Plant fiber reinforced modified soy-based resin composite material

A technology of soybean oil-based resin and plant fiber, which is applied in the direction of synthetic resin layered products, wood processing equipment, lamination, etc., can solve the problems of poor interface bonding, poor mechanical properties, and shortage of petroleum-based resin raw materials, and achieve impact The effect of strength improvement

Active Publication Date: 2015-03-25
FUJIAN AGRI & FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] The object of the present invention is to provide a plant fiber-reinforced modified soybean oil-based resin composite material and its preparation method to solve the shortage of petroleu

Method used

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  • Plant fiber reinforced modified soy-based resin composite material
  • Plant fiber reinforced modified soy-based resin composite material
  • Plant fiber reinforced modified soy-based resin composite material

Examples

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Example Embodiment

[0014] Example 1

[0015] Raw material: plant fiber is hemp fiber (the number of hemp fiber is 130 and the average length is 3cm), purchased from Anhui Tongling Sanxing Hemp Industry Co., Ltd.; soybean oil-based resin is made of N -Vinylpyrrolidone (NVP) and epoxy soybean oil acrylate (AESO) are blended to obtain: NVP is purchased from Shanghai Jingchun (Aladdin) Industrial Co., Ltd.; AESO (model: F03; viscosity (23°C): 8000-20000cps ; Acid value: ≤ 12 mgKOH / g) was purchased from Jiangsu Litian Technology Co., Ltd.; the modifier was isophorone diisocyanate (IPDI), purchased from Tixiai (Shanghai) Chemical Industry Development Co., Ltd.; the initiator was Tert-Butyl Peroxybenzoate (TBPB), purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.

[0016] Plant fiber / modified soybean oil-based resin composite material:

[0017] The preparation process of modified soybean oil-based resin is as follows: put soybean oil-based resin (95g) and modifier (5g) in a round-bottomed flask, stir ...

Example Embodiment

[0020] Example 2

[0021] Raw material: plant fiber is hemp fiber (the number of hemp fiber is 130 and the average length is 3cm), purchased from Anhui Tongling Sanxing Hemp Industry Co., Ltd.; soybean oil-based resin is made of N -Vinylpyrrolidone (NVP) and epoxy soybean oil acrylate (AESO) are blended to obtain: NVP is purchased from Shanghai Jingchun (Aladdin) Industrial Co., Ltd.; AESO (model: F03; viscosity (23°C): 8000-20000cps ; Acid value: ≤ 12 mgKOH / g) was purchased from Jiangsu Litian Technology Co., Ltd.; the modifier was isophorone diisocyanate (IPDI), purchased from Tixiai (Shanghai) Chemical Industry Development Co., Ltd.; the initiator was Tert-Butyl Peroxybenzoate (TBPB), purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.

[0022] Plant fiber / modified soybean oil-based resin composite material:

[0023] The preparation process of modified soybean oil-based resin is as follows: put soybean oil-based resin (90g) and modifier (10g) in a round-bottomed flask, stir...

Example Embodiment

[0026] Example 3

[0027] Raw material: plant fiber is hemp fiber (the number of hemp fiber is 130 and the average length is 3cm), purchased from Anhui Tongling Sanxing Hemp Industry Co., Ltd.; soybean oil-based resin is made of N -Vinylpyrrolidone (NVP) and epoxy soybean oil acrylate (AESO) are blended to obtain: NVP is purchased from Shanghai Jingchun (Aladdin) Industrial Co., Ltd.; AESO (model: F03; viscosity (23°C): 8000-20000cps ; Acid value: ≤ 12 mgKOH / g) was purchased from Jiangsu Litian Technology Co., Ltd.; the modifier was isophorone diisocyanate (IPDI), purchased from Tixiai (Shanghai) Chemical Industry Development Co., Ltd.; the initiator was Tert-Butyl Peroxybenzoate (TBPB), purchased from Sigma-Aldrich (Shanghai) Trading Co., Ltd.

[0028] Plant fiber / modified soybean oil-based resin composite material:

[0029] The preparation process of modified soybean oil-based resin is as follows: put soybean oil-based resin (85g) and modifier (15g) in a round bottom flask, stir w...

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Abstract

The invention discloses a plant fiber reinforced modified soy-based resin composite material and a preparation method thereof. Cross-linking agents and epoxidized soybean oil acrylate are blended to prepare soy-based resin, the soy-based resin is modified by modifiers to obtain modified soy-based resin, and plant fibers, the modified soy-based resin and initiators are hot-pressed to obtain the plant fiber reinforced modified soy-based resin composite material. The plant fiber reinforced modified soy-based resin composite material has excellent tensile strength, tensile modulus, bending strength, bending modulus and impact strength.

Description

technical field [0001] The invention belongs to the technical field of natural plant fiber-reinforced resin composite materials, and in particular relates to a plant fiber-reinforced modified soybean oil-based resin composite material and a preparation method thereof. Background technique [0002] In natural plant fiber reinforced polymer composites, the most commonly used thermosetting resins are epoxy resins, phenolic resins and unsaturated polyester resins. Generally, these thermosetting resins have good mechanical properties, chemical resistance and process performance, but the environmental and air pollution problems caused by the volatilization of toxic substances (such as formaldehyde, styrene, etc.) during use have caused great focus on. In addition, the continuous depletion of petroleum resources and rising prices have forced people to seek and develop new renewable bio-based resins. Acrylate epoxidized soybean oil (AESO) is obtained by reacting soybean oil with a...

Claims

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Application Information

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IPC IPC(8): C08L75/14C08L97/02B32B27/04B32B27/12B32B27/40B32B37/02B32B37/06B27N3/04
Inventor 刘文地邱仁辉谢天顺许博皓沈云玉
Owner FUJIAN AGRI & FORESTRY UNIV
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