The invention discloses a nano Co2O3 / Fe3O4 composite PMS activation catalyst as well as a preparation method and application thereof, and belongs to the technical field of nano catalytic materials. Comprising the following raw materials in parts by weight: 18-36 parts of modified
chitosan, 100-200 parts of a
citric acid solution, 3-7 parts of
cobalt chloride hexahydrate and 4-8 parts of
ferric chloride hexahydrate. According to the prepared catalyst, Fe3O4 and Co2O3 nanoparticles are loaded in a biological carbon material, so that the activation of the
bimetal catalytic PMS is better; the
magnetism of Fe is beneficial to
recovery of the catalyst, so that the cost is reduced;
chitosan is modified, so that the PMS activation efficiency of the catalyst is enhanced; therefore, the prepared catalyst takes
chitosan as a base material, is loaded with Fe and Co and is doped with N and S, has a synergistic effect, is extremely high in PMS activation efficiency, can be recycled through magnetic force, is low in cost and has a remarkable application value in the
water treatment industry.