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A kind of preparation method of carbon nanotube reinforced aluminum alloy semi-solid slurry

A semi-solid slurry and carbon nanotube technology, which is applied in the field of metal material manufacturing, can solve the problems of pollution and corrosion of molten metal, expensive stirring equipment, magnetic leakage, etc., and achieves uniform secondary phase distribution, stable process and safe operation. Effect

Active Publication Date: 2022-05-20
NANCHANG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the mechanical stirring method has the following disadvantages: the molten metal is easily polluted and corroded by the stirrer, and there is a blind zone of stirring, resulting in insufficient uniformity of the slurry, and the stirring process is easy to get involved in gas and inclusions, which in turn affects the quality of the semi-solid billet
Among them, the electromagnetic stirring method has the following disadvantages: the stirring equipment is relatively expensive, the electromagnetic gap of the device is large, and the magnetic flux leakage is serious, and part of the energy cannot be used for stirring the metal melt, which greatly increases the production cost.
Among them, the strain-induced melt activation method has the following disadvantages: an additional pre-deformation process is required, the cost is increased, and the size of the prepared semi-solid green body is small
The near-liquidus method has the following disadvantages: the preparation cycle is long, and it is difficult to accurately control the pouring temperature of the melt

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A method for preparing carbon nanotube reinforced aluminum alloy semi-solid slurry, comprising the following steps:

[0031] (1) Mix an appropriate amount of carbon nanotubes with an outer diameter of 20-60nm, a length of 10-30μm, and a purity of ≥99.5% with absolute ethanol in a beaker, mixing 3.0g of carbon nanotubes per 100ml of ethanol, and then put them into an ultrasonic Perform ultrasonic dispersion treatment in the instrument for 120min, the ultrasonic power is 450W, and the frequency is 40kHz; the purity is ≥99.9%, the particle size is 100-200 mesh aluminum powder, potassium tetrafluoroaluminate powder and absolute ethanol are mixed in a beaker at a rate of 150ml of ethanol 45g of aluminum powder and 3.0g of potassium tetrafluoroaluminate were mixed by mechanical stirring for 120min at a stirring speed of 120r / min; then, the mixed and dispersed aluminum powder-tetrafluoroaluminate was evenly added to the carbon nanotube ethanol dispersion after ultrasonic Conti...

Embodiment 2

[0039] A method for preparing carbon nanotube reinforced aluminum alloy semi-solid slurry, comprising the following steps:

[0040] (1) Mix an appropriate amount of carbon nanotubes with an outer diameter of 20-60nm, a length of 10-30μm, and a purity of ≥99.5% with absolute ethanol in a beaker, mixing 2.5g of carbon nanotubes per 100ml of ethanol, and then put them into an ultrasonic Perform ultrasonic dispersion treatment in the instrument for 100min, the ultrasonic power is 400W, and the frequency is 35kHz; the purity ≥ 99.9%, the particle size is 100-200 mesh aluminum powder, potassium tetrafluoroaluminate powder and absolute ethanol in a beaker at a rate of 150ml of ethanol solution Mix 40g of aluminum powder and 2.5g of potassium tetrafluoroaluminate for 100min by mechanical stirring at a stirring speed of 100r / min; then add the mixed and dispersed aluminum powder-tetrafluoroaluminum evenly into the carbon nanotube ethanol dispersion after ultrasonic Continue to ultrasoni...

Embodiment 3

[0048] A method for preparing carbon nanotube reinforced aluminum alloy semi-solid slurry, comprising the following steps:

[0049] (1) Mix an appropriate amount of carbon nanotubes with an outer diameter of 20-60nm, a length of 10-30μm, and a purity of ≥99.5% with absolute ethanol in a beaker with 3.5g of carbon nanotubes per 100ml of ethanol, and then put them into an ultrasonic Perform ultrasonic dispersion treatment in the instrument for 150min, the ultrasonic power is 480W, and the frequency is 45kHz; the purity ≥ 99.9%, the particle size is 100-200 mesh aluminum powder, potassium tetrafluoroaluminate powder and absolute ethanol are mixed in a beaker at a rate of 150ml of ethanol 50g of aluminum powder and 3.5g of potassium tetrafluoroaluminate were mixed by mechanical stirring for 150min at a stirring speed of 140r / min; then, the mixed and dispersed aluminum powder-tetrafluoroaluminate was evenly added to the carbon nanotube ethanol dispersion after ultrasonic Continue t...

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Abstract

The invention provides a method for preparing carbon nanotube reinforced aluminum alloy semi-solid slurry, which belongs to the technical field of metal material manufacturing. A method for preparing carbon nanotube reinforced aluminum alloy semi-solid slurry, comprising the following steps: under the condition of melting and casting, after refining Al-Mg-Si alloy to remove slag, under argon protection state, use a bell jar to place Al-CNTs ‑KAlF 4 The intermediate prefabricated block is pressed into the alloy melt, and 2.1-3.2kW high-energy ultrasound is applied during the addition process, and then the temperature is quickly lowered to 610-650°C for heat preservation, and a second high-energy ultrasound is performed for a short time, followed by rapid water quenching. A semi-solid structure with uniform spheroidization is obtained under the process conditions. The invention is safe in operation and stable in process. The structure of the prepared semi-solid slurry is obviously finer than that of the matrix structure without adding the intermediate prefabricated block under the same conditions. The interface between the carbon nanotube and the alloy matrix is ​​well combined, and the distribution of the secondary phase is also more uniform. .

Description

technical field [0001] The invention belongs to the technical field of metal material manufacture, and in particular relates to a preparation method of carbon nanotube reinforced aluminum alloy semi-solid slurry. Background technique [0002] In recent years, a green and low-carbon lifestyle has been vigorously advocated, and scientific exploration is also trying to find a breakthrough in green development. At present, cars are becoming more and more personalized, and additional devices further increase the weight of the car body. Therefore, lightweight parts are an inevitable choice for car companies to achieve the goals of reducing body weight and exhaust emissions. For this reason, more and more body parts are gradually replaced by aluminum alloy parts, such as cylinder blocks, cylinder heads, wheels, transmission housings and other shell parts, as well as body panels such as doors, engine covers, and roof covers. However, pure aluminum alloy sometimes cannot fully meet ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/10C22C21/08C22C32/00
CPCC22C1/1015C22C1/1036C22C21/08C22C26/00C22C2026/002C22C2026/008C22C1/12
Inventor 闫洪刘智彬熊俊杰
Owner NANCHANG UNIV
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