Electrode pole piece and electrochemical device comprising said electrode pole piece
A pole piece and anode technology, which is applied in the field of electrochemical devices, can solve the problems of reducing the safety of batteries and electrochemical short circuits, and achieve the effects of improving uneven lithium deposition, improving safety, and reducing the probability of lithium dendrite formation
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[0141] Preparation of lithium-ion batteries
[0142] The cathode active material is prepared into a lithium ion battery by the following preparation method. Specifically, the cathode active material, conductive agent, and binder are fully stirred and mixed in N-methylpyrrolidone according to a certain weight ratio to make a cathode slurry, and then the obtained cathode slurry is evenly coated on the cathode current collector The front and back surfaces of the aluminum foil are dried at 85°C to obtain a cathode active material layer, and then cold pressed, stripped, cut into pieces, and cathode tabs are welded to obtain a cathode sheet.
[0143] Fully stir and mix the anode active material, binder, and dispersant in deionized water according to a certain weight ratio to make an anode slurry, and then evenly coat the anode slurry on the front and back of the anode current collector copper foil , and then dried at 85°C to form an anode active material layer, and then perform c...
Embodiment 1-9 and comparative example 1-10
[0154] Examples 1-9 involved zone coating the cathode tab without zone coating the anode tab. The following will specifically describe the preparation method of the cathode sheet in Examples 1-9 and Comparative Examples 1-10:
[0155] The preparation method of the electrode pole piece of embodiment 1:
[0156] (1) Preparation of slurry
[0157] Cathode LiNi 0.8 co 0.1 mn 0.1 o 2 / LiCoO 2 Slurry: the cathode active component LiNi 0.8 co 0.1 mn 0.1 o 2 / LiCoO 2 , the conductive agent Super-P and the binder polyvinylidene fluoride PVDF are mixed in a weight ratio of 97%: 1.5%: 1.5%, and diluted with an appropriate amount of N-methylpyrrolidone, and then stirred in a vacuum mixer to form a uniform cathode slurry material.
[0158] Anode graphite slurry: mix positive active component graphite, binder styrene-butadiene rubber SBR and dispersant carboxymethyl cellulose CMC in a 97%:1%:2% weight ratio, and dilute with an appropriate amount of distilled water, and then mix ...
Embodiment 10-14 and comparative example 11-15
[0176] Examples 10-14 and Comparative Examples 11-15 only involve zone coating on the anode pole piece, but not zone coating on the cathode pole piece. The preparation methods of the anode pole pieces in Examples 10-14 and Comparative Examples 11-15 will be described in detail below:
[0177] The preparation method of the electrode pole piece of embodiment 10:
[0178] (1) Preparation of slurry
[0179] Anode graphite / hard carbon slurry: mix positive active component graphite / hard carbon, binder styrene-butadiene rubber SBR and dispersant carboxymethyl cellulose CMC in a 97%:1%:2% weight ratio, and dilute with an appropriate amount of distilled water , and then stirred in a vacuum mixer to form a uniform anode slurry.
[0180] Cathode LiNi 0.8 co 0.1 mn 0.1 o 2 Slurry: the cathode active component LiNi 0.8 co 0.1 mn 0.1 o 2 , the conductive agent Super-P and the binder polyvinylidene fluoride PVDF are mixed in a weight ratio of 97%: 1.5%: 1.5%, and diluted with an ap...
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