A kind of production method of preparing potassium dihydrogen phosphate by-product tobacco special fertilizer
A special tobacco fertilizer and potassium dihydrogen phosphate technology, which is applied to ammonium orthophosphate fertilizers, alkaline orthophosphate fertilizers, phosphate fertilizers, etc., can solve incomplete crystallization of potassium dihydrogen phosphate, insufficient purity of potassium dihydrogen phosphate products, Potassium dihydrogen phosphate product waste and other issues have achieved significant environmental protection value and economic benefits, significant economic benefits, and reduced production costs
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Embodiment 1
[0056] A production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer, comprising the following steps:
[0057] (1) Preparation and mixing of raw materials: put phosphoric acid and carbonamide in a stirred reactor at a molar ratio of 1.2:1, raise the temperature to 160°C at a heating rate of 5°C / min, and control the stirring speed of the stirring tank to 100r / min to stir Mixing reaction 4h, obtain urea phosphate intermediate slurry;
[0058] (2) Preparation of KH 2 PO 4 : Add 1.3mol of potassium hydroxide 3h at a uniform speed into the reaction kettle containing the urea phosphate intermediate slurry obtained in step 1), and adopt a stirring speed of 160r / min to stir and react for 30min to obtain potassium-containing urea phosphate slurry;
[0059] (3) Cyclic crystallization and filtration: the potassium-containing urea phosphate slurry obtained in step 2) is placed in a cooling crystallizer to cool down to a temperature of 20° C., and...
Embodiment 2
[0062] A production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer, comprising the following steps:
[0063] (1) Preparation and mixing of raw materials: put the phosphoric acid solution with a concentration of 48% and the carbonamide solution with a concentration of 35% in a stirred reactor at a molar ratio of 1:1.3, and heat up to 90°C at a heating rate of 5°C / min , control the stirring speed of the stirred tank to be 100r / min stirring and mixing reaction for 4.2h, and obtain the urea phosphate intermediate slurry;
[0064](2) Preparation of KH 2 PO 4 : the potassium hydroxide solution 3h of 1.1mol is added at a constant speed into the reactor containing the urea phosphate intermediate slurry prepared by step 1), and the stirring speed is 205r / min for stirring and reacting for 70min to obtain the potassium urea phosphate slurry ;
[0065] (3) Cyclic crystallization filtration: the potassium-containing urea phosphate slurry obtain...
Embodiment 3
[0068] A production method for preparing potassium dihydrogen phosphate by-product tobacco special fertilizer, comprising the following steps:
[0069] (1) Preparation and mixing of raw materials: put phosphoric acid and carbonamide in a stirred reactor at a molar ratio of 1.6:1, raise the temperature to 80°C at a heating rate of 5°C / min, and control the stirring speed of the stirring tank to 210r / min. Mixing reaction 5h, obtain urea phosphate intermediate slurry;
[0070] (2) Preparation of KH 2 PO 4 : the potassium hydroxide 2h of 1.1mol is added in the reactor containing the urea phosphate intermediate slurry that step 1) makes at a uniform speed again, and adopting stirring speed is 205r / min stirring reaction 70min, obtains potassium-containing urea phosphate slurry;
[0071] (3) Cyclic crystallization and filtration: the potassium-containing urea phosphate slurry obtained in step 2) is placed in a cooling crystallizer to cool down to a temperature of 19° C., and the coo...
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