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Method for preparing electro-fused magnesia alumina spinel

A technology of aluminum spinel and fused magnesia, which is applied in the field of preparing fused magnesia aluminum spinel, can solve the problems of environmental pollution and waste of resources, and achieve the effect of reducing environmental pollution

Inactive Publication Date: 2009-02-18
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Except for a small amount of used alumina-magnesia-carbon bricks that are broken and mixed into alumina-magnesia-carbon bricks, a large number of used alumina-magnesia-carbon bricks are piled up like mountains, which wastes resources and pollutes the environment.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0013] A method for preparing fused magnesia-aluminum spinel. The raw material of the preparation method is the used alumina-magnesia-carbon brick, and its chemical composition is: Al 2 o 3 68.12%, MgO 13.96%, and C 8.12%. The used aluminum-magnesium-carbon is placed in an electric arc furnace for electric melting and smelting under the condition of 2000-2600° C., taken out after cooling, crushed and separated to obtain fused magnesium-aluminum spinel.

[0014] According to X-ray diffraction analysis, the main phases are magnesium aluminum spinel and corundum, with a small amount of SiC phase. The analysis result of chemical composition is: Al 2 o 3 83.46%, MgO 14.22%, bulk density 3.35g / cm 3 , The apparent porosity is 4.0%.

Embodiment 2

[0016] A method for preparing fused magnesia-aluminum spinel. The raw material of the preparation method is the used alumina-magnesia-carbon brick, and its chemical composition is: Al 2 o 3 58.81%, MgO 22.46%, and C 9.26%. The used aluminum-magnesium-carbon is placed in an electric arc furnace for electric melting and smelting under the condition of 2000-2600° C., and after cooling, it is taken out, crushed and separated to obtain fused magnesium-aluminum spinel.

[0017] According to X-ray diffraction analysis, the main phases are magnesium aluminum spinel and corundum, with a small amount of SiC phase. The analysis result of chemical composition is: Al 2 o 3 73.62%, MgO 23.61%, bulk density 3.25g / cm 3 , The apparent porosity is 4.5%.

Embodiment 3

[0019] A method for preparing fused magnesia-aluminum spinel. The raw material of this preparation method is mainly used alumina-magnesia-carbon bricks, and its chemical composition is: Al 2 o 3 68.12%, MgO 13.96%, and C 8.12%. Mix 55-65% of the used alumina-magnesia-carbon bricks with 35-45% of bauxite powder according to the weight percentage and place them in an electric arc furnace for electric melting and smelting at 1800-2400°C. After cooling, take them out, crush them, Separate and obtain fused magnesia-aluminum spinel. .

[0020] According to X-ray diffraction analysis, the main phases are corundum and magnesium aluminum spinel, chemical composition analysis: Al 2 o 3 is 91.32%, MgO is 7.85%, and the bulk density is 3.46g / cm 3 , The apparent porosity is 4%.

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Abstract

This invention relates to a method for producing electro-melting magnesium aluminate spinel by applying used Mg-Al carbon bricks. The procedures comprise: mix 45-100wt% used Mg-Al carbon bricks with 0-55wt% bauxite powder and put the mixture in the electric arc furnace for electric melting at 1800-3000Deg C, after cooling pull it out for disintegrating and separating. The main chemical composition of the used Mg-Al carbon bricks at weight ratio is: Al2O3 50-75%, MgO 5-30%, and C 2-20%.This invention applies the C in the used Mg-Al carbon bricks as reducing agent and steel in the used Mg-Al carbon bricks as clarifying agent to remove the impurity oxidate substances like SiO2, Fe2O3 and TiO2 during the melting process, so as to obtain the electro-melting magnesium aluminate spinel. This invention can turn waste to be useful and decrease environmental pollution.

Description

1. Technical field [0001] The invention belongs to the technical field of preparing fused magnesia-aluminum spinel refractory materials. In particular, it relates to a method for preparing fused magnesia-aluminum spinel by utilizing the used alumina-magnesia-carbon brick. 2. Background technology [0002] The iron and steel industry is the industry that consumes the most refractory materials. It accounts for more than 70% of refractory materials. Recently, my country's iron and steel industry has developed rapidly, and it is estimated that it will reach 400 million tons in 2006. Calculated on the basis of 40 kilograms of refractory materials per ton of steel, the annual consumption of refractory materials is about 16 million tons, and the refractory materials that are actually eroded by slag only account for about 35% of the total. That is, about 10 million tons of refractory materials are discarded every year, which not only causes waste of resources, but also pollutes t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B35/443
Inventor 李远兵李亚伟雷中兴蔡鄂汉李楠金胜利洪学勤
Owner WUHAN UNIV OF SCI & TECH