A kind of hydrogel that can be used for marine antifouling and its preparation method and application
A hydrogel, hydrophilic technology, applied in antifouling/underwater coatings, biocide-containing paints, coatings, etc., can solve the problems of reduced mechanical properties, impact, and hydrogen bonds cannot be restored to the original.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
preparation example Construction
[0067] The preparation method of the present invention will be further described in detail in conjunction with specific examples below. It should be understood that the following examples are only for illustrating and explaining the present invention, and should not be construed as limiting the protection scope of the present invention. All technologies realized based on the above contents of the present invention are covered within the scope of protection intended by the present invention.
[0068] The experimental methods used in the following examples are conventional methods unless otherwise specified; the reagents and materials used in the following examples can be obtained from commercial sources unless otherwise specified.
[0069] In the present invention, the rehydratable property refers to that the hydrogel can quickly absorb water and reach its original state without swelling after dehydration.
[0070] In the present invention, the mechanical stability refers to t...
preparation example 1
[0073] Add 100ml of ethyl acetate to a 250ml round-bottomed flask with a magnet, then add 1,3-propane sultone (0.1mol), then dimethylaminoethyl methacrylate ( DMAEMA) (0.1 mol) was added dropwise to the solution. After 24 hours, the reaction was stopped and vacuum filtration was performed. Subsequently, it was washed three times with ethyl acetate and dried under vacuum to obtain a white powder product, which was confirmed by NMR.
[0074] figure 1 For the nuclear magnetic spectrum of the zwitterionic compound 3-(2-methacryloyloxyethyl dimethylamino)propanesulfonate (DMAPS) prepared in Preparation Example 1, it can be seen from the figure that each hydrogen of DMAPS Assignment: 1.80(s,3H,bH), 2.13(m,2H,gH), 3.21(s,6H,eH), 2.88, 3.79, 3.61(dH,fH,hH), 4.5(d,2H,cH) , 6.22 (s, 1H, aH), 5.76 (d, 1H, aH), 4.7 (solvent, D2O peak), indicating that the prepared product is 3-(2-methacryloyloxyethyl dimethylamino) propanesulfonate (DMAPS).
Embodiment 1
[0075] Embodiment 1: Preparation of PHEM-5%D hydrogel:
[0076] Weigh 4g of hydroxyethyl methacrylate (HEMA) into a beaker, then add 0.5g of methacrylic acid (MMA), then pour 5mL of deionized water, then add 0.5g of 3-(2-methacryloyloxy Ethyldimethylamino)propanesulfonate (DMAPS), then 100mg of polyethylene glycol dimethacrylate (PEGDMA) was added as a cross-linking agent and 20mg of 2,2-diethoxyacetophenone ( DEOP) as an initiator, stirred evenly, ultrasonically removed air bubbles, then poured into a PTFE mold, placed in a 365nm ultraviolet light source and irradiated for 600s to obtain a PHEM-5%D hydrogel sample with a thickness of 1mm and a length and width of 5*5cm.
PUM
Property | Measurement | Unit |
---|---|---|
wavelength | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com