1 hour to obtain a metal alkoxide sol. Under stirring, the organosiloxane sol and the metal alkoxide sol were mixed, and stirred at room temperature for 2 hours to obtain a mixed sol.

[0047] Then at room temperature, a solution containing 4% chloroauric acid in anhydrous methanol was prepared.

[0048] Finally, und...

Embodiment 3

[0055] 1) Pretreatment of aluminum alloy samples

[0056] The pretreatment of the aluminum alloy samples is carried out according to the provisions of the aviation industry standard HB / Z 233-1993 "Sulfuric Acid Anodizing Process of Aluminum and Aluminum Alloys".

[0057] 2) Sol preparation

[0058] First, at room temperature, 5ml of anhydrous acetic acid was added to 300ml of absolute ethanol, and then 600ml of γ-glycidyloxypropyltrimethoxysilane was slowly added, stirred evenly and continued for 1 hour to obtain an organosiloxane sol. At the same time, 8 ml of anhydrous acetic acid and 60 ml of zirconium n-propoxide were poured into 100 ml of anhydrous methanol, and stirred evenly for 1 hour to obtain a metal alkoxide sol. Under stirring, the organosiloxane sol and the metal alkoxide sol were mixed, and stirred at room temperature for 2 hours to obtain a mixed sol.

[0059] Then, at room temperature, a solution containing 6% chloroauric acid in anhydrous methanol was prepar...

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PUM

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Abstract

The invention belongs to a preparation technology of a composite coating layer on the surface of metal, and relates to a composite sol coating material for the surface of aluminum alloy, and a preparation method and a coating method of the composite sol coating material. The composite sol coating material is characterized by being prepared from organic siloxane, metal alkoxide, a catalyst, an ultraviolet active solution, an organic polymerization initiator and a solvent. The preparation method comprises the preparation steps of preparing raw materials; preparing organic siloxane sol; preparing a metal alkoxide sol; mixing; preparing the ultraviolet active solution; preparing the composite sol coating material. The coating method comprises the coating steps of washing; composite sol coating material coating; coating layer drying. According to the composite sol coating material for the surface of the aluminum alloy, and the preparation method and the coating method of the composite sol coating material, provided by the invention, the distribution uniformity of nanoparticles or microparticles in a final coating layer is greatly increased, and the abrasive resistance of the final coating layer is further increased.

Description

technical field [0001] The invention belongs to the preparation technology of a metal surface composite coating, and relates to a composite sol coating for the surface of an aluminum alloy, a preparation method and a coating method thereof. Background technique [0002] Aluminum alloy materials are widely used in aviation, aerospace, construction, automobile and many other industrial fields, and are one of the most commonly used metal materials. However, the corrosion resistance of most aluminum alloys is poor, and surface protection treatments such as anodic oxidation and chemical oxidation are generally required when used. However, although the anodic oxidation process can provide a good corrosion-resistant film layer, it will damage the fatigue performance of the aluminum alloy substrate; the chemical oxidation process generally uses hexavalent chromium and other substances that are harmful to the environment and human health. At the same time, the wear resistance of ano...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D183/04C09D7/12C09D5/08B05D7/14
CPCB05D7/14C09D5/08C09D7/61C09D183/04
Inventor 詹中伟孙志华彭超汤智慧宇波
Owner AVIC BEIJING INST OF AERONAUTICAL MATERIALS