Silver nanowire-silver complex composite conductive ink and preparation method of transparent conductive film thereof

A transparent conductive film and nano-silver wire technology, applied in the field of liquid crystal, can solve the problems of inability to improve the stability of nano-silver wire ink, short shelf life, agglomeration and sedimentation, etc. The effect of uniformity and easy industrial production

Active Publication Date: 2017-11-14
CHINA LUCKY FILM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Nano-silver wires have high surface activity and are prone to agglomeration and sedimentation when dispersed in solvents. On the one hand, the prepared nano-silver wire ink has poor stability and short shelf life, making it difficult for industrial production; on the other hand, it causes the formation of nano-silver wire ink. Thin film, poor resistance uniformity, does not meet application requirements
In order to solve these problems, technicians have adopted many methods to adjust the formula of silver nano wire ink to improve the problem of agglomeration and sedimentation of nano silver wire and poor uniformity of film resistance.
For example, adding a high polym

Method used

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  • Silver nanowire-silver complex composite conductive ink and preparation method of transparent conductive film thereof

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preparation example Construction

[0030] A preparation method of nano-silver wire transparent conductive film, the method comprising the following steps:

[0031] (1) Corona or plasma treatment is performed on the flexible transparent substrate;

[0032] (2) the nano-silver wire-silver complex composite conductive ink according to claim 1 is applied to the flexible transparent substrate surface by slit coating, slope coating, micro-gravure coating or doctor blade coating method, After thermal curing, a nano-silver wire-silver complex composite conductive layer is formed;

[0033] (3) Apply the protective layer coating solution to the surface of the nano-silver wire-silver complex composite conductive layer by slit coating, slope coating, micro-gravure coating or doctor blade coating method, and heat-cure or light-cure Finally, a protective layer is formed to obtain a transparent conductive film of nano-silver wires.

[0034]The flexible transparent substrate suitable for the present invention requires certai...

Embodiment 1

[0039] Step 1: Handling the Flexible Transparent Substrate

[0040] 100μm thick PET is selected, the width is 550mm, the total light transmittance is 91.3%, the haze is 0.34%, and the surface energy is 36dyn / cm after 0.8kV voltage corona.

[0041] The second step: preparation of nano-silver wire-silver complex composite layer

[0042] Preparation of nano-silver wire-silver complex composite conductive ink: 1) Disperse nano-silver wires with a wire diameter of 25nm and a length of 15 μm in ethanol solvent, and prepare 8L of nano-silver wire ink with a concentration of 0.5wt%; 2) Disperse the silver complex AgSCN in the stabilizer terpineol, and prepare 2L silver complex ink with a concentration of 10wt%; 3) then mix 8L nano-silver wire ink and 2L silver complex ink, and stir for 0.5h Form nano silver wire-silver complex conductive ink.

[0043] Coating nano-silver wire-silver complex conductive ink: use a slit coater to coat the above-prepared nano-silver wire-silver complex ...

Embodiment 2

[0048] Step 1: Handling the Flexible Transparent Substrate

[0049] Use PC with a thickness of 125 μm, a width of 560 mm, a total light transmittance of 88.2%, a haze of 0.78%, and a surface energy of 38 dyn / cm after corona with a voltage of 0.6 kV.

[0050] The second step: preparation of nano-silver wire-silver complex composite layer

[0051] Preparation of nano-silver wire-silver complex composite conductive ink: 1) Disperse nano-silver wires with a wire diameter of 50 nm and a length of 10 μm in an aqueous solvent to prepare 8.5 L of nano-silver wire ink with a concentration of 1 wt %; 2) Silver complex AgOCN is dispersed in stabilizer 2-phenoxyethanol, is mixed with the silver complex ink 1.5L of 8wt%; 3) then 8.5L nano-silver line ink and 1.5L silver complex ink are mixed , and stirred for 0.5h to form silver nano wire-silver complex conductive ink.

[0052] Coating nano-silver wire-silver complex conductive ink: use a slope flow coater to coat the above-prepared nano...

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Abstract

The invention discloses silver nanowire-silver complex composite conductive ink which comprises silver nanowire ink and silver complex ink, wherein the silver nanowire ink accounts for 80-95 wt%, and the silver complex ink accounts for 5-20 wt%; the silver nanowire ink comprises a silver nanowire and a dispersing agent, the silver nanowire accounts for 0.5-5 wt%, and the dispersing agent accounts for 95-99.5 wt%; and the silver complex ink comprises a silver complex and a stabilizer, the silver complex accounts for 5-10 wt%, and the stabilizer accounts for 90-95wt%. According to the silver nanowire-silver complex composite conductive ink disclosed by the invention, the preservation period of the composite conductive ink can be prolonged, industrialized production is easily realized, the conductivity and uniformity of the formed film are improved, the speed of separating out the silver nanowire in the silver nanowire ink can be effectively reduced, and the silver nanowire is prevented from being agglomerated and settled; and meanwhile, the resistance uniformity of the silver nanowire after film formation can be increased.

Description

technical field [0001] The invention relates to the technical field of liquid crystals, in particular to a preparation method based on nano-silver wire conductive ink and a transparent conductive film thereof. Background technique [0002] Transparent conductive film is a flexible film with high light transmittance and conductive properties in the visible light range, which can be used in various fields such as touch, display, photovoltaic, lighting, and wearable electronic devices. At present, ITO conductive film occupies 90% of the market of transparent conductive film, but it has the problems of high price, poor flexibility, high energy consumption and high resistance, so there is an urgent need for new alternative technologies suitable for bending applications and large-scale applications. [0003] The nano-silver wire transparent conductive film realizes the conductive function by forming a network structure through intersecting and interpenetrating nano-silver wires, a...

Claims

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Application Information

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IPC IPC(8): C09D11/52C08J7/04C08J7/06C08L67/02C08L69/00C08L83/04C08L79/08
CPCC08J7/06C08J2367/02C08J2369/00C08J2379/08C08J2383/04C08J2429/04C08J2433/00C08J2465/00C08J2475/04C08J2483/04C09D11/52C08J7/0427
Inventor 侯丽新李鹤程媛王亚丽宋鑫刘贤豪赵伟建王佳
Owner CHINA LUCKY FILM CORP
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