Manufacturing technology for low-sulfur activated carbon

A technology of sulfur activated carbon and preparation process, which is applied in the direction of inorganic chemistry, non-metallic elements, carbon compounds, etc., can solve the problems of incomplete removal, lack of analysis and explanation, insufficient technical disclosure, etc., and achieve clean and microscopic sulfur removal. The effect of increasing porosity and improving adsorption performance

Active Publication Date: 2013-11-27
上海正海活性炭有限公司 +1
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Problems solved by technology

Although the invention mentions the obtaining of high-grade flue gas desulfurization activated carbon, the technical disclosure is insufficient, the process and the obtained desulfurization products lack organic connection, lack of analysis and explanation in line with chemical principles, and lack of practicability
[0011] On the web page of China Encyclopedia http: / / www.chinabaike.com / article / 316 / 327 / 2007 / 2007022156712.html, it is introduced that sulfuric acid liquid or hydrochloric acid vapor can be used as a carbonizing agent for wool to remove vegetable cellulose in wool Although the material process can remove trace amounts of sulfur, its technical purpose is not to remove sulfur, nor can it be removed completely.

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  • Manufacturing technology for low-sulfur activated carbon

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Embodiment

[0033] like figure 1 The low-sulfur activated carbon preparation process shown, the specific process is as follows:

[0034] 1. First soak the carbon-containing raw material in ammonium dihydrogen phosphate solution; carry out the carbonization process of smoldering treatment at a temperature of 180 to 360 degrees.

[0035] 2. Desulfurization process: Put the carbonized material in a fluoroplastic container; then, while stirring the carbonized material, mix a mixture of nitric acid with a weight ratio of 20% and a concentration of 60% and hydrochloric acid with a concentration of 30%. (The molar ratio of nitric acid to hydrochloric acid is 2:1) As a desulfurizing agent, it is sprayed into the carbonized material and soaked to oxidize the sulfur element in it; after the carbonized material is soaked in the desulfurizing agent, the sulfur element is oxidized into a water-soluble compound, such as Sulfuric acid, sulfate, rinse twice with soft water, distilled water or deionized ...

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Abstract

The invention provides a manufacturing technology for low-sulfur activated carbon. A desulfuration process, an alkali wash process and a drying process are added in a carbonizing process and an activation process, wherein a desulfurization agent of 10-30% is sprayed into the carbonized material to oxidize the contained sulfur element to a water-soluble compound to be removed through rinsing; an alkali liquor such as ammonia water is adopted for regulation for neutrality, and a drying process is conducted; in the carbonizing process, carbonizing agents such as ammonium dihydrogen phosphate or ammonium chloride can be used for impregnating the carbonized material for carbonizing processing under the working condition of 160-330 DEG C; the desulfurization agent is preferably a blend of nitric acid with concentration of 60-70% and hydrochloric acid with the concentration of 25-37%. The manufacturing technology can effectively remove the sulfur element in the activated carbon, so that the activated carbon has a wider application range and a better effect, the porosity of the activated carbon is increased, and the adsorptive property is remarkably improved.

Description

technical field [0001] The invention relates to a process for preparing activated carbon used in industry. Background technique [0002] To prepare activated carbon, it is necessary to prepare the carbonized material intermediate first. [0003] In the carbonization process for preparing carbonized materials and the activation process for making activated carbon, [0004] The carbon-containing raw materials used to make carbonized materials are generally coal, wood, fruit shells or plant roots. Sulfur is one of the essential nutrients for plants, and it accounts for a few percent of the dry weight of the plant (the way sulfur enters the plant: absorb sulfate from the soil, and transform it into cysteine ​​through biochemical action. Sulfur-containing biomass such as acid and protein; therefore, coal and wood shells from plants all contain sulfur elements). The carbonized raw materials are carbonized through the carbonization process (generally smoldering in isolated air a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/08C01B32/312
Inventor 姚正飞姚海华顾永华其他发明人请求不公开姓名
Owner 上海正海活性炭有限公司
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