Latex formulations with reduced yellowing
A kind of latex and formula technology, applied in the field of non-yellow latex formula
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example 1
[0073] Example 1: Single acrylic latex seeded with polystyrene
[0074] A reaction flask with a volume of 2 L was equipped with a mechanical stirring device, a reflux condenser, a thermometer and an inlet, and contained water (870 mL), latex seed crystals (68 g of a 33% by weight polystyrene emulsion), and Rhodapon SLS (15 grams of 33% (percentage by weight) hydration solution); Rhodapon SLS is a kind of sodium lauryl sulfate surfactant produced by Rhone-Planck, adding APS initiator (3 gram of initiator dissolved in 15 ml of water). After waiting 5 minutes, a mixture of 2-EHA (59.8 grams), MMA (150 grams), MAA (13 grams) and AAEM (25.7 grams) was added to the stirred reaction mixture at a rate of about 3.8 grams / minute. Aqueous ammonium hydroxide (1.03 g ammonium hydroxide dissolved in 33 mL water) was then added to the stirred reaction mixture over an additional 5 minutes. The reaction mixture was then stirred at 80°C for 15 minutes, and MMA (36.3 grams), 2-EHA (155.2 gram...
example 2
[0075] Example 2: Single acrylic latex with MMA seeds
[0076] A reaction flask with a volume of 2 liters was equipped with a mechanical stirring device, a reflux condenser, a thermometer and an inlet. Water (870 ml), latex seeds (68 grams of 33% (weight percent) MMA emulsion) and Rhodapon® were contained in the flask. SLS brand surfactant (15 grams of 33% (weight percent) hydration solution) was added at 80° C. with APS initiator (3 grams of initiator dissolved in 15 milliliters of water). After waiting 5 minutes, a mixture of 2-EHA (59.8 grams), MMA (150 grams), MAA (13 grams) and AAEM (25.7 grams) was added to the stirred reaction mixture at a rate of about 3.8 grams / minute. Aqueous ammonium hydroxide (1.03 g ammonium hydroxide dissolved in 33 mL water) was then added to the stirred reaction mixture over an additional 5 minutes. The reaction mixture was then stirred at 80°C for 15 minutes, and MMA (36.3 grams), 2-EHA (155.2 grams), 1,6HDDA ( 11.0 g) and AAEM (7.53 g). ...
example 3
[0077] Example 3: Latex with polystyrene seeds and MMA outer layer
[0078] A reaction flask with a volume of 2 L was equipped with a mechanical stirring device, a reflux condenser, a thermometer and an inlet, and contained water (870 mL), latex seed crystals (68 g of a 33% by weight polystyrene emulsion), and Rhodapon(R) SLS brand surfactant (15 grams of 33% by weight hydrated solution) was added with APS initiator (3 grams of initiator dissolved in 15 ml of water) at 80°C. After waiting 5 minutes, St (24.6 grams), 2-EHA (59.8 grams), MMA (125.5 grams), MAA (13 grams) and AAEM (25.7 grams) mixture. Aqueous ammonium hydroxide (1.03 g ammonium hydroxide dissolved in 33 mL water) was then added to the stirred reaction mixture over an additional 5 minutes. The reaction mixture was then stirred at 80° C. for 15 minutes, and St (36.3 grams), 2-EHA (155.2 grams), 1,6HDDA ( 11.0 g) and AAEM (7.53 g). After the addition was complete, the reaction mixture was stirred for 15 minut...
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