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Water-permeable electrochemical microbial reactive barrier and application method thereof

A microbial reaction and electrochemical technology, applied in chemical instruments and methods, biological water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of increased remediation costs, exhausted reactants, and a lot of power consumption. , to achieve the best effect of pollution control and reduce the cost of remediation costs

Inactive Publication Date: 2014-04-16
NAT CHENG KUNG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, most of the problems with physical methods are not effective, because the nature of pollutants is not the same, so not all pollutants can be removed by the same physical method, and it will consume manpower and material resources to remove the remaining Pollutants
If the chemical oxidation mechanism is used to degrade organic pollutants, there will be a problem that the reactants are exhausted and must be replaced
If it is degraded by a biological mechanism, there will be a problem that a sufficient amount of electron acceptors must be supplied, and a large amount of power must be consumed to supply a sufficient amount, and at the same time, it is easy to cause uneven mass transfer.
Therefore, it is necessary to constantly replenish or add oxidants (electron suppliers for microorganisms), which will inevitably lead to an increase in the cost of remediation

Method used

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  • Water-permeable electrochemical microbial reactive barrier and application method thereof
  • Water-permeable electrochemical microbial reactive barrier and application method thereof
  • Water-permeable electrochemical microbial reactive barrier and application method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031] Embodiment 1: In-situ (on-the-spot) microbial decomposition efficacy test (with electrodes as electron acceptors)

[0032] In this embodiment, benzene is used as the target organic pollutant (concentration is about 350ppm), and the compound microorganisms of polluted soil are used as the source of planting bacteria. In the reaction bottle, the degradation and bioelectric current generation tests are carried out, and the applied voltage is 0.2V vs.Ag / After AgCl, during the experiment, it can be observed that the surface of conductive activated carbon fibers is gradually coated with biofilm.

[0033] The correlation between the presence of benzene and the bioelectric current is as follows: Figure 4 shown. After adding 140ppm of benzene at the beginning of the experiment ( Figure 4 As shown by arrow a), there is no instantaneous current generation (showing that benzene is not directly oxidized by the electrode), and then the current gradually increases, the highest va...

Embodiment 2

[0035] Example 2: Verification experiment of a simulated soil pipe column of a permeable electrochemical microbial reaction wall

[0036] Embodiment two is to carry out the simulation test of the permeable electrochemical microbial reaction wall with soil pipe column in the laboratory, the soil pipe column in the present embodiment is 45 centimeters long, and internal diameter is 3 centimeters, and it comprises one deck conductive activated carbon fiber layer ( Thickness 15 centimeters) and a platinum (Pt) cathode, it is arranged on the adjacent side distance of this conductive activated carbon fiber layer at a distance of 5 centimeters, the experimental process is carried out in a continuous flow mode, and the hydraulic retention time is within 2 days. The simulated pollutants contained in the influent solution are benzene, toluene, ethylbenzene, and p-xylene (BTEX for short), and the test concentrations are about 19524, 15383, 14981, and 7257 ppb, respectively, which are take...

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Abstract

The invention relates to a water-permeable electrochemical microbial reactive barrier and an application method thereof. The water-permeable electrochemical microbial reactive barrier comprises at least a conductive fibrous layer and at least a cathode. The conductive fibrous layer is applied with an appropriate voltage. All traditional chemotype or biotype water-permeable reactive barriers have a problem that an oxidant (electron accepter of microbes) which is depleted needs continuous supplement by replacement or adding of the oxidant. According to the invention, the conductive fibrous layer with high surface area is adopted as the electron accepter of microbes in vitro, so the problem of continuous supplement or replacement of the oxidant of traditional methods is effectively solved. The invention provides the water-permeable electrochemical microbial reactive barrier, and the reactive barrier can be maintained to normally operate by directly attaching relevant pollutant decomposers to the surface of the fibrous layer by in situ microbes to grow, and needing only proper voltage to lead out electrons generated by the biochemical reaction of the in situ microbes without adding applied oxidants.

Description

technical field [0001] The invention is a water-permeable electrochemical microbial reaction wall, in particular a water-permeable electrochemical microbial reaction wall which can effectively decompose organic pollutants without adding any chemical agents to avoid polluting groundwater. Background technique [0002] The so-called reaction wall is one of the measures to prevent pollutants from flowing with groundwater. It is installed in gas stations, oil refineries, and even some petrochemical industrial plants to avoid the spread of groundwater polluted by organic pollutants. Its use is to pollute Such devices are arranged in the vertical direction downstream of the groundwater. [0003] The traditional reaction wall is a permeable reaction wall. Its principle is that when the pollutants flow through the permeable reaction wall, they will be blocked by the permeable reaction wall, and then through physical methods (such as precipitation, etc.), chemical methods (such as O...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F3/34
Inventor 王永福陈威吉洪旭文潘柏岑郑幸雄
Owner NAT CHENG KUNG UNIV
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