Delivery particle
A technology for delivering particles and beneficial agents, applied in microcapsule formulations, detergent compositions, chemical instruments and methods, etc.
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Embodiment 1
[0090] Example 1: 50% by weight core / 50% by weight calcium carbonate wall microcapsules
[0091] A 10% dispersion of nano calcium carbonate (Omya UK, Derbyshire, UK) in tap water was prepared. The dispersion was stirred well, the solids were allowed to settle out, and the liquid portion was decanted. Repeat this step until the surface tension of the liquid phase becomes constant. Add 8 grams of benefit agent (fragrance) to 12 grams of the final dispersion and stir well to make an oil-in-water emulsion. Simultaneous titration of 20 mL of 4M calcium chloride solution (Sigma Aldrich, Milwaukee, WI) and 40 mL of 2M sodium carbonate (Sigma Aldrich, Milwaukee, WI) in the oil-in-water emulsion to prepare microcapsules, the rate of calcium chloride was about 1 mL / min, the rate of sodium carbonate was about 2 mL / min. The microcapsules are then decanted from the bulk liquid. Measure this microcapsule according to the test method of this description, and find to have following char...
Embodiment 2
[0093] Example 2: Back titration of 50 wt% core / 50 wt% calcium carbonate wall microcapsules
[0094] 6 mL of carbonate microcapsules from Example 1 were added to 4 mL of calcium chloride solution to form a suspension. The suspension was added dropwise to 20 mL of sodium carbonate. Approximately 70% of the suspension liquid was decanted, and the remaining suspension was added dropwise to 20 mL of calcium chloride solution. The bulk of the liquid was then decanted, leaving a thick suspension of microcapsules. The microcapsules were tested according to Test Method Four (4) "Leakage of Benefit Agents" of this specification and were found to have an average leakage of 0.005%.
Embodiment 3
[0095] Example 3: Interfacial Polymerization of 50 wt% Core / 50 wt% Calcium Carbonate Wall Microcapsules
[0096] 0.005 g of trimesoyl chloride was added to the 8 g of benefit agent and mixed to ensure dissolution. Microcapsules were then prepared according to the method in Example 1, said microcapsules having the following parameters: 50% by weight core / 50% by weight calcium carbonate wall.
[0097] Next, 1 g of diethylenetriamine was dissolved in 20 mL of water to form a solution. This solution was mixed with the aforementioned capsules and stirred gently. The microcapsules were tested according to Test Method Four (4) "Leakage of Benefit Agents" of this specification and were found to have an average leakage of 0.002%.
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