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Solvent-type flame-retardant pressure-sensitive adhesive and preparation method thereof

A pressure-sensitive adhesive, solvent-based technology, applied in the direction of adhesive types, ester copolymer adhesives, non-polymer adhesive additives, etc., can solve the problem that the flame-retardant effect of flame-retardant pressure-sensitive adhesives cannot be solved. Guaranteed, low initial adhesion of pressure-sensitive adhesives and other issues, to achieve the effect of uniform fusion and high flame retardant efficiency

Inactive Publication Date: 2011-12-28
BEIJING COMENS NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, acrylic acid is mostly used to prepare flame-retardant pressure-sensitive adhesives, but with the development of water-based polymerization technology of acrylate monomers, the existing technology is more and more focused on the development technology of acrylic series pressure-sensitive adhesives. Be more water-based, which necessarily results in significantly lower initial tack for pressure-sensitive adhesives
Moreover, due to the particle accumulation and film-forming mechanism of the aqueous emulsion, the phase separation between the flame retardant and the latex particles will cause the flame retardant effect of the existing flame retardant pressure-sensitive adhesives to be unguaranteed.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] This embodiment 1 provides a solvent-based flame-retardant pressure-sensitive adhesive, which is composed of a solvent-based pressure-sensitive adhesive and an organic flame retardant blended in a weight ratio of 10:0.5-2.0 ;

[0032] Wherein, the organic flame retardant adopts organophosphorus flame retardant; triphenyl phosphate, trimethyl phosphate, triethyl phosphate, trioctyl phosphate, tris(2-chloroethyl) phosphate, Any one or several of diphenyl 2-ethylhexyl phosphate.

[0033] The solvent-based pressure-sensitive adhesive is composed of acrylate soft monomers, acrylate hard monomers, acrylate functional monomers, organic solvents, oil-soluble initiators and chain transfer agents, and the amount of each component Calculated by weight percentage: 20-35% of acrylate soft monomer, 5-20% of acrylate hard monomer, 0.5-5% of acrylate functional monomer, 42-70% of organic solvent, oil Soluble initiator 0.1-3%, chain transfer agent 0.05-0.5%.

[0034] In the above-men...

Embodiment 2

[0046] This embodiment 2 provides a solvent-based flame-retardant pressure-sensitive adhesive, which is composed of a solvent-based pressure-sensitive adhesive and an organic flame retardant blended in a weight ratio of 10:1; wherein , the organic flame retardant is trioctyl phosphate;

[0047] Among them, the solvent-based pressure-sensitive adhesive is composed of the raw materials in the following table:

[0048] Raw Materials (Solvent Based Pressure Sensitive Adhesives)

weight percentage (%)

2-Ethylhexyl Acrylate

20

ethyl acrylate

10

Methyl acrylate

14

acrylic

1.5

Hydroxyethyl Acrylate

2.0

ethyl acetate

40

toluene

10

Benzoyl peroxide

2.3

dodecanethiol

0.2

[0049] The preparation method of the above-mentioned solvent-based flame-retardant pressure-sensitive adhesive is carried out according to the following steps:

[0050]Preparation o...

Embodiment 3

[0053] This embodiment 3 provides a solvent-based flame-retardant pressure-sensitive adhesive, which is composed of a solvent-based pressure-sensitive adhesive and an organic flame retardant blended in a weight ratio of 10:0.6; wherein , the organic flame retardant is trimethyl phosphate;

[0054] Among them, the solvent-based pressure-sensitive adhesive is composed of the raw materials in the following table:

[0055] Raw Materials (Solvent Based Pressure Sensitive Adhesives)

weight percentage (%)

Butyl acrylate

35

Methyl methacrylate

9

Methacrylate

1.5

Hydroxyethyl Acrylate

2.0

ethyl acetate

45

Xylene

5

Azodiethylbutyronitrile

2.2

dodecanethiol

0.3

[0056] The preparation method of the above-mentioned solvent-based flame-retardant pressure-sensitive adhesive is carried out according to the following steps:

[0057] Preparation of solvent-based press...

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Abstract

The invention discloses a solvent-type flame-retardant pressure-sensitive adhesive and a preparation method thereof, belonging to the field of adhesives. The flame-retardant pressure-sensitive adhesive is composed of a solvent-type pressure-sensitive adhesive and an organic flame retardant blended in a weight ratio of 10:0.5-2.0; wherein, the organic flame retardant is a phosphorus-based flame retardant; The solvent-type pressure-sensitive adhesive is composed of the following components by weight percentage: 20% to 35% of acrylate type soft monomers, 5% to 20% of enolate type hard monomers, 5% to 20% of enolate type functional monomers 0.5-5%, organic solvent 42-70%, oil-soluble initiator 0.1-3%, chain transfer agent 0.05-0.5%. The flame-retardant pressure-sensitive adhesive adopts a solvent system, and the flame-retardant coating in the flame-retardant pressure-sensitive adhesive is selected from a solvent-based coating, and the melting film-forming of the solvent-based coating ensures The flame-retardant pressure-sensitive adhesive itself is more uniform in the film-forming process, making the flame-retardant efficiency of the same amount of flame retardant higher, so that the solvent-based flame-retardant pressure-sensitive adhesive has high initial viscosity and high efficiency. flame retardant effect.

Description

technical field [0001] The invention relates to the field of adhesives, in particular to a solvent-type flame-retardant pressure-sensitive adhesive and a preparation method thereof. Background technique [0002] At present, acrylic acid is mostly used to prepare flame-retardant pressure-sensitive adhesives, but with the development of water-based polymerization technology of acrylate monomers, the existing technology is more and more focused on the development technology of acrylic series pressure-sensitive adhesives. It tends to be more water-based, which inevitably leads to a substantial reduction in the initial tack of the pressure-sensitive adhesive. Moreover, because the particle accumulation and film-forming mechanism of the aqueous emulsion will cause the phase separation of the flame retardant and the latex particles, the flame-retardant effect of the existing flame-retardant pressure-sensitive adhesives cannot be guaranteed. Contents of the invention [0003] Bas...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J133/08C09J11/06C09J9/00
Inventor 李岗沈峰邓煜东
Owner BEIJING COMENS NEW MATERIALS