Gel electrolyte and preparation method thereof, dye-sensitized battery
A dye-sensitized battery and gel electrolyte technology, which is applied in the field of solar cells, can solve the problems of volatile electrolyte, unstable properties, and low electrical conductivity, and achieve the effects of stable properties, large contact area, and high electrical conductivity.
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Embodiment 1
[0028] This embodiment provides a gel electrolyte and a preparation method thereof.
[0029] The preparation method of the organic conductive film layer comprises the following steps:
[0030] 1) The step of dissolving the solute in the solvent
[0031] The mass ratio of elemental iodine and potassium iodide is 1: 1 to get elemental iodine and potassium iodide as solute, be dissolved in the polycarbonate as solvent and make solution; Wherein, in the solution, I 3 - The concentration of the substance is 0.1mol / L, I - The concentration of the substance is 0.01mol / L.
[0032] 2) Mixing step
[0033] Stir the solution described in step 1) at 80°C for 12 hours, and add gelling agent polyethylene glycol 5000 to form a viscous mixture while stirring; wherein, the mass ratio of solvent to gelling agent is 1:0.25.
[0034] 3) Reaction steps
[0035] Add the viscous mixture described in step 2) into the reactor, and react for 5 hours at 200°C to prepare a gel electrolyte.
[0036...
Embodiment 2
[0039] This embodiment provides a gel electrolyte and a preparation method thereof.
[0040] The preparation method of the organic conductive film layer comprises the following steps:
[0041] 1) The step of dissolving the solute in the solvent
[0042] The mass ratio of elemental iodine and potassium iodide is 1: 10 to get elemental iodine and potassium iodide as solute, be dissolved in the polycarbonate as solvent and make solution; Wherein, in the solution, I 3 - The amount concentration of the substance of is 0.01mol / L, and the amount concentration of the substance of I- is 0.1mol / L.
[0043] 2) Mixing step
[0044] The solution described in step 1) was stirred at 120°C for 20 hours, and a gelling agent polyethylene glycol 10,000 was added while stirring to form a viscous mixture; wherein, the mass ratio of the solvent to the gelling agent was 1:0.5.
[0045] 3) Reaction steps
[0046] Add the viscous mixture described in step 2) into the reactor, and react at 150°C f...
Embodiment 3
[0048] This embodiment provides a gel electrolyte and a preparation method thereof.
[0049] The preparation method of the organic conductive film layer comprises the following steps:
[0050] 1) The step of dissolving the solute in the solvent
[0051] The mass ratio of elemental iodine and potassium iodide is 1: 5 to get elemental iodine and potassium iodide as solute, be dissolved in the polycarbonate as solvent and make solution; Wherein, in the solution, I 3 - The concentration of the substance is 0.05mol / L, I - The concentration of the substance is 0.07mol / L.
[0052] 2) Mixing step
[0053] Stir the solution described in step 1) at 100°C for 36 hours, and add gelling agent polyethylene glycol 20000 while stirring to form a viscous mixture; wherein, the mass ratio of solvent to gelling agent is 1:0.8.
[0054] 3) Reaction steps
[0055] Add the viscous mixture described in step 2) into the reactor, and react at 180°C for 10 hours to prepare a gel electrolyte.
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