Solar water heater phase change heat storage material and its preparing method

A technology of phase-change heat storage materials and solar water heaters, which is applied in the field of solar heat storage materials, can solve the problems that the amount and time of solar energy cannot be well matched and coordinated, the density of water heat storage energy is low, and solar energy is not enough. Effects of small volume and cost, high latent heat of phase change, and small volume change of phase change

Inactive Publication Date: 2006-08-23
NANJING UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the supply and demand of solar energy cannot be well matched and coordinated in terms of quantity and time, a large amount of energy is wasted
For example, excess solar energy during the day causes solar energy to be wasted in vain, and solar energy is not enough at night and in rainy days
Moreover, in solar water heaters, the water heat storage energy storage density is low, the volume is large, and the energy storage efficiency is poor.
At present, there is no efficient and stable phase change heat storage material that can make solar energy available on demand

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A phase change heat storage material for solar water heaters according to the present invention, which is mixed according to the following mass percentages: sodium acetate trihydrate is 89%, barium hydroxide octahydrate is 4%, sodium borate decahydrate is 4% It is 2%, zinc acetate is 1%, sodium dodecylbenzene sulfonate is 2%, and gelatin is 2%.

[0024] During preparation, the mixture mixed in the above proportion is heated to a completely molten state and uniformly stirred to form a eutectic mixture, and finally the eutectic mixture is packaged in a solar water heater heat storage device. The phase transition temperature is 57.2℃ and the latent heat of phase transition is 243.8kJ / kg.

Embodiment 2

[0026] Another phase change heat storage material for solar water heaters according to the present invention, which is mixed according to the following mass percentages: 82% sodium acetate trihydrate, 7% barium hydroxide octahydrate, boric acid decahydrate Sodium is 3%, zinc acetate is 2%, sodium dodecylbenzene sulfonate is 3%, and gelatin is 3%.

[0027] During preparation, the mixture mixed in the above proportion is heated to a completely molten state and uniformly stirred to form a eutectic mixture, and finally the eutectic mixture is packaged in a solar water heater heat storage device. The phase transition temperature is 52.8℃ and the latent heat of phase transition is 220.6kJ / kg.

Embodiment 3

[0029] Another phase change heat storage material for solar water heaters according to the present invention, which is mixed according to the following mass percentages: 85% of sodium acetate trihydrate, 5% of barium hydroxide octahydrate, and boric acid decahydrate Sodium is 1%, zinc acetate is 4%, sodium dodecylbenzene sulfonate is 1%, and gelatin is 4%.

[0030] During preparation, the mixture mixed in the above proportion is heated to a completely molten state and uniformly stirred to form a eutectic mixture, and finally the eutectic mixture is packaged in a solar water heater heat storage device. The phase transition temperature is determined to be 55.3℃, and the latent heat of phase transition is 232.2kJ / kg.

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Abstract

The present invention discloses a kind of phase change heat storing material for solar water heater and its preparation process. The phase change heat storing material consists of sodium acetate trihydrate 80-90 wt%, barium hydroxide octahydrate 1-10 wt%, sodium borate decahydrate 1-5 wt%, zinc acetate 1-5 wt%, sodium dodecyl benzene sulfonate 1-5 wt% and gelatin 1-5 wt%. During the preparation, the mixture of the above said materials are heated to smelt completely to form the eutectic mixture, which is mounted inside solar water heater. The phase change heat storing material for solar water heater has phase change temperature fitting the operation temperature of solar water heater, high phase change latent heat, no overcooling and phase separation, no toxicity, no corrosion, stable performance and high repeatability, and is especially suitable for use in solar water heater.

Description

1. Technical Field [0001] The invention relates to a solar heat storage material, in particular to a phase change heat storage material for solar water heaters and a preparation method thereof. 2. Background technology [0002] Energy saving and environmental protection are the most important topics in the field of energy utilization. Using the latent heat of phase change materials for energy storage is a new type of environmental protection and energy saving technology. In the process of its own phase change, the phase change material absorbs heat from the environment and releases heat to the environment when needed, so as to achieve the purpose of controlling the temperature of the surrounding environment and saving energy. It has broad application prospects in solar energy utilization, heat recovery, refrigeration and air conditioning, building energy saving, aerospace and other fields. [0003] Since the reform and opening up, my country's overall national strength and people...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K5/06F24J2/48
CPCY02E10/40
Inventor 方贵银邢琳杨帆李辉
Owner NANJING UNIV
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