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A kind of production method of preparing potassium dihydrogen phosphate by-product tobacco special fertilizer

A special tobacco fertilizer and potassium dihydrogen phosphate technology, which is applied to ammonium orthophosphate fertilizers, alkaline orthophosphate fertilizers, phosphate fertilizers, etc., can solve incomplete crystallization of potassium dihydrogen phosphate, insufficient purity of potassium dihydrogen phosphate products, Potassium dihydrogen phosphate product waste and other issues have achieved significant environmental protection value and economic benefits, significant economic benefits, and reduced production costs

Inactive Publication Date: 2016-03-16
GUIZHOU KAILIN GRP CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] At the same time, there is also a technology for preparing compound fertilizers for crops, but there is no technical solution for combining elements in the compound fertilizer preparation process according to the needs of crops and making compound fertilizers in a compound state. Tobacco is a relatively special economic crop; there is no literature found in the process of preparing potassium dihydrogen phosphate products by the reaction of phosphoric acid and urea, the waste of a large amount of potassium dihydrogen phosphate products caused by incomplete crystallization of potassium dihydrogen phosphate, And the excessive crystallization of potassium dihydrogen phosphate will contain a large amount of impurities, and then the purity of the potassium dihydrogen phosphate product is not enough, and the technical problems that are difficult to eliminate in the conversion of a large amount of waste liquid are solved.

Method used

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  • A kind of production method of preparing potassium dihydrogen phosphate by-product tobacco special fertilizer
  • A kind of production method of preparing potassium dihydrogen phosphate by-product tobacco special fertilizer
  • A kind of production method of preparing potassium dihydrogen phosphate by-product tobacco special fertilizer

Examples

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Effect test

Embodiment 1

[0056] A production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer, comprising the following steps:

[0057] (1) Preparation and mixing of raw materials: put phosphoric acid and carbonamide in a stirred reactor at a molar ratio of 1.2:1, raise the temperature to 160°C at a heating rate of 5°C / min, and control the stirring speed of the stirring tank to 100r / min to stir Mixing reaction 4h, obtain urea phosphate intermediate slurry;

[0058] (2) Preparation of KH 2 PO 4 : Add 1.3mol of potassium hydroxide 3h at a uniform speed into the reaction kettle containing the urea phosphate intermediate slurry obtained in step 1), and adopt a stirring speed of 160r / min to stir and react for 30min to obtain potassium-containing urea phosphate slurry;

[0059] (3) Cyclic crystallization and filtration: the potassium-containing urea phosphate slurry obtained in step 2) is placed in a cooling crystallizer to cool down to a temperature of 20° C., and...

Embodiment 2

[0062] A production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer, comprising the following steps:

[0063] (1) Preparation and mixing of raw materials: put the phosphoric acid solution with a concentration of 48% and the carbonamide solution with a concentration of 35% in a stirred reactor at a molar ratio of 1:1.3, and heat up to 90°C at a heating rate of 5°C / min , control the stirring speed of the stirred tank to be 100r / min stirring and mixing reaction for 4.2h, and obtain the urea phosphate intermediate slurry;

[0064](2) Preparation of KH 2 PO 4 : the potassium hydroxide solution 3h of 1.1mol is added at a constant speed into the reactor containing the urea phosphate intermediate slurry prepared by step 1), and the stirring speed is 205r / min for stirring and reacting for 70min to obtain the potassium urea phosphate slurry ;

[0065] (3) Cyclic crystallization filtration: the potassium-containing urea phosphate slurry obtain...

Embodiment 3

[0068] A production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer, comprising the following steps:

[0069] (1) Preparation and mixing of raw materials: put phosphoric acid and carbonamide in a stirred reactor at a molar ratio of 1.6:1, raise the temperature to 80°C at a heating rate of 5°C / min, and control the stirring speed of the stirring tank to 210r / min. Mixing reaction 5h, obtain urea phosphate intermediate slurry;

[0070] (2) Preparation of KH 2 PO 4 : the potassium hydroxide 2h of 1.1mol is added in the reactor containing the urea phosphate intermediate slurry that step 1) makes at a uniform speed again, and adopting stirring speed is 205r / min stirring reaction 70min, obtains potassium-containing urea phosphate slurry;

[0071] (3) Cyclic crystallization and filtration: the potassium-containing urea phosphate slurry obtained in step 2) is placed in a cooling crystallizer to cool down to a temperature of 19° C., and the coo...

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Abstract

The invention relates to the technical field of chemical engineering, in particular to a production method of special tobacco fertilizer serving as a byproduct of preparation of monopotassium phosphate. The special tobacco fertilizer serving as the byproduct prepared from waste liquid obtained by preparation of the monopotassium phosphate by a wet method is produced by detecting and analyzing the element content of the special tobacco fertilizer and an effective absorption form and an effective absorption amount of tobaccos to nitrogen, phosphorus and potassium elements and adjusting and matching the element content in a technical production process; the matching contents of a large quantity of nutritional elements such as nitrogen, phosphorus and potassium are adjusted, so that excessive nutritional elements are prevented from being introduced into soil, and the environmental pollution caused by solidification of composite fertilizer and blocking of the soil is avoided; furthermore, the phenomenon that the composite tobacco fertilizer is extremely high in production cost due to element mis-matching is also avoided; the production method is obvious in environment-friendly value and high in economical benefit.

Description

technical field [0001] The invention relates to the technical field of chemical industry, in particular to a production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer. Background technique [0002] Nitrogen, phosphorus, and potassium are essential nutrients for plant growth. The uptake of nitrogen by plant roots is mainly in the inorganic form [NH 4 + ] and [NO 3 - ]; Phosphorus mainly in the form of [H 2 PO 4 - ] form is taken up by plants; potassium dissociates in water into [K + ], absorbed by plant roots. Urea is an organic nitrogen fertilizer, which needs to be hydrolyzed into ammonium carbonate or ammonium bicarbonate by the action of urease in the soil before it can be absorbed and utilized by crops. [0003] At the same time, potassium dihydrogen phosphate is a kind of potassium dihydrogen phosphate that can be applied in fields such as industry and agriculture, and has a wide range of uses. For example, in the ind...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B25/30C05G1/00C05B7/00
Inventor 韩朝应高贵龙廖吉星赵伟毅朱飞武陈肖虎彭宝林曾舒
Owner GUIZHOU KAILIN GRP CO LTD
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