Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Asymmetric iridium(iii) phosphorescent complex containing dibenzophosphine group and its synthesis method

A phosphorescent complex, benzophosphine technology, which is applied in the field of asymmetric iridium phosphorescent complexes and their synthesis, can solve the problems such as the development lag of phosphorescent materials, achieve high external quantum efficiency and current efficiency, and achieve the effect of full conversion

Inactive Publication Date: 2018-11-23
XI AN JIAOTONG UNIV +1
View PDF4 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, due to the lack of electron injection / transport functional groups, the development of complex phosphorescent materials with electron injection / transport properties is relatively lagging behind.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Asymmetric iridium(iii) phosphorescent complex containing dibenzophosphine group and its synthesis method
  • Asymmetric iridium(iii) phosphorescent complex containing dibenzophosphine group and its synthesis method
  • Asymmetric iridium(iii) phosphorescent complex containing dibenzophosphine group and its synthesis method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Asymmetric iridium (III) phosphorescent complex Ir-PON containing dibenzophosphine group, its chemical formula is: C 51 h 39 IrN 3 o 3 P, the molecular structural formula is:

[0038]

[0039] Its synthetic method comprises the following steps:

[0040] Step 1: Obtain the ligand L-PO according to the synthesis method of the above-mentioned ligand containing diphenylphosphine group;

[0041] Step 2: Under a nitrogen atmosphere, weigh 0.35g (1mmol) of ligand L-PO, 0.32g (1mmol) of ligand L-N (for the synthesis of ligands, see references Adv.Funct.Mater.2008,18,499–511) and Add 0.32g of iridium trichloride hydrate (60% iridium content) into the SCHLENK reaction tube, add 30mL of degassed mixed solvent of ethylene glycol ether and water (V:V=3:1), heat up to 110°C and stir for reaction 16 Hour. After the reaction system was cooled to room temperature, an appropriate amount of brine was added to the reaction mixture, and a precipitate appeared. Take the filter cake...

Embodiment 2

[0045] Asymmetric iridium(III) phosphorescent complex Ir-POO containing dibenzophosphine group, the formula is: C 45 h 34 IrN 2 o 4 P, the molecular structural formula is:

[0046]

[0047] Its synthetic method comprises the following steps:

[0048] Step 1: Obtain the ligand L-PO according to the synthesis method of the above-mentioned ligand containing diphenylphosphine group;

[0049] Step 2: Under a nitrogen atmosphere, weigh 0.35g (1mmol) of ligand L-PO, 0.25g (1mmol) of ligand L-O (for the synthesis of ligands, see references Adv.Funct.Mater.2008,18,499–511) and Add 0.32g of iridium trichloride hydrate (iridium content 60%) into the SCHLENK reaction tube, add 30mL of degassed mixed solvent of ethylene glycol ether and water (V:V=3:1), heat up to 110°C and stir for 16 hours . After the reaction system was cooled to room temperature, an appropriate amount of brine was added to the reaction mixture, and a precipitate appeared. Take the filter cake by suction filtr...

Embodiment 3

[0053] Asymmetric iridium (III) phosphorescent complex Ir-POB containing dibenzophosphine group, its chemical formula is: C 57 h 51 BYZGR 2 o 3 P, the molecular structural formula is:

[0054]

[0055] Its synthetic method comprises the following steps:

[0056] Step 1: Obtain the ligand L-PO according to the synthesis method of the above-mentioned ligand containing diphenylphosphine group;

[0057] Step 2: Under nitrogen atmosphere, weigh 0.35g (1mmol) of ligand L-PO, 0.41g (1mmol) of ligand L-B (for the synthesis of ligands, refer to references Adv.Funct.Mater.2008,18,499–511) and Add 0.32g of iridium trichloride hydrate (60% iridium content) into the SCHLENK reaction tube, add 30mL of degassed mixed solvent of ethylene glycol ether and water (V:V=3:1), heat up to 110°C and stir for reaction 16 Hour. After the reaction system was cooled to room temperature, an appropriate amount of brine was added to the reaction mixture, and a precipitate appeared. Take the filter...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

Asymmetric iridium (III) phosphorescent complex containing dibenzophosphine group and its synthesis method; the synthesis of ligand L-PO takes 2-phenylpyridine and p-bromophenylboronic acid as raw materials through Suzuki coupling reaction Synthesis of 2-(4-bromophenyl)pyridine; 2-(4-bromophenyl)pyridine by reaction with n-butyllithium and trimethyl borate 4-(2-pyridyl)phenylboronic acid; 4-(2 ‑pyridyl) phenylboronic acid reacts with ortho-dibromobenzene through Suzuki coupling to generate a pyridine derivative containing 2‑bromobiphenyl structure. The Grignard reagent of this compound reacts with phenyl phosphorus dichloride, and then passes through palladium acetate catalyzed conditions. The ring-closing reaction can wait until the ligand L-PO containing dibenzophosphine group, and the asymmetric iridium (III) phosphorescent complex containing dibenzophosphine group prepared by the present invention has excellent electron The injection / transport properties can significantly improve the electroluminescent efficiency of organic electroluminescent devices based on these materials.

Description

technical field [0001] The invention relates to the technical field of organic electroluminescence, in particular to an asymmetric iridium (III) phosphorescent complex containing a dibenzophosphine group and a synthesis method thereof. Background technique [0002] Organic electroluminescent technology is a self-luminous technology of organic electroluminescent materials under the action of an electric field. Under the action of the electric field, electrons and holes are injected from the cathode and anode respectively, and migrate to the light-emitting layer under the action of the electric field; electrons and holes recombine in the light-emitting layer to form excitons, and the excitons undergo radiation decay, and finally the energy emitted in the form of light. Theoretical calculations show that in the excitons produced by the recombination of electrons and holes, the ratio of singlet excitons to triplet excitons is 1:3, and the relaxation from the triplet state to th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C07F15/00C09K11/06
CPCC07F15/0033C09K11/06C09K2211/185
Inventor 周桂江徐先彬杨晓龙潘俊生
Owner XI AN JIAOTONG UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products