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TCE bleaching technology for sulfate pulp of growing poplar by biological chemical method

A kraft pulp and biochemical technology, applied in pulp bleaching, digester, textile and paper making, etc., can solve the problems of high energy consumption for refining, poor whiteness stability, easy yellowing, etc. The effect of saving beating energy consumption and less beating whiteness loss

Active Publication Date: 2013-10-02
QILU UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In recent years, high-yield pulp has developed rapidly, but high-yield pulp has disadvantages such as high energy consumption for refining, low pulp strength, poor whiteness stability, and easy yellowing, which makes it difficult to make some paper products from high-yield pulp. High strength, not easy to yellow, good thermal stability paper

Method used

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  • TCE bleaching technology for sulfate pulp of growing poplar by biological chemical method
  • TCE bleaching technology for sulfate pulp of growing poplar by biological chemical method
  • TCE bleaching technology for sulfate pulp of growing poplar by biological chemical method

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Effect test

Embodiment 1

[0033] Example 1 Process optimization of xylanase treatment of fast-growing poplar kraft pulp

[0034] Xylanase is a specific catalytic protein, which has strict requirements on the environment, that is to say, each enzyme has its specific and most suitable environmental conditions. Xylanase has achieved obvious effects in chemical pulping and bleaching pretreatment. According to relevant literature, the factors affecting xylanase pretreatment mainly include enzyme dosage, temperature, pH value and time, etc. These factors have varying degrees of influence on the effect of oxygen delignification and subsequent bleaching. Among these influencing factors, temperature and pH value are related to the characteristics of xylanase itself, but have relatively little influence on the properties of slurry. In this experiment, by changing the experimental conditions, the most suitable process conditions for pretreatment of fast-growing poplar kraft pulp were discussed with different xyl...

Embodiment 2

[0103] The optimization of embodiment 2 bleaching process conditions

[0104] 2.1.1 Raw materials

[0105] The fast-growing poplar chips used in the experiment were mixed fast-growing poplar chips, which were obtained from Shandong Sun Paper Co., Ltd. The length of the wood chips is 15-25mm, the width is 10-20mm, and the thickness is 3-5mm. The qualified rate of the wood chips is over 90%.

[0106] Xylanase X 1 Provided by Novozymes, liquid, without cellulase activity; xylanase X 2 、X 3 All are provided by Shenzhen Lvweikang Biological Co., Ltd., all are white powdery solids, and none of them contain cellulase activity.

[0107] 2.1.2 Cooking experiment

[0108] Cook in a 15L electric heating rotary cooking pot to obtain the raw material of fast-growing poplar sulfate. The conditions for cooking are: the amount of alkali used is 20% (for absolute dry raw materials, Na 2 O meter), the degree of sulfidation is 24%, the liquid ratio is 1:4, the highest cooking temperature ...

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Abstract

The invention discloses a TCE (Total Chlorine-Free) bleaching technology for sulfate pulp of growing poplar by biological chemical method. The technology comprises the following steps: (1), cooking: getting fast-growing polar pieces; putting the fast-growing polar pieces into a distilling pan for cooking, so as to obtain primary pulp, and then washing and screening the primary pulp to obtain paper pulp; (2), pre-treating the paper pulp with xylanase; (3), TCE bleaching: bleaching the paper pulp pre-treated with the xylanase, wherein the bleaching process is one of OP-Q-P, O1-O2P-Q-P or O1P-O2P-Q-P. According to the TCE (Total Chlorine-Free) bleaching technology for sulfate pulp of growing poplar by biological chemical method, the xylanase is adopted to pre-treat the paper pulp, then one of the bleaching processes OP-Q-P, O1-O2P-Q-P or O1P-O2P-Q-P is adopted for bleaching, so that the paper pulp with higher whiteness and viscosity is obtained; compared with the paper pulp obtained through directly bleaching without xylanase pre-treatment, the paper pulp provided by the invention has the advantages that the loss value of whiteness is lesser, the folding strength is higher 45 times averagely, the bursting index is higher 0.45 N*m*g <-1> averagely, the breaking length is higher 0.35 KM, and the tearing index is quite. The beating revolution number is lesser when the paper pulp reaches the same or similar beating degree, and the 20% of beating energy consumption can be saved approximately.

Description

technical field [0001] The invention relates to a kraft pulp biochemical TCF bleaching process of fast-growing poplar, belonging to the technical field of papermaking. Background technique [0002] Fast-growing poplar is the main tree species used in forestry-paper integration construction in northern my country. It belongs to fast-growing broad-leaved wood. They have fast growth, strong adaptability, high natural whiteness, loose material, good absorption of liquid medicine, and relatively high lignin content. Low, high content of cellulose and hemicellulose, can be used to produce chemical pulp, semi-chemical pulp and mechanical pulp, etc., is one of the main high-quality papermaking raw materials in northern my country. Fast-growing poplar is widely planted in northern Europe, North America and northern my country. It includes many varieties, representative ones are black poplar, triploid poplar, and Zhonglin poplar. The growth characteristics and composition of these fast...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21C9/10D21C9/16D21C7/02
Inventor 吉兴香陈嘉川杨桂花田中建刘玉王鲁燕
Owner QILU UNIV OF TECH
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