A kind of transparent polyimide film with excellent performance and preparation method thereof
A transparent polyimide and polyimide film technology, applied in the field of organic film manufacturing, can solve the problem of poor surface wettability and adhesion of polyimide film, unfavorable polyimide film coating, Bonding and cleaning, easy failure and other issues
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Embodiment 1
[0045] (1) Add 180g of N,N-dimethylacetamide solvent to a 500ml three-necked round bottom flask equipped with a nitrogen inlet and mechanical stirring, and then add 0.3mol of diamine A: 4,4'-diaminodiphenyl ether , 0.4mol diamine B: 1,4-cyclohexanediamine and 0.3mol diamine C: 4,4'-diamino-2,2'-ditrifluoromethyl-1,1'-biphenyl, the The mixture was stirred at room temperature to dissolve the diamine and obtain a clear solution, then slowly added 0.5 mol dianhydride A: 4,4-hexafluoroisopropylphthalic anhydride, 0.5 mol dianhydride B: 1,2,4, 5-cyclohexanetetracarboxylic dianhydride reacts with diamine, continues to add 0.015mol 4,4-hexafluoroisopropyl phthalic anhydride to end-capping, and then stirs the mixture in an ice-water bath for 24 hours to obtain a viscosity of 2000poise of polyamic acid solution, then add 0.0012mol trometamol and 0.0006mol D-glucosamine, mix well to obtain polyamic acid solution.
[0046] (2) Stir the polyamic acid solution obtained in step (1) with 0.0...
Embodiment 2-6
[0048] The difference from Example 1 is that the amount of some compounds in Examples 2-6 is different from that in Example 1, as shown in Table 1, and the rest are the same.
[0049] Table 1.
[0050]
Embodiment 7-11
[0052] The difference from Example 1 is that the types of some compounds in Examples 7-11 are different from those in Example 1, as shown in Table 2, and the rest are the same.
[0053] Table 2.
[0054]
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