Magnet powder, and method for preparing magnet by using the powder
A technology of magnets and powders, applied in the direction of magnetism of inorganic materials, can solve the problems of high magnetic field strength requirements, increased equipment load, difficulty in control, etc., to achieve high sintering density and orientation, reduced raw material costs, and low purity requirements.
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specific Embodiment 1
[0059] This embodiment has a ferrite main phase of the following molecular formula:
[0060] (M 1-x A x )O·n(Fe 1-y D. y ) m o 3 ,
[0061] Wherein M is at least one element in strontium and barium;
[0062] A is at least one element of rare earth elements and bismuth, and A must contain lanthanum;
[0063] D is at least one element among cobalt, manganese and zinc, and D must contain cobalt;
[0064] x, m, n, y represent molar ratios, satisfying x=mny, and x=0.1-0.4, m=1.93-2.00, n=6.2-6.4.
[0065] refer to Image 6 , Figure 8 , Figure 9 , Different values of x, m, and n have different effects on Br and Hcj when the ferrite used is sintered at 1223°C and 1230°C. Among them, when x=0.25-0.35, m=1.95-1.97, and n=6.3, Br and Hcj have relatively high values. Therefore, x=0.25-0.35, m=1.95-1.97, and n=6.3 are the optimum values of x, m, and n.
[0066] For the sintering of the magnetic powder with the above ferrite main phase molecular formula into ferrite, th...
specific Embodiment 2
[0081] The present embodiment selects raw material with embodiment 1. The manufacturing method is characterized by: in,
[0082] When weighing, measure according to (Srl-xLax)0·6.3(Fel-yCoy)mO3. Where x=0.3, so the metering formula is (Sr0.7La0.3)O·6.3(Fe 1-y D. y ) m o 3 .
[0083] Adjust m, and weigh the experiment according to m=1.93, 1.95, 1.97, 2.00 respectively, and y is calculated by formula x=mny.
[0084] In the fine grinding process, put the coarse powder into a ball mill, add water and other additives, and finely grind until the average particle size is about 0.73 microns.
[0085] The highest sintering temperature of the product is 1223°C and 1237°C. The magnetic properties of the resulting product are as Figure 8 shown. It can be seen from the figure that when m=1.95-1.97, Br and Hcj have relatively high values. All the other processing steps are identical with embodiment 1.
specific Embodiment 3
[0086] The characteristics of this embodiment are: in the manufacturing method, the selected raw materials are the same as those in Embodiment 1.
[0087] When weighing, adjust the molar ratio n, weigh the experiment respectively by n=6.2, 6.3, 6.4, x=0.3,
[0088] m=1.97, y is calculated by the formula x=mny, and the molecular formula for measurement is:
[0089] (Sr 0.7 La 0.3 )O·n(Fe 1-y D. y ) 1.97 o 3 .
[0090] Grind the end face of the fired magnet block and test the magnetic properties. The highest sintering temperature of the product is 1220°C and 1229°C, and the magnetic properties of the product are as follows: Figure 9 shown. It can be seen from the figure that when n=6.3, Br and Hcj have relatively high values.
[0091] In other embodiments of the present invention, the ferrite main phase having the following molecular formula:
[0092] (M 1-x A x )O·n(Fe 1-y D. y ) m o 3 ,
[0093] Wherein M can also select barium element;
[0094] A can choos...
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