Unlock instant, AI-driven research and patent intelligence for your innovation.

A graphite-metal frame composite bipolar plate and its preparation method

A metal frame and bipolar plate technology, applied to battery electrodes, structural parts, electrical components, etc., can solve the problems of high cost and difficult surface modification of metal plates, and achieve enhanced bending strength, good electrical conductivity, and increased overall The effect of intensity

Active Publication Date: 2020-10-02
QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] In view of the problems existing in the above-mentioned prior art, the object of the present invention is to provide a graphite-metal frame composite bipolar plate and a preparation method thereof. The present invention prepares the graphite-metal frame bonded composite bipolar plate of the present invention, which has strength High, excellent electrical conductivity, strong corrosion resistance, etc., solve the problem of difficult surface modification and high cost of large-area metal plates, suitable for industrialization, and have great application prospects

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A graphite-metal frame composite bipolar plate and its preparation method
  • A graphite-metal frame composite bipolar plate and its preparation method
  • A graphite-metal frame composite bipolar plate and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0062] A preparation method of graphite-metal frame composite bipolar plate:

[0063] 1) Preparation of graphite plate: Put 65wt% of artificial graphite, 20wt% of phenolic resin, 15wt% of carbon nanotubes and carbon black and other additives into a high-speed stirrer for mixing for 20 minutes. Then, the mixture is put into a twin-screw extruder for kneading and granulation, and graphite plates with fuel flow channels 8 and oxidant flow channels 12 are prepared respectively by extrusion and calendering. The thickness of the graphite plates is 0.8 mm, the fuel flow channel and the oxidant flow channel are concave-convex structures, the flow channel depth is 0.3mm, and the width is 1mm.

[0064] 2) Preparation of the metal frame of the anode plate: a 0.1 mm thick stainless steel 316 plate is stamped and formed in a mold, and the metal frame 401 of the anode plate after stamping is distributed with a first fuel inlet 101, a second fuel inlet 102, a first Fuel outlet 201, second f...

Embodiment 2

[0068] A preparation method of graphite-metal frame composite bipolar plate:

[0069] 1) Put 70wt% of expanded graphite, 15wt% of polypropylene, 15wt% of carbon nanotubes and copper powder and other additives into a high-speed stirrer for mixing for 30 minutes. Then, the mixture is molded to prepare graphite plates with fuel flow channels 8 and oxidant flow channels 12 respectively. The thickness of the graphite plate is 1.0mm, and both the fuel flow channels and the oxidant flow channels are concave-convex structures. The depth of the runners is 0.4mm and the width is 1mm.

[0070] 2) Preparation of the metal frame of the anode plate: the same as in Example 1, the difference is that the 0.1 mm thick stainless steel 316 plate is replaced with a 0.2 mm thick titanium alloy TC4 plate.

[0071] 3) Preparation of the metal frame of the cathode plate: the same as in Example 1, the difference is that the 0.1 mm thick stainless steel 316 plate is replaced with a 0.2 mm thick titaniu...

Embodiment 3

[0074] 1. Preparation of graphite-metal frame composite bipolar plate

[0075] 1) Put 75wt% of natural graphite, 20wt% of polyethylene, 10wt% of carbon fiber and carbon black and other additives into a high-speed stirrer for mixing for 30 minutes. Then, the mixed materials are injected into graphite plates with fuel flow channels 8 and oxidant flow channels 12 respectively. The thickness of the graphite plates is 1.2mm, and both the fuel flow channels and the oxidant flow channels have a concave-convex structure. The depth of the runners is 0.3mm and the width is 1mm.

[0076] 2) Preparation of the metal frame of the anode plate: the same as in Example 1, the difference is that the 0.1 mm thick stainless steel 316 plate is replaced by the 0.2 mm thick stainless steel 304 plate.

[0077] 3) Preparation of the metal frame of the cathode plate: the same as in Example 1, the difference is that the 0.1 mm thick stainless steel 316 plate is replaced by a 0.2 mm thick stainless stee...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
depthaaaaaaaaaa
Login to View More

Abstract

The invention relates to a graphite-metal frame composite bipolar plate and a preparation method thereof. The bipolar plate comprises a negative electrode plate and a positive electrode plate; the negative electrode plate and the positive electrode plate are both formed by a metal frame and a graphite plate in a gluing manner separately, wherein the whole graphite plate is glued in the metal framethrough a gluing region on the metal frame; and the negative electrode plate and the positive electrode plate are connected in a sealing manner to form the graphite-metal frame glued composite bipolar plate. The preparation method comprises the steps of preparation of the graphite plate, preparation of the metal frame of the positive electrode plate and preparation of the metal frame of the negative electrode plate. The graphite-metal frame glued composite bipolar plate prepared in the invention has the characteristics of high intensity, excellent conductive performance, high corrosion resistance and the like; the main body of the graphite-metal frame composite bipolar plate is the graphite plate and each frame is a metal plate, so that coating treatment of the large-area metal plate is omitted, and the problem of performance inconsistency and the like caused by troublesome large-area coating process and uneven coating can be avoided, and extremely high application prospect is achieved.

Description

technical field [0001] The invention belongs to the technical field of proton exchange membrane fuel cells, and in particular relates to a graphite-metal frame composite bipolar plate and a preparation method thereof. Background technique [0002] Proton exchange membrane fuel cell is an electrochemical energy conversion device. Its energy conversion efficiency is not limited by the Carnot cycle. It can directly convert chemical energy into electrical energy efficiently and cleanly, and the product is pure water, which truly achieves zero emissions. , Zero pollution. Proton exchange membrane fuel cells have shown broad application prospects in civil and military fields such as transportation, portable power supplies, distributed power stations, aerospace and underwater vehicles. [0003] The bipolar plate is the core component of the proton exchange membrane fuel cell (PEMFC). It is the main part of the volume and weight of the PEMFC cell. The bipolar plate accounts for 60...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/86H01M4/96H01M4/88
CPCH01M4/86H01M4/88H01M4/96Y02E60/50
Inventor 李晓锦柳臻白兆圆
Owner QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI