This application discloses a method for preparing low-dust-generating PVDF
masterbatch based on a loaded micro / nano conductive network, specifically disclosing the preparation method as follows:
Transition metal carbides are synthesized in situ on multi-walled carbon nanotubes in a
solid phase, and a
platinum shell is deposited to obtain a conductive
building agent; then, 65%-80% of PVDF resin, 8%-15% of the conductive
building agent, 5%-15% of PMMA-co-PMAA compatibilizer, and 1%-5% of fluorosilicone composite additive are mixed, melt-extruded, and continuously quenched in a constant-temperature water bath at 20℃-25℃ to lock
crystal formation. The resulting PVDF
masterbatch exhibits extremely low particle release, stable electrostatic dissipation, and high rigidity, and its
metal ion precipitation meets the SEMI F57
ion precipitation requirements, making it suitable for ultra-clean equipment such as
semiconductor wafer carriers. This application synthesizes
transition metal carbides in situ on multi-walled carbon nanotubes and coats them with a
platinum shell. The conductive network is locked by the coordination bond between the
platinum shell and the compatibilizer, reducing filler shedding and achieving zero dust generation. A high-efficiency conductive pathway is constructed with a low filler ratio. A rapid cooling
crystal-locking process and fluorosilicone additives are used to balance high rigidity, high rheological properties and mirror-like flatness.