Biphenyl tetramine compound and organic electroluminescent device
A biphenyltetramine and compound technology, applied in the field of biphenyltetramine compounds and their organic electroluminescent devices, can solve the problems of reduced device life, damage to interface contacts, and light-emitting devices that cannot meet the lifespan, efficiency and energy consumption. Achieve the effect of long half-life and low driving voltage
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[0093] Compound Preparation and Characterization
[0094] Description of starting materials, reagents, and characterization equipment:
[0095] The raw material used in the present invention and reagent are reagent pure;
[0096] The mass spectrometry uses the AXIMA-CFRplus matrix-assisted laser desorption ionization flight mass spectrometer of Shimadzu Group UK Kratos Analytical Company, and chloroform is used as the solvent;
[0097] For elemental analysis, a VarioELcube organic elemental analyzer from German Elementar Company was used, and the sample mass was 5-10 mg;
[0098] Nuclear magnetic resonance (1HNMR) uses Bruker-510 type nuclear magnetic resonance spectrometer (Germany Bruker company), 600MHz, CDCl3 is a solvent, and TMS is an internal standard.
[0099] Synthesis Example 1: Synthesis of Compound (1)
[0100]
[0101] 3.0g0.020mol of E, 1.9g0.020mol of F, 0.50g0.90mmol of Pd 2 (dba), 0.1g0.50mmol of P(t-Bu) and 4.0g0.040mol of NaOtBu are put into two-necke...
Embodiment 1~7
[0163] Embodiment 1~7 (manufacture of organic electroluminescence device)
[0164] In Examples 1 to 7, compounds (1), (2), (21), (34), (87), (150), and (124) listed in Table 1 were used instead of HI as the hole injection material. -1. Except for the above, the same operation was carried out to fabricate an organic electroluminescent device. For the obtained organic electroluminescence device, the measurement data of the emission color, half-life and driving voltage are shown in Table 1.
Embodiment 8~11
[0165] Embodiment 8~11 (manufacture of organic electroluminescence device)
[0166] In Examples 8 to 11, the compounds (125), (129), (128), and (152) described in Table 1 were used instead of TBDB as the hole transport material, and the same operation was carried out to produce Electromechanical Luminescent Devices. For the obtained organic electroluminescence device, the measurement data of the emission color, half-life and driving voltage are shown in Table 1.
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