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Copper-zirconium-cobalt modified stainless steel and machining and heat treatment method thereof

A heat treatment method and stainless steel technology, applied in the field of austenitic stainless steel, can solve the problems such as the inability to meet the requirements of bipolar plate materials and the increase of contact resistance.

Inactive Publication Date: 2019-02-15
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The passivation layer formed by 316L stainless steel without surface treatment in the fuel cell environment will lead to an increase in contact resistance, which cannot meet the requirements of bipolar plate materials

Method used

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  • Copper-zirconium-cobalt modified stainless steel and machining and heat treatment method thereof
  • Copper-zirconium-cobalt modified stainless steel and machining and heat treatment method thereof
  • Copper-zirconium-cobalt modified stainless steel and machining and heat treatment method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0051] Select electrical pure iron, metal chromium sheet, metal nickel plate, metal molybdenum, 316 stainless steel scrap, pure copper block, pure cobalt sheet, and metal zirconium as raw materials. The stainless steel composition is as follows: C=0.03, Ni=12, Cr=16.0 , Mo=2.0, Zr=0.22, Cu=0.2, Co=0.1, Mn=1.2, Si=0.8, P≤0.035, S≤0.030, Fe=balance.

[0052] After the corresponding raw materials are weighed according to the composition requirements, the argon shielded arc melting is carried out, and the temperature of the molten pool is maintained at 1720°C during melting; the molten steel is calmed for 10 minutes before pouring, and the molten steel is poured under argon shielding at 1600°C.

[0053] The plate is hot-rolled by a flat-roll mill. The hot-rolling plan is to heat the cast billet to 1290°C, hold it for 5 hours, and then roll it out of the furnace. The hot-rolling start temperature is 1190°C, and the final rolling temperature is 950°C. The total amount of plate hot r...

Embodiment 2

[0059] Select 316L stainless steel waste, pure copper block, pure cobalt sheet, and iron zirconium as raw materials. The stainless steel composition is as follows: C=0.014, Ni=12.8, Cr=16.8, Mo=2.4, Zr=0.30, Cu=0.3, Co= 0.2, Mn=1.2, Si=0.7, P≤0.035, S≤0.030, Fe=balance.

[0060] After weighing the corresponding raw materials according to the composition requirements, vacuum induction melting is carried out, and the temperature of the molten pool is maintained at 1680°C during melting; the molten steel is calmed for 5 minutes before pouring, and the molten steel is vacuum poured at 1500°C.

[0061] The plate is hot-rolled by a flat-roll mill. The hot-rolling plan is to heat the cast slab to 1270°C, heat it for 5 hours and then roll it out of the furnace. The hot-rolling start temperature is 1160°C and the final rolling temperature is 1000°C. The total amount of hot rolling of the plate is 65%.

[0062] The plate is deformed by cold rolling, and the total reduction of cold roll...

Embodiment 3

[0066]Select electrical pure iron, metal chromium sheet, metal nickel plate, metal molybdenum, pure copper block, pure cobalt sheet, zirconium iron, and graphite block as raw materials. The stainless steel composition is as follows: C=0.025, Ni=15.0, Cr=18.0, Mo=3.0, Zr=0.36, Cu=0.4, Co=0.3, Mn=0.8, Si=0.5, P≤0.035, S≤0.030, Fe=balance.

[0067] After weighing the corresponding raw materials according to the composition requirements, they are induction smelted under the protection of argon gas.

[0068] The plate is hot-rolled with a flat roll mill. The hot-rolling plan is to heat the cast billet to 1280°C, keep it warm for 4 hours, and then roll it out of the furnace. The hot-rolling start temperature is 1180°C, and the final rolling temperature is 980°C. The total amount of hot rolling of the plate is 70%.

[0069] The plate is deformed by cold rolling, and the total reduction of cold rolling is 82%.

[0070] The plate is annealed at 1100°C, the holding time is 60 minutes,...

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Abstract

Disclosed are copper-zirconium-cobalt modified stainless steel and a processing and heat treatment method of the copper-zirconium-cobalt modified stainless steel. The copper-zirconium-cobalt modifiedstainless steel comprises the following alloy elements of, by mass percentage, C<=0.03, 12.0-15.0 of Ni, 16.0-18.0 of Cr, 2.0-3.0 of Mo, Zr<=0.53, 0.2-0.8 of Cu, 0.1-0.5 of Co, Mn<=2.0, Si<=1.0, P<=0.035, S<=0.030 and the balance Fe, wherein 7.59*C<=Zr<=7.59*C+0.3. Hot deformation cogging and cold deformation are carried out to break and disperse ZrC, and high-temperature solid solution treatment is performed to achieve grain coarsening. Under the condition of oxygen supply, the corrosion current density of a 0.5mol / L H2SO4 electrolyte containing 5*10<-6>F<-> at 80 DEG C is 1.23-1.76muA / cm<2> and is equivalent to that of a surface-coated stainless steel bipolar plate material. The copper-zirconium-cobalt modified stainless steel and the processing and heat treatment method of thecopper-zirconium-cobalt modified stainless steel have the advantages of low hardness, high extensibility and facilitating bipolar plate flow passage forming.

Description

technical field [0001] The invention belongs to the field of austenitic stainless steel, relates to composition design, processing and heat treatment method of high corrosion resistance austenitic stainless steel, and can be widely used in energy, electric power, chemical industry and daily life. technical background [0002] A fuel cell is a device that directly converts the chemical energy between hydrogen fuel and oxidant into electrical energy through an electrode reaction. Due to its high efficiency, low pollution, short construction time, good reliability and maintainability, it is the fourth generation power generation technology after hydropower, thermal power and nuclear power. Among many fuel cells, the proton exchange membrane fuel cell is a new type of fuel cell that develops late, but it develops most rapidly. [0003] In a fuel cell, the conductive separators that support, collect, divide oxidants and reductants and guide the flow of oxidants and reductants on...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/44C22C38/50C22C38/42C22C38/52C22C38/58C22C38/04C22C38/02C21D8/02C21D1/18
CPCC21D1/18C21D8/0226C21D8/0236C21D8/0273C21D2211/001C22C38/02C22C38/04C22C38/42C22C38/44C22C38/50C22C38/52C22C38/58Y02P10/20
Inventor 罗丰华赵林李国平雷龙林徐然王宸
Owner CENT SOUTH UNIV