Asymmetric iridium(iii) phosphorescent complex containing dibenzophosphine group and its synthesis method
A phosphorescent complex, benzophosphine technology, which is applied in the field of asymmetric iridium phosphorescent complexes and their synthesis, can solve the problems such as the development lag of phosphorescent materials, achieve high external quantum efficiency and current efficiency, and achieve the effect of full conversion
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Embodiment 1
[0037] Asymmetric iridium (III) phosphorescent complex Ir-PON containing dibenzophosphine group, its chemical formula is: C 51 h 39 IrN 3 o 3 P, the molecular structural formula is:
[0038]
[0039] Its synthetic method comprises the following steps:
[0040] Step 1: Obtain the ligand L-PO according to the synthesis method of the above-mentioned ligand containing diphenylphosphine group;
[0041] Step 2: Under a nitrogen atmosphere, weigh 0.35g (1mmol) of ligand L-PO, 0.32g (1mmol) of ligand L-N (for the synthesis of ligands, see references Adv.Funct.Mater.2008,18,499–511) and Add 0.32g of iridium trichloride hydrate (60% iridium content) into the SCHLENK reaction tube, add 30mL of degassed mixed solvent of ethylene glycol ether and water (V:V=3:1), heat up to 110°C and stir for reaction 16 Hour. After the reaction system was cooled to room temperature, an appropriate amount of brine was added to the reaction mixture, and a precipitate appeared. Take the filter cake...
Embodiment 2
[0045] Asymmetric iridium(III) phosphorescent complex Ir-POO containing dibenzophosphine group, the formula is: C 45 h 34 IrN 2 o 4 P, the molecular structural formula is:
[0046]
[0047] Its synthetic method comprises the following steps:
[0048] Step 1: Obtain the ligand L-PO according to the synthesis method of the above-mentioned ligand containing diphenylphosphine group;
[0049] Step 2: Under a nitrogen atmosphere, weigh 0.35g (1mmol) of ligand L-PO, 0.25g (1mmol) of ligand L-O (for the synthesis of ligands, see references Adv.Funct.Mater.2008,18,499–511) and Add 0.32g of iridium trichloride hydrate (iridium content 60%) into the SCHLENK reaction tube, add 30mL of degassed mixed solvent of ethylene glycol ether and water (V:V=3:1), heat up to 110°C and stir for 16 hours . After the reaction system was cooled to room temperature, an appropriate amount of brine was added to the reaction mixture, and a precipitate appeared. Take the filter cake by suction filtr...
Embodiment 3
[0053] Asymmetric iridium (III) phosphorescent complex Ir-POB containing dibenzophosphine group, its chemical formula is: C 57 h 51 BYZGR 2 o 3 P, the molecular structural formula is:
[0054]
[0055] Its synthetic method comprises the following steps:
[0056] Step 1: Obtain the ligand L-PO according to the synthesis method of the above-mentioned ligand containing diphenylphosphine group;
[0057] Step 2: Under nitrogen atmosphere, weigh 0.35g (1mmol) of ligand L-PO, 0.41g (1mmol) of ligand L-B (for the synthesis of ligands, refer to references Adv.Funct.Mater.2008,18,499–511) and Add 0.32g of iridium trichloride hydrate (60% iridium content) into the SCHLENK reaction tube, add 30mL of degassed mixed solvent of ethylene glycol ether and water (V:V=3:1), heat up to 110°C and stir for reaction 16 Hour. After the reaction system was cooled to room temperature, an appropriate amount of brine was added to the reaction mixture, and a precipitate appeared. Take the filter...
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