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Wood preservative and method for producing same

a preservative and wood technology, applied in the field of biocidal compositions, can solve the problems that copper compounds alone cannot be used as wood preservative treatments, and achieve the effect of reducing the number of dissolved compounds

Inactive Publication Date: 2019-08-15
KOPPERS PERFORMANCE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0019]The prepared micronized penflufen compositions are stable under high-shear mixing and subject to multiple pressure treatments. In addition, the milled penflufen particles can be mixed with compositions containing copper compounds and the mixture of penflufen / copper is also stable under high shear mixing and subject to multiple pressure treatment. Upon storage, the mean particle size, the d95 and the d50 of the prepared penflufen compositions remain stable from the first month to the sixth month.

Problems solved by technology

Compositions comprising copper compounds alone, however, cannot be used as wood preservative treatments because the presence of copper-tolerant fungi in wood prevents such compositions from being effective.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0093]The synergism was determined using a modified method as described by Kull et al. (Applied Microbiology, 1961 (9): 538-541). The modified method is described as below:

QA / Qa+QB / Qb=SI

Where:

[0094]Qa=concentration of substance A alone which controls a particular decay fungus

Qb=concentration of substance B alone which controls a particular decay fungus

QA=concentration of substance A in the concentration of the A and B mixture at which controls a particular decay fungus

QB=concentration of substance B in the concentration of the A and B mixture at which controls a particular decay fungus

SI=1 means additivity

SI>1 means antagonism

SI<1 means synergism

example 2

ic Activity of a Combination of Copper Fungicide and Penflufen Against Various Wood Decay Brown Rot Fungi

[0095]Wood cubes measuring 19 mm×19 mm×19 mm were prepared from southern pine sapwood. One set of wood cubes were pressured treated with serial treating solutions containing penflufen fungicide. A second set of wood cubes were pressure treated with treating solutions containing the copper fungicide. A third set of wood cubes were pressure treated with treating solutions containing a mixture of the copper and penflufen. The treated wood samples were exposed to various fungi to conduct a laboratory decay resistance test following protocols as described in American Wood Protection Association Standard E10-2015. Before and after exposure to fungi, the wood samples were weighed to determine the weight percent loss. No weight loss means complete control of the fungal attack. The results are reported in Table 1.

TABLE 1Copper Retention inCu to PenflufenBrown Rot FungiWood as Cu in kg / m3R...

example 3

es Treated with Amine Copper and Penflufen Field Efficacy Testing

[0096]Wood stakes measuring 19 mm×19 mm×450 mm were prepared from southern pine sapwood. The wood stakes were treated with treating solutions containing a copper ethanolamine solution and a penflufen emulsion at different ratios varying from copper:penflufen of 5:1 to 200:1. The treated wood stakes were installed in field testing plots such as Gainesville, Fla. and Maunawili, Hi., and both testing locations have been well established to have severe decay hazard. The field stakes were inspected for efficacy against decay fungi and termite annually, and the test were conducted following protocols as described in American Wood Protection Association Standard E7. The annual inspection results from both filed locations indicated that wood stakes treated with copper and penflufen are resistant to decay and termite attack.

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PUM

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Abstract

A synergistic aqueous wood preservative composition comprising a copper compound and penflufen. The copper compounds of the compositions of the invention may be soluble, partially solubilized or micronized particles. The penflufen of the compositions of the invention may be solubilized, emulsified or particulate. The wood preservative compositions of the present invention are surprisingly provided as stable dispersions and confer surprising and unexpected resistance to treated wood and wood products.

Description

[0001]This application is a divisional of U.S. patent application Ser. No. 15 / 840,877, filed Dec. 13, 2017, which claims priority to U.S. Provisional Application No. 62 / 435,504 filed Dec. 16, 2016, and U.S. Provisional Application No. 62 / 437,372 filed Dec. 21, 2016, each of which is incorporated by reference in its entirety herein.FIELD OF THE INVENTION[0002]The present invention relates to biocidal compositions, particularly wood preservative compositions comprising one or more copper compounds and penflufen. More particularly, the invention relates to a method of manufacture of particulate-based biocidal compositions capable of being injected into wood, the biocidal compositions, methods of preserving wood using the compositions, and wood treated with the compositions of this invention.BACKGROUND OF THE INVENTION[0003]Copper compounds are common biocides for the protection of wood or wood products from fungal decay. Compositions comprising copper compounds alone, however, cannot b...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): A01N43/56A01N59/20B27K3/42B27K3/08B27K3/22A01N25/04B27K3/52B27K3/38
CPCA01N43/56A01N59/20B27K3/42B27K3/08B27K3/22A01N25/04B27K3/52B27K3/38B27K2240/20B27K3/005B27K3/007B27K3/0207B27K3/163B27K3/20B27K3/30B27K3/343B27K5/0055B27K3/34
Inventor ZHANG, JUNTHAM, PETERHORTON, JOHN
Owner KOPPERS PERFORMANCE CHEM