A special sizing agent for cement-based material reinforced basalt fiber and its preparation method

A technology of basalt fiber and cement-based material, which is applied in the field of basalt fiber sizing agent, can solve the problems such as the inability to improve the compatibility of basalt fiber and cement-based material, and achieve the effects of clear production structure, good toughness and lubricity, and simple method.

Active Publication Date: 2018-07-10
浙江长兴市政建设有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the defect that the existing basalt fiber sizing agent cannot improve the compatibility of basalt fiber and cement-based materials, and provide a special sizing agent for cement-based materials to strengthen basalt fiber and its preparation method; the sizing agent of the present invention contains improved The fiber surface is modified by the modifier while infiltrating, so that the surface roughness of the fiber is increased and a large number of active groups are grafted, thereby improving the chemical bonding and mechanical riveting ability between the basalt fiber and the cement-based material , improve the compatibility of basalt fiber and cement-based materials, and promote the popularization and application of basalt fiber in the field of cement-based material reinforcement

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] (1) 15 parts by weight of a modifier containing ammonium phosphate: sodium hydroxide: sodium silicate mixed in a mass ratio of 3:2:5 is dissolved in 20 parts by weight of water to form a mixed solution A; 50 parts by weight of After dissolving the acrylate copolymer emulsion with 20 parts by weight of water, add 10 parts by weight of silane coupling agent and 3 parts by weight of methyl stearate to form mixed solution B;

[0030] (2) Add the mixed solution A obtained in step 1 into the mixed solution B and mix evenly to form a mixed solution C;

[0031] (3) Defoaming the mixed solution C obtained in step 2 to obtain a special sizing for cement-based materials reinforced basalt fibers.

Embodiment 2

[0033] (1) Dissolving 10 parts by weight of a modifier containing sodium phosphate: potassium hydroxide: potassium silicate in a mass ratio of 2:3:6 is dissolved in 10 parts by weight of water to form a mixed solution A; 60 parts by weight of After polyvinyl alcohol is dissolved in 30 parts by weight of water, 15 parts by weight of silane coupling agent and 1 part by weight of methyl stearate are added to form mixed solution B;

[0034] (2) Add the mixed solution A obtained in step 1 into the mixed solution B and mix evenly to form a mixed solution C;

[0035] (3) Defoaming the mixed solution C obtained in step 2 to obtain a special sizing for cement-based materials reinforced basalt fibers.

Embodiment 3

[0037] (1) Dissolve 20 parts by weight of a modifier containing potassium phosphate: calcium hydroxide: sodium silicate and potassium silicate in a mass ratio of 4:1:3 with 20 parts by weight of water to form a mixed solution A; Add the silane coupling agent of 5 parts by weight and the methyl stearate of 5 parts by weight after dissolving the acrylate copolymer emulsion of parts by weight with 30 parts by weight of water to form mixed solution B;

[0038] (2) Add the mixed solution A obtained in step 1 into the mixed solution B and mix evenly to form a mixed solution C;

[0039] (3) Defoaming the mixed solution C obtained in step 2 to obtain a special sizing for cement-based materials reinforced basalt fibers.

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PUM

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Abstract

The invention discloses a cement-based material reinforced basalt fiber special impregnating agent, and a preparation method thereof. The cement-based material reinforced basalt fiber special impregnating agent comprises, by weight, 40 to 60 parts of a film forming agent, 5 to 15 parts of a coupling reagent, 1 to 5 parts of a lubricating agent, 10 to 20 parts of a modifying agent, and 30 to 50 parts of water; the modifying agent comprises a soluble phosphate, a strong base, and a dissoluble silicate at a mass ratio of 2-4:1-3:3-6. The cement-based material reinforced basalt fiber special impregnating agent is used for impregnating and fiber surface modifying at the same time, fiber surface roughness is increased, and a large amount of active site and active groups are formed on fiber surfaces, so that chemical bonding and mechanical riveting of basalt fiber with a cement-based material are realized, an integrated stable whole body is formed by basalt fiber and the cement matrix, reinforcing effect on the cement-based material is obvious, reinforcing effect is excellent, and popularization and application of basalt fiber in the cement-based material is promoted.

Description

technical field [0001] The invention relates to the field of basalt fiber wetting agent, in particular to a special wetting agent for reinforcing basalt fiber with cement-based materials and a preparation method thereof. Background technique [0002] Basalt fiber is a new type of inorganic environmentally friendly green high-performance fiber material, and it is one of the four high-performance fibers that will be developed in my country in the future. The basalt rock material composed of basalt is melted at high temperature and then prepared by spinning process. Basalt continuous fiber not only has good stability, but also has various excellent properties such as electrical insulation, corrosion resistance, combustion resistance, and high temperature resistance. Moreover, the production process of basalt fiber produces less waste and less environmental pollution. It can be directly transferred to the ecological environment without any harm, so it is a veritable green and en...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C25/40C03C25/28C03C25/285
CPCC04B20/1074C04B20/1066C04B20/107C04B20/1051C04B20/1033C04B20/1025C04B14/4656
Inventor 不公告发明人
Owner 浙江长兴市政建设有限公司
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