This invention relates to the field of
ion sieve technology, providing a
titanium-based
lithium-
ion adsorbent, its preparation method, and its applications. The invention involves pyrolyzing NH2-MIL-125(Ti), then mixing it with
lithium carbonate for
calcination, granulating it using an
ethylene-
vinyl alcohol copolymer as a binder, and finally
acid washing to obtain the
titanium-based
lithium-
ion adsorbent. This invention integrates
metal-organic framework (MOF)-derived carbon intercalation,
nitrogen doping, and
polymer-assisted
granulation into a
single process, preparing a particulate adsorbent with a
hierarchical porous structure, strong hydrophilicity, and abundant active sites, showing great potential for industrial applications. Example results show that the adsorbent of this invention, under conditions of pH=12 and 25℃, exhibits a high Li-ion concentration of 24 h. + The adsorption capacity reached 33.95 mg / g. After five cycles of adsorption and
desorption, the adsorption capacity could still reach 96.9% of the initial adsorption capacity, and the
titanium dissolution loss in each cycle was only about 0.4%.