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34results about How to "Slow down aggregation" patented technology

Silicon-based composite material, preparation method and application thereof

The invention provides a silicon-based composite material, a preparation method and an application thereof. The silicon-based composite material comprises nanometer silicon particles and polyaniline cladding layers cladded on surface of the nanometer silicon particles, and Si-C covalent bonds are formed between the nanometer silicon particles and the polyaniline coating layers. The preparation method of the silicon-based composite material comprises carrying out a diazotization reaction of P-phenylenediamine (H2N-Ar-NH2) in the presence of nitrite under an acidic condition to generate diazonium salts; adding the nanometer silicon particles into a solution of a complete diazotization reaction for a replacement reaction to obtain nanometer silicon precursors with aniline monomers connected to the surfaces of the nanometer silicon particles through the Si-C covalent bonds; adding the nanometer silicon precursors into a microemulsion mixed from an oil phase and a water phase, adjusting a pH value of the solution, adding the aniline monomers; and adding an initiator enabling polymerization of the aniline into the microemulsion for an aniline polymerization reaction, thereby obtaining the silicon-based composite material with polyaniline-cladded nanometer silicon particles. The silicon-based composite material provided by the invention can improve a cladding effect.
Owner:DONGGUAN AMPEREX TECH +1

Preparation method of organic-inorganic hybridized monolithic column

The invention discloses an organic-inorganic hybridized monolithic column as well as a preparation method and an application thereof. The monolithic column comprises a silica gel framework and has a typical reversed phase chromatographic mechanism through introducing octyl. According to the monolithic column, tetraethoxysilane is served as an inorganic monomer, octyltriethoxysilane is served as an organic-inorganic hybridized monomer, a binary porogenic agent Pluronic F127 / lauryl amine is used for substituting for the conventional single porogenic agent-lauryl amine, methanol / water is served as a solvent, hydrochloric acid and lauryl amine are used as acid-base regulators, and the monolithic column is synthesized by adopting a double-step acid-base sol-gel method. The monolithic column obtained by the method is of an ideal double-pore structure, a preparation process is simple and easy to operate, and high column efficiency is obtained. Through utilizing the synthesizing method of the monolithic column, naphthalene is served as an analyte, and the height of the obtained column plate is reduced to 20-30 micrometers from 70-80 micrometers. The hybridized monolithic column can be used for the reversed phase chromatographic separation and enrichment of various hydrophobic substances.
Owner:DALIAN INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Liquid crystal polyester, liquid crystal polyester composition and products made thereof

ActiveCN109749066BGood melt dischargePrevent riotsPolyesterPolymer science
The invention provides a liquid crystal polyester, a liquid crystal polyester composition and products made thereof. In the liquid crystal polyester provided by the present invention, it must contain repeating units derived from aromatic oxycarbonyl (I) and a small amount of aromatic dicarboxylic acid (IV), and may also contain repeating units derived from aromatic dioxy (II) and a repeating unit (III) derived from an aromatic dicarbonyl group; the molar ratio of the repeating unit composition satisfies the following conditions: the repeating unit (I) derived from an aromatic oxycarbonyl group, the repeating unit (II) derived from an aromatic dioxyl group ) and the repeating unit (III) derived from the aromatic dicarbonyl group and the sum of the three are 100mol%, wherein a small amount of aromatic dicarboxylic acid is introduced in the liquid crystal polyester, so that the excessive molar ratio of carboxyl groups in the liquid crystal polyester is 0.1- 5%, which is calculated by (carboxyl group-hydroxyl group) / hydroxyl group×100mol%; in the present invention, a small amount of excess aromatic dicarboxylic acid is introduced into the liquid crystal polyester preparation process, and the liquid crystal polyester prepared Has excellent anti-foaming properties and good melt discharge.
Owner:KINGFA SCI & TECH CO LTD +1
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