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Graphite electrode with a diameter of 348mm and its manufacturing method

A graphite electrode and graphite crushing technology, which is applied in the field of graphite electrodes, can solve the problems of high strength and low porosity

Active Publication Date: 2016-08-31
焦作市中州炭素有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Existing graphite electrodes are far from meeting the requirements of high density, high strength, and low porosity. At the same time, this new type of graphite electrode can also be used as a high-end joint material, providing a new substitute for graphite electrode joints

Method used

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  • Graphite electrode with a diameter of 348mm and its manufacturing method
  • Graphite electrode with a diameter of 348mm and its manufacturing method

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preparation example Construction

[0015] A kind of preparation method of diameter 348mm graphite electrode its preparation method is as follows:

[0016] (1) Calcination: Three kinds of high-quality petroleum cokes from Fushun, Tianjin and Jinzhou are mixed and pre-crushed according to the ratio of 40-60%, 20-30% and 20-30%, and then calcined. Density ≥ 2.08g / ㎝³, powder resistivity ≤ 500μΩm;

[0017] (2) Ingredients: Mix the petroleum coke calcined in step (1) and the domestic needle coke at a ratio of 70-80% and 20-30%, crush and sieve to obtain dry materials of different particle sizes, according to the following weight Percentage composition for batching: 18~25% of mixed petroleum coke with medium particle size of 2~0.5mm, 18~25% of mixed petroleum coke with small particle size below 0.5mm, 48~55% of powder with particle size of 0.074mm, and 5~12% of graphite powder with particle size below 2mm %; Finally, adding 10-25% of the total weight of dry material raw crushed;

[0018] (3) Making raw electrode pro...

Embodiment 1

[0028] The graphite electrode with a diameter of 348 mm in this embodiment is mainly composed of high-quality mixed petroleum coke as raw material of different particle sizes. 18% of petroleum coke, 55% of 0.074mm powder, and 9% of graphite fragments with a particle size of 2mm or less; add 24% of the binder in the dry material, and add 0.3% of stearic acid in the dry material; Add raw ground 10% by total weight of dry ingredients.

[0029] The preparation method of the 348mm diameter graphite electrode of the present embodiment is as follows:

[0030] (1) Calcination: Three kinds of high-quality petroleum cokes from Fushun, Tianjin and Jinzhou are mixed and pre-crushed according to the proportion of 40%, 30% and 30%, and then calcined. Resistivity≤500μΩm;

[0031] (2) Ingredients: Mix the petroleum coke calcined in step (1) and domestic needle coke at a ratio of 70% and 30%, grind and sieve to obtain dry materials of different particle sizes, and mix according to the follow...

Embodiment 2

[0037] The graphite electrode with a diameter of 348 mm in this embodiment mainly consists of high-quality mixed petroleum cokes of different particle sizes as raw materials. The composition of the dry materials is: 25% of mixed petroleum coke with a medium particle size of 0.5 mm, and small particle sizes below 0.5 mm. 18% of mixed petroleum coke, 52% of 0.074mm powder, and 5% of graphite fragments with a particle size of less than 2mm; add 28% of the binder in the dry material, and add 0.5% of stearic acid in the dry material ; Add 25% of the total weight of the dry ingredients raw mince.

[0038] The preparation method of the 348mm diameter graphite electrode of the present embodiment is as follows:

[0039] (1) Calcination: Three kinds of high-quality petroleum cokes from Fushun, Tianjin and Jinzhou are mixed and pre-crushed according to the ratio of 60%, 20% and 20%, and then calcined. Resistivity≤500μΩm;

[0040] (2) Ingredients: Mix the petroleum coke calcined in step...

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Abstract

The invention discloses a graphite electrode with a diameter of 348 mm. Its components are mainly dry materials of different particle sizes made of high-quality mixed petroleum coke as raw materials. The finished product is prepared. The present invention adopts mixed petroleum coke with medium particle size and small particle size, and the mixed petroleum coke with small particle size below 0.5mm is 18~25%. It is more suitable for graphite crucibles, impermeable graphite substrates, etc.; the primary roasting curve is maintained at 400-800°C for 165 hours, and this critical volatilization period is slowed down to prevent the product from cracking due to excessive heating and volatiles that cannot be discharged in time. It has successfully solved the problem that the small particle size powder multi-electrode is easy to crack during the roasting and graphitization heat treatment process, and the yield is low. The pass rate of the first bake and graphitization pass rate of the product reached 98.5% and 99.2% respectively.

Description

technical field [0001] The invention relates to a graphite electrode, in particular to a graphite electrode with a diameter of 348 mm and a production method thereof. Background technique [0002] With the development of science and technology, products need to be constantly upgraded to meet market demand. The market demands more and more for existing graphite electrodes, especially graphite crucibles. The existing graphite electrodes are far from meeting the requirements of high density, high strength, and low porosity. At the same time, this new type of graphite electrode can also be used as a high-end joint material, providing a new substitute for graphite electrode joints. The formula of this patented product adopts medium and small particle size materials to theoretically solve the problem of high porosity and ensure the impermeability of the product. Contents of the invention [0003] The object of the present invention is to provide a graphite electrode with a dia...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B31/04
Inventor 冯立明郑兴龙牛进才张跃丽王联合陈勇
Owner 焦作市中州炭素有限责任公司