Method for producing endoplasmic reticulum
A manufacturing method and vesicle technology, which can be applied to medical preparations without active ingredients, medical preparations containing active ingredients, and pharmaceutical formulas, etc., and can solve the problems of insufficient particle size control and failure to be practical.
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Embodiment 1
[0051] As complex lipids, a total of 10 g of 1,2-dipalmitoyl-sn-glycero-3-phosphatidylcholine (DPPC), cholesterol, 1,5-O-dicetyl-N-succinyl -glutamic acid (DHSG), and 1,2-distearoyl-sn-glycerol-3-phosphatidylethanolamine-N-polyethylene glycol 5000 (DSPE-PEG5000, the molecular weight of the PEG chain is 5000) according to mole The ratio was 5 / 4 / 0.9 / 0.03, dissolved in 1 dL of tert-butanol, and poured into a 0.5 L eggplant-type flask. Next, freezing was carried out in a dry ice / methanol mixed cooling medium, and it was carried out for 24 hours in a freeze-drying apparatus (FD-1000 manufactured by Tokyo Rika Co., Ltd.) to obtain a composite lipid powder. 10 g of this powder was put into a THINKEY CORPORATION cylindrical container made of Teflon (outer diameter: 76 mm, height about 93 mm, inner wall with unevenness, clover shape when viewed from above the container), and high-purity human hemoglobin was added Solution (carbon monoxide binding-HbCO body, 45g / dL, 0.4dL, pH7.4). The...
Embodiment 2
[0059] Using the same lipid species as in Example 1, DPPC / cholesterol / DHSG / DSPE-PEG5000 was dissolved in 1 dL of tert-butanol so that the molar ratio was 5 / 4 / 0.9 / 0.03 and the total lipid weight was 10 g. , added to an eggplant-shaped flask. Next, it was freeze-dried with liquid nitrogen to obtain complex lipid powder. Next, this complex lipid was put into the same Teflon cylindrical container as that used in Example 1, and 0.5 dL of ultrapure water was added thereto. The weight of the negatively charged lipid DHSG was 1.13 g, corresponding to 1.48 m mole, and 0.074 mL of 1N-NaOH solution was added in order to neutralize it with an equivalent amount of NaOH. Then, cover the inner cover and seal it, use a kneading device (rotation and revolution agitator, manufactured by THINKEY CORPORATION, ARE-310) to knead for 5 minutes (revolution 2000 rotations, rotation 800 rotations), after cooling for 5 minutes, carry out again Kneading was performed for 5 minutes, and the treatment wa...
Embodiment 3
[0061] Manufactured by Nippon Fine Chemical Co., Ltd. Dissolve DPPC / cholesterol / DHSG / DSPE-PEG5000 in an organic solvent so that the molar ratio becomes 5 / 4 / 0.9 / 0.03, and use the CRUX method to make the organic solvent Complex lipid powder obtained by rapid evaporation. For 10 g of this complex lipid powder, in the same manner as in Example 1, 0.4 dL of thick hemoglobin solution was added, and a kneading device (autorotation revolution agitator, manufactured by THINKEY CORPORATION, ARE-310, revolution speed 1000 revolutions, rotation speed 400 revolutions) the operation of kneading for 6 minutes and cooling for 3 minutes was repeated 30 times. The temperature rise of the paste stayed around 30°C. All kneading was carried out for 180 minutes. At this stage, the viscosity of the obtained paste was measured at 25°C with a rheometer (MCR-300, manufactured by Anton Paar Co.), and it was about 2200cP (shear rate 1000s -1 , 23℃), about 10000cP (shear speed 100s -1 , 23℃), about 52...
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