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Copper and niobium reinforced corrosion-resistant austenitic stainless steel and preparation method thereof

A technology of austenitic stainless steel and stainless steel, applied in the field of austenitic stainless steel, can solve problems affecting the safe operation of nuclear power plants, damage to components or equipment, etc., and achieve the effects of excellent corrosion resistance, reduced corrosion rate, high hardness and strength

Inactive Publication Date: 2019-04-12
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When corrosion reaches a certain level, it will cause damage to components or equipment, and in severe cases, it will affect the safe operation of the entire nuclear power plant.

Method used

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  • Copper and niobium reinforced corrosion-resistant austenitic stainless steel and preparation method thereof
  • Copper and niobium reinforced corrosion-resistant austenitic stainless steel and preparation method thereof
  • Copper and niobium reinforced corrosion-resistant austenitic stainless steel and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Select electrical pure iron, metal chromium sheet, metal nickel plate, metal molybdenum, 316 stainless steel scrap, pure copper plate, and metal niobium as raw materials. The stainless steel composition is as follows: C=0.03, Ni=12.0, Cr=16.0, Mo=2.4, Nb=0.23, Cu=0.2, Mn=1.2, Si=0.8, P≤0.035, S≤0.030, Fe=balance. After weighing the corresponding raw materials according to the composition requirements, argon shielded arc melting, the temperature of the molten pool is kept at 1720°C during melting; the molten steel is calmed for 10 minutes before pouring, and the molten steel is poured under argon shielding at 1650°C. Cast into round ingots.

[0052] The ingot can be opened by hot forging, and the billet after hot forging is then cross-rolled and pierced to obtain a pipe billet; hot forging and cross-rolled piercing are heated to 1260 ° C, kept for 5 hours and then released for forging, the initial forging temperature is 1170 ° C, and the final forging temperature is 1170...

Embodiment 2

[0057] 316L stainless steel waste, pure copper plate, and ferroniobium are selected as raw materials, and the stainless steel components configured are as follows: C=0.25, Ni=13.0, Cr=16.8, Mo=2.6, Nb=0.30, Cu=0.3, Mn=1.2, Si=0.7 , P≤0.035, S≤0.030, Fe=balance.

[0058] After weighing the corresponding raw materials according to the composition requirements, vacuum induction melting is carried out, and the temperature of the molten pool is maintained at 1680°C during melting; the molten steel is calmed for 5 minutes before pouring, and the molten steel is vacuum poured at 1550°C. Cast into square ingots.

[0059] The billet is heated to 1270°C, and after 3 hours of heat preservation, the billet is opened by pass rolling. The initial rolling temperature is 1160°C, the final rolling temperature is 980°C, and the total area reduction rate of rolling is 62%. Bars were obtained, and the total rolling deformation was calculated as 82% according to the reduction of area. The bar is...

Embodiment 3

[0062] Select electrical pure iron, metal chromium sheet, metal nickel plate, metal molybdenum, pure copper plate, ferroniobium, and graphite block as raw materials, and the composition of the configured stainless steel is as follows: C=0.26, Ni=14.0, Cr=17.0, Mo=2.5, Nb =0.36, Cu=0.4, Mn=0.8, Si=0.5, P≤0.035, S≤0.030, Fe=balance.

[0063] After weighing the corresponding raw materials according to the composition requirements, they are induction smelted under the protection of argon, and the temperature of the molten pool is kept at 1700°C during smelting. Cast into round ingots.

[0064] The cast ingot can be rolled by a universal rolling mill with two pairs of parallel rolls. The cast billet is heated to 1280°C, held for 4 hours and rolled out of the furnace. The rate is calculated as 65%;

[0065] The T-shaped profile is prepared by universal rolling, and the total rolling deformation is calculated as 85% according to the reduction of area;

[0066] After cold rolling, ...

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Abstract

The invention discloses copper and niobium reinforced corrosion-resistant austenitic stainless steel and a preparation method thereof. Alloy elements comprise smaller than or equal to 0.03 C, 12.0-15.0 Ni, 16.0-18.0 Cr, 2.0-3.0 Mo, smaller than or equal to 0.53 Nb, 0.2-0.8 Cu, smaller than or equal to 2.0 Mn, smaller than or equal to 1.0 Si, smaller than or equal to 0.035 P, smaller than or equalto 0.030 S, and the balance Fe, wherein 7.73xC<=Nb<=7.73xC+0.3. After alloy smelting, due to thermal deformation cogging and cold deformation, NbC can be sufficiently broken and distributed in a dispersed manner, and due to high temperature solid solution treatment, coarse and large austenite grains are obtained. Under the hydrogen introducing condition, the alloy corroding current in a 0.5 mol / LH2SO4 electrolyte containing 5x10<-6>F<-> at 80 DEG C is 7.4-9.9 muA / cm<2>, compared with 316L stainless steel, the corroding speed is substantially lowered, and the mechanical performance is slightlysuperior to that of the 316L stainless steel.

Description

technical field [0001] The invention belongs to the field of austenitic stainless steel, relates to composition design, processing and heat treatment method of high corrosion resistance austenitic stainless steel, and can be widely used in energy, electric power, chemical industry and daily life. technical background [0002] Due to its excellent mechanical and corrosion resistance, stainless steel is widely used in energy, electric power, chemical and other fields. Austenitic stainless steel is widely used in the nuclear power industry because of its good mechanical properties, machinability, corrosion resistance and neutron radiation resistance. 304L and 316LN austenitic stainless steel are used as structural materials for the main pipeline of the PWR primary circuit, reactor internals, drive mechanism, main pump and pump shaft and other key equipment. These materials have served in harsh water chemical environments such as high temperature, high pressure and radiation fo...

Claims

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Application Information

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IPC IPC(8): C22C38/44C22C38/48C22C38/42C22C38/52C22C38/58C22C38/04C22C38/02B21C37/00C21D8/00
CPCB21C37/00C21D8/005C21D2211/001C22C38/02C22C38/04C22C38/42C22C38/44C22C38/48C22C38/52C22C38/58Y02P10/20
Inventor 罗丰华李国平吴子恺赵甲正刘涛艾兴
Owner CENT SOUTH UNIV