Thermoplastic resin composition and its preparation method
A technology of thermoplastic resins and compositions, applied in the direction of nanotechnology, nanotechnology, nanotechnology, etc. for materials and surface science, capable of solving undetermined problems
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[0019] (1) The preparation method of the thermoplastic resin composition involved in this embodiment includes: step (a), mixing carbon nanofibers in an elastomer containing unsaturated bonds or groups that have affinity for carbon nanofibers and Disperse the composite elastomer by shearing force to form a composite elastomer; and step (b) kneading the composite elastomer and the thermoplastic resin.
[0020] (2) The preparation method of the thermoplastic resin composition involved in this embodiment includes: step (c), mixing the thermoplastic resin with an elastomer containing unsaturated bonds or groups that have affinity for carbon nanofibers; And in step (d), the mixture of the thermoplastic resin and the elastomer is mixed with carbon nanofibers and dispersed by shearing force.
[0021] The thermoplastic resin composition involved in this embodiment includes: a matrix containing a thermoplastic resin and an elastomer; and carbon nanofibers, the carbon nanofibers are disperse...
Embodiment
[0082] Hereinafter, embodiments of the present invention will be described in detail, but the present invention is not limited to this.
[0083] (1) Preparation of samples of Examples 1 to 6
[0084] Process (a):
[0085] Put the amount of elastomer shown in Table 1 into a 6-inch open mill roll (roll temperature 10-50°C), wind it on a roll with a roll gap of 1mm, put and mix carbon nanofibers into the elastomer, and put the roll Adjust the gap to 0.1mm and perform 5 thin-layer passes to obtain a composite elastomer in which carbon nanofibers are dispersed in the elastomer. The roller rotation speed was set to 22 rpm / 20 rpm.
[0086] Process (b):
[0087] The composite elastomer was wound on a 6-inch open-rolling roll with a heated hot roll, the thermoplastic resin in the amount shown in Table 1 was put in and mixed, and the thermoplastic resin with a thickness of 1.2 mm was extruded in a sheet form. At this time, the heat roller temperature was set to 180°C in Examples 1, 2, 5, an...
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