Carrier and developer for electrostatic image development, and image formation method and apparatus
An electrostatic image development, developer technology, applied in the direction of developer, electric recording process applying charge pattern, electric recording process applying charge pattern, etc. and/or the long-term stability of the resistance and the effect of inhibiting adhesion
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no. 1 approach
[0088] The carrier of the first embodiment (carrier particle having a magnetic particle as a core)
[0089] In the carrier of the first embodiment, examples of the core material include: magnetic metals such as iron, steel, nickel, and cobalt; alloys of at least one of these metals with manganese, chromium, and / or rare earth elements (e.g., iron-nickel alloys, cobalt-iron alloys, and aluminum-iron alloys); and magnetic oxides such as ferrites and magnetite. Considering the use of the magnetic brush method as the developing means, the core is preferably magnetic particles.
[0090] In the carrier of the first embodiment, the volume average particle diameter of the core is preferably about 10 μm to about 500 μm. In the first and third to fifth aspects, the volume average particle diameter is more preferably about 30 μm to about 150 μm, still more preferably about 30 μm to about 100 μm. In the second aspect, the volume average particle diameter is more preferably about 20 μm to...
Embodiment 1
[0297] With elbow jet (elbow-jet) equipment (product number: EJ-LABO, produced by Nippon Steel Mining Co., Ltd.), at the classification point of 25 μm and 45 μm, ferrite particles (comprising Cu-Zn, and having 4.5g / cm 3 Density, volume average particle diameter of 35 μm and shape factor SF1 of 125) were classified to remove powder and coarse powder to obtain core particles to be coated.
[0298] For the resulting particle size distribution of the core particles to be coated, the particle size distribution index (D 84v / D 50v ) is 1.18, and the particle size distribution index on the particle side (D 50P / D 16P ) is 1.20, the volume average particle diameter is 37 μm, and the shape factor SF1 is 124.
[0299] 20 parts by mass of a toluene solution (solid content: 15 parts by mass) of a styrene-methyl methacrylate copolymer (weight average molecular weight 80,000) was added to 100 parts by mass of the core particles to be coated. The resulting mixture was stirred for 10 mi...
Embodiment 2 to 4
[0305] Carriers (2) to (4) were produced in the same manner as in Example 1, except that, for the number of repetitions of the powder / coarse powder removal treatment with an elbow spraying device to obtain a resin-coated carrier, From three times to 2 to 5 times. The respective total energies of carriers (2) to (4) are listed in Table 1.
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