Sintered body, light emitting tube and process for manufacturing the same
A manufacturing method and technology of sintered bodies, applied to the manufacture of ships or lead wires, parts of gas discharge lamps, etc., can solve problems such as inapplicability and difficulty in improving productivity
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Embodiment 1
[0121] In this example, an arc tube as a sintered body was produced. The molded body constituting the sintered body was produced by the following method. That is, 100 parts by weight of alumina powder (trade name alumina AES-11C, manufactured by Sumitomo Chemical Industries, Ltd.) as a raw material powder, 0.025 parts by weight of magnesium, 24 parts by weight of dimethylmalonate as a dispersion medium, 2 parts by weight of Bihejul 3100 (trade name, manufactured by Sumitomo Bioretain Co., Ltd.) as a gelling agent, 1 part by weight of Mariarim AKM0351 (trade name, manufactured by NOF Corporation) as a dispersant, and triethylamine as a catalyst 0.2 parts by weight were mixed and used. This slurry was cast at room temperature in an aluminum alloy mold, and then left to stand at room temperature for 1 hour. Next, it was left to stand at 40° C. for 30 minutes to perform curing and demolding. Furthermore, it was left to stand at each temperature of room temperature and then 90°C...
Embodiment 2
[0129] Example 2 An arc tube as a sintered body was produced. The molded body constituting the sintered body was produced by the following method. That is, 100 parts by weight of alumina powder (trade name Alumina AKP-20, manufactured by Sumitomo Chemical Industries, Ltd.) as a raw material powder, 0.025 parts by weight of magnesium, Chemretsu 6080 (trade name, Hodo Keya Ashland Chemical Co., Ltd.) as a dispersion medium Co., Ltd.) 27 parts by weight, 0.3 parts by weight of ethylene glycol, 4 parts by weight of SBU isocyanate 0775 (trade name, manufactured by Sumitomo Bayer Uletan Co., Ltd.) as a gelling agent, and Mariarim AKM0351 (trade name, manufactured by NOF Corporation) as a dispersant Co., Ltd.) 3 parts by weight and 0.1 parts by weight of Kao Laisha No. 25 (trade name, Kao Corporation) as a catalyst were mixed and used. After casting this slurry into the same mold as in Example 1 at room temperature, it was left to stand at room temperature for 1 hour. Next, it was ...
Embodiment 3
[0134] The sintered body A of Example 3 was produced through the same steps as in Example 2 except that the magnesium in the above-mentioned bonding paste was 0.020 parts by weight. When the thermal shock resistance of the sintered body A of Example 3 was evaluated by the quenching method in water, no cracks occurred in the sintered body A of Example 3 even at 150°C. Further, after the thermal shock resistance evaluation of the sintered body A, when the leakage amount of the cylinder part was measured with a He leakage measuring machine, it was 1×10 -8 atm·cc / second or less. In Example 3, the average grain size of the sintered portion of the molded body was 24.3 μm, and the average grain size near the center of the width direction of the sintered portion of the junction was 47.5 μm. The average crystal grain size was 34.1 μm from the center of the width direction of the sintered portion of the junction to the vicinity of a position 150 μm from one side of the sintered portion...
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Abstract
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