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A special sizing agent for polyamide material reinforced basalt fiber and its preparation method

A basalt fiber and sizing technology, which is applied in the field of polyamide material reinforced basalt fiber special sizing agent and its preparation, can solve the problems that the compatibility between basalt fiber and polyamide materials cannot be improved, so as to promote wide application and improve compatibility properties, and the effect of improving chemical bonding ability

Inactive Publication Date: 2019-01-01
石狮市日久军警装备有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to overcome the defect that the existing basalt fiber sizing agent cannot improve the compatibility of basalt fiber and polyamide materials, and provide a special sizing agent for polyamide reinforced basalt fiber and its preparation method; the sizing agent of the present invention contains modified The modifier modifies the surface of the fiber while infiltrating, increasing the surface roughness of the fiber and grafting a large number of active groups, thereby improving the chemical bonding and mechanical riveting capabilities between the basalt fiber and the polyamide material, Improve the compatibility of basalt fiber and polyamide materials, and promote the popularization and application of basalt fiber in the field of polyamide material reinforcement

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] (1) Dissolve 15 parts by weight of a modifier containing sodium nitrate: sodium hydroxide: methyldiethoxysilane quaternary ammonium salt in a mass ratio of 3:2:2 with 20 parts by weight of water to form a mixed solution A; 50 parts by weight of polyurethane is dissolved with 20 parts by weight of water, and then 10 parts by weight of silane coupling agent and methyl stearate of 3 parts by weight are added to form mixed solution B;

[0029] (2) Add the mixed solution A obtained in step 1 into the mixed solution B and mix evenly to form a mixed solution C;

[0030] (3) Defoaming the mixed solution C obtained in step 2 to obtain a special sizing for polyamide material reinforced basalt fiber.

Embodiment 2

[0032] (1) Dissolve 10 parts by weight of a modifier containing potassium nitrate: potassium hydroxide: polysiloxane quaternary ammonium salt in a mass ratio of 2:1:1 with 10 parts by weight of water to form a mixed solution A; After 60 parts by weight of polyurethane are dissolved in 30 parts by weight of water, 15 parts by weight of silane coupling agent and 1 part by weight of methyl stearate are added to form mixed solution B;

[0033] (2) Add the mixed solution A obtained in step 1 into the mixed solution B and mix evenly to form a mixed solution C;

[0034] (3) Defoaming the mixed solution C obtained in step 2 to obtain a special sizing for polyamide material reinforced basalt fiber.

Embodiment 3

[0036] (1) Dissolve 20 parts by weight of a modifier containing ammonium nitrate: calcium hydroxide: trialkoxysilane quaternary ammonium salt in a mass ratio of 4:3:4 with 20 parts by weight of water to form a mixed solution A; After 40 parts by weight of polyurethane are dissolved in 30 parts by weight of water, 5 parts by weight of silane coupling agent and 5 parts by weight of methyl stearate are added to form mixed solution B;

[0037](2) Add the mixed solution A obtained in step 1 into the mixed solution B and mix evenly to form a mixed solution C;

[0038] (3) Defoaming the mixed solution C obtained in step 2 to obtain a special sizing for polyamide material reinforced basalt fiber.

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Abstract

The invention discloses a wetting agent special for polyamide material reinforcing basalt fibers and a preparation method of the wetting agent. The wetting agent provided by the invention comprises the following components in parts by weight: 40-60 parts of a film forming agent, 5-15 parts of a coupling agent, 1-5 parts of a lubricant, 10-20 parts of a modifier and 30-50 parts of water, wherein the modifier comprises a nitrate, a strong base and a quaternary ammonium salt at a mass ratio of 2-4: 1-3: 1-4. The modifier is used for modifying surfaces of the fibers while wetting, to improve the roughness of the surfaces of the fibers and form a large number of active sites and active groups, thereby chemically bonding and mechanically riveting to the polyamide material, uniformly and stably integrating with the polyamide material, significantly reinforcing the polyamide material, realizing excellent reinforcing effect, and promoting promotion and application of the basalt fibers in the field of reinforcement of the polyamide material.

Description

technical field [0001] The invention relates to the field of basalt fiber sizing agent, in particular to a special sizing agent for polyamide material reinforced basalt fiber and a preparation method thereof. Background technique [0002] Basalt fiber is a new type of inorganic environmentally friendly green high-performance fiber material, and it is one of the four high-performance fibers that will be developed in my country in the future. The basalt rock material composed of basalt is melted at high temperature and then prepared by spinning process. Basalt continuous fiber not only has good stability, but also has various excellent properties such as electrical insulation, corrosion resistance, combustion resistance, and high temperature resistance. Moreover, the production process of basalt fiber produces less waste and less environmental pollution. It can be directly transferred to the ecological environment without any harm, so it is a veritable green and environmental ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/00C08K9/02C08K9/04C08K9/06C08K7/10
CPCC08J2377/00C08K7/10C08K9/02C08K9/04C08K9/06C08K9/08C08L77/00
Inventor 不公告发明人
Owner 石狮市日久军警装备有限公司
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