Biphenyl tetramine compound and organic electroluminescent device

A biphenyltetramine and compound technology, applied in the field of biphenyltetramine compounds and their organic electroluminescent devices, can solve the problems of reduced device life, damage to interface contacts, and light-emitting devices that cannot meet the lifespan, efficiency and energy consumption. Achieve the effect of long half-life and low driving voltage

Active Publication Date: 2020-07-14
CHANGCHUN HYPERIONS TECH CO LTD
View PDF7 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This kind of crystallization will destroy the uniformity of the film, and at the same time destroy the good interfacial contact between the hole transport layer, the anode and the organic layer, resulting in a decrease in the life of the device. Therefore, to improve the life of the device, it is usually used Transition temperature (T g )s material
[0003] Hole-injection materials or hole-transport materials are major obstacles to the full practical application of organic electroluminescent technology, which directly limit the luminous efficiency, service life and operating voltage of the device.
Organic electroluminescent devices with hole injection layers or hole transport layers made of traditional materials cannot meet the needs of life, efficiency, and energy consumption, so materials that have significantly improved these properties are needed

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Biphenyl tetramine compound and organic electroluminescent device
  • Biphenyl tetramine compound and organic electroluminescent device
  • Biphenyl tetramine compound and organic electroluminescent device

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0093] Compound Preparation and Characterization

[0094] Description of starting materials, reagents, and characterization equipment:

[0095] The raw material used in the present invention and reagent are reagent pure;

[0096] The mass spectrometry uses the AXIMA-CFRplus matrix-assisted laser desorption ionization flight mass spectrometer of Shimadzu Group UK Kratos Analytical Company, and chloroform is used as the solvent;

[0097] For elemental analysis, a VarioELcube organic elemental analyzer from German Elementar Company was used, and the sample mass was 5-10 mg;

[0098] Nuclear magnetic resonance (1HNMR) uses Bruker-510 type nuclear magnetic resonance spectrometer (Germany Bruker company), 600MHz, CDCl3 is a solvent, and TMS is an internal standard.

[0099] Synthesis Example 1: Synthesis of Compound (1)

[0100]

[0101] 3.0g0.020mol of E, 1.9g0.020mol of F, 0.50g0.90mmol of Pd 2 (dba), 0.1g0.50mmol of P(t-Bu) and 4.0g0.040mol of NaOtBu are put into two-necke...

Embodiment 1~7

[0163] Embodiment 1~7 (manufacture of organic electroluminescence device)

[0164] In Examples 1 to 7, compounds (1), (2), (21), (34), (87), (150), and (124) listed in Table 1 were used instead of HI as the hole injection material. -1. Except for the above, the same operation was carried out to fabricate an organic electroluminescent device. For the obtained organic electroluminescence device, the measurement data of the emission color, half-life and driving voltage are shown in Table 1.

Embodiment 8~11

[0165] Embodiment 8~11 (manufacture of organic electroluminescence device)

[0166] In Examples 8 to 11, the compounds (125), (129), (128), and (152) described in Table 1 were used instead of TBDB as the hole transport material, and the same operation was carried out to produce Electromechanical Luminescent Devices. For the obtained organic electroluminescence device, the measurement data of the emission color, half-life and driving voltage are shown in Table 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention provides a biphenyl tetramine compound and an organic light-emitting device. The biphenyl tetramine compound is good in charge transfer performance, long in time luminescence, large in conjugation area, easy to prepare, low in cost and capable of being well applied to the technical field of organic light-emitting devices, and the service life of the device can be prolonged, and the efficiency of the device can be improved.

Description

technical field [0001] The invention relates to the technical field of organic photoelectric materials, in particular to a biphenyltetramine compound and an organic electroluminescence device thereof. Background technique [0002] Organic light-emitting devices (organic light-emitting devices), referred to as OLED, is an all-solid-state flat-panel display technology developed in the 1980s. Organic electroluminescence refers to the phenomenon that organic semiconductor materials emit light through carrier injection, transport, recombination to form excitons and exciton decay under the drive of an electric field. In organic electroluminescent devices, the function of the hole transport layer is to improve the transport efficiency of holes in the device and block electrons in the light-emitting layer to achieve the maximum recombination of carriers. The hole transport layer can reduce the energy barrier of holes during the injection process, increase the hole injection efficie...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & AuthorityApplications(China)
IPC IPC(8): C07D307/66C07D333/36C07D307/82C07D333/66C07D307/79C07D333/54C07D409/14C07D307/91C07D333/76C07C211/61H01L51/50H01L51/54
CPCC07D307/66C07D333/36C07D307/82C07D333/66C07D307/79C07D333/54C07D409/14C07D307/91C07D333/76C07C211/61C07C2603/18H10K85/615H10K85/653H10K85/655H10K85/631H10K85/636H10K85/633H10K85/6576H10K85/6574H10K50/15H10K50/17
Inventor邵钰杰董秀芹苗玉鹤孙月
OwnerCHANGCHUN HYPERIONS TECH CO LTD