Protein synthetic fiber and its production method

A technology for synthetic fibers and manufacturing methods, applied in the direction of cellulose/protein conjugated rayon, etc., can solve the problems of inability to guarantee fiber quality, trouble, protein loss, etc. The effect of mutual solubility

Inactive Publication Date: 2005-08-31
李官奇
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In the application document with the patent application number 02101961.4, a method for producing protein synthetic fiber spinning dope is disclosed. In this application, the spinning dope contains plant protein and animal protein, which adds new raw materials to the resources for producing fibers. , but what is disclosed in this document is only a kind of spinning stock solution, which is an intermediate product in the production of fibers, and cannot be directly used by people, and although the solution contains two kinds of proteins and polyvinyl alcohol, However, due to the narrow range of the two protein ingredients, the natural resources for making fibers cannot be fully utilized. In addition, in this application, the ratio of vegetable protein to animal protein must be close, and in the process of making the spinning stock solution, the two These proteins and polyvinyl alcohol are dissolved separately to make a solution, and then they are blended, and a variety of additives need to be added, which not only adds trouble to the liquid preparation work, but also increases the cost. And detrimental to product quality, because the solution that is used to dissolve protein in this application is mainly sodium sulfite aqueous solution, so when adopting the spinning process of vinylon for this spinning solution, part protein loss will be in the coagulation bath, thus Fiber quality cannot be guaranteed

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment 1: Add the alkaline solution that the pH value is 9.6 to the soya bean that soaks in water and grind by wet method, dissolve under the condition that temperature is 29 ℃, material-water ratio is 1: 15, and dissolution time is 180 minutes, put Add gelatin to an alkaline solution with a pH value of 9.6, and dissolve it at a temperature of 28°C. The ratio of material to water is 1:40, and the dissolution process takes 240 minutes. The dissolution process should be stirred, then allowed to stand and separated to remove waste residue. To obtain the leachate, add hydrochloric acid in the leachate, adjust the isoelectric point of the leachate to obtain the isolated protein; the prepared plant protein isolate and animal protein isolate are dissolved in triethanolamine-containing triethanolamine with a pH value of 12 at a dry solid weight ratio of 1:29 In the aqueous solution, the initial temperature of dissolution is 30°C, then heated to 91°C, then the temperature is ...

Embodiment 2

[0025] Example 2: Put the crushed and defatted soybeans and cheese protein into a solution with a pH value of 7.8, and dissolve them at a temperature of 28°C. The dissolution time is 120 minutes. The dissolution process should be stirred, and then allowed to stand , separate and remove the waste residue to obtain leachate, add phosphoric acid in the leachate to adjust the isoelectric point to obtain isolated protein, and dissolve the two isolated proteins in a solution containing triethanolamine with a pH value of 1.5 at a ratio of 5:21. The temperature is 40°C, then heated to 95°C, and kept at 95°C for 20 minutes to make a protein solution with a concentration of 5% As; add polyvinyl alcohol (PVA) that has been washed into the protein solution, Make it blend and copolymerize at a temperature of 95°C, raise the temperature to 98°C and keep it for 60 minutes to make a spinning solution containing animal and vegetable protein and polyvinyl alcohol, and adjust the solution to a co...

Embodiment 3

[0027] Embodiment 3: Put the degreased cottonseed meal into a solution with a pH value of 9.5, and dissolve it at a temperature of 29.5°C. The ratio of material to water is 1: 15, and the dissolution time is 70 minutes. The dissolution process should be stirred. Then stand still, separate and remove the waste residue to obtain leachate, add phosphoric acid in the leachate to adjust the isoelectric point, obtain plant protein isolate, add shellac in the alkaline solution with a pH value of 10, the ratio of material to water is 1: 15, at temperature Dissolve under the condition of 29.5°C, the dissolution time is 100 minutes, the dissolution process should be stirred, and then stand still, separate and remove the waste residue to obtain the leachate, add phosphoric acid to the leachate, adjust the isoelectric point of the leachate to obtain animal protein isolation; separate the plant Protein and animal protein isolate are dissolved in a solution containing triethanolamine with a ...

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PUM

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Abstract

The present invention discloses a protein synthetic fibre. It is formed from plant protein, animal protein and polyvinyl alcohol. The ratio of total weight of two proteins in fibre weight is: from 1% to less than 20% to from 20% to 40% of from greater than 40% to 99%, the rest is polyvinyl alcohol, and when the ratio of total weighto f two proteins in the fibre weight is from 20% to 40%, the ratio of one of them in the total weight of proteins is from 1% to 25% or from 75% to 99%. It also discloses the production method of said fibre. The fibre is good in breathable moisture permeability, and has the flexible and good dermophilic property of cashmere.

Description

technical field [0001] The invention belongs to textile materials, and in particular relates to synthetic fibers composed of vegetable protein, animal protein and polyvinyl alcohol, and also relates to a manufacturing method of the synthetic fibers. Background technique [0002] It is known that the fiber containing protein is except natural silk, and Japan has disclosed a kind of information of separating protein from milk to produce synthetic silk in the journal of fiber protein chemistry. This product expands the source of production fiber, in order to further expand the fiber Production, and on the basis of ensuring the good performance of fiber products, the inventor once disclosed a kind of synthetic fiber by plant protein and the manufacturing method of the fiber in the patent "99116636.1", and in the patent application document with the application number 02109966.9 Disclosed is a synthetic fiber having a different plant protein content than the prior application and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F8/02
Inventor 李官奇
Owner 李官奇
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