Glass fiber reinforced NPG-PETG transparent composite material and preparation method thereof

A technology of glass fiber and composite materials, which is applied in the field of glass fiber reinforced NPG-PETG transparent composite materials and its preparation, which can solve the problems of low toughness and achieve the effects of high fluidity, high surface gloss and high impact strength

Active Publication Date: 2020-02-18
腾龙特种树脂(厦门)有限公司
View PDF3 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] NPG-PETG is formed by esterification and polycondensation of neopentyl glycol, ethylene glycol and terephthalic acid. It is a new transparent

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Glass fiber reinforced NPG-PETG transparent composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0033] Example 1:

[0034] A glass fiber reinforced NPG-PETG transparent composite material. Each component in the raw material is calculated in parts by weight, including 50 parts of NPG-PETG, 50 parts of modified glass fibers, 0.9 parts of antioxidants, and 0.3 parts of lubricants.

[0035] The above NPG-PETG is formed by esterification and condensation polymerization of three monomers: neopentyl glycol, ethylene glycol and terephthalic acid.

[0036] Stearate is selected for the above lubricant.

[0037] The antioxidant 1010 is a phenolic antioxidant.

[0038] The preparation method of the above modified glass fiber includes the following steps:

[0039] S1: Take an appropriate amount of glass fiber with a length of 3-4.5mm and a monofilament diameter of 8-17μm into a 9.5mol / L phosphoric acid solution, where the mass ratio of the glass fiber to the phosphoric acid solution is 1:25, and stir for 3min at room temperature;

[0040] S2: Filter the treated glass fiber from the phosphoric ac...

Example Embodiment

[0048] Example 2:

[0049] A glass fiber reinforced NPG-PETG transparent composite material. Each component in the raw material is calculated in parts by weight, including 60 parts of NPG-PETG, 40 parts of modified glass fiber, 0.1 part of antioxidant, and 0.6 part of lubricant.

[0050] The above NPG-PETG is formed by esterification and condensation polymerization of three monomers: neopentyl glycol, ethylene glycol and terephthalic acid.

[0051] The above-mentioned lubricants are fatty alcohol diacid esters.

[0052] The antioxidant 168 is a phosphite lipid antioxidant.

[0053] The preparation method of the above modified glass fiber includes the following steps:

[0054] S1: Take an appropriate amount of glass fiber with a length of 3-4.5mm and a monofilament diameter of 8-17μm into a 9.5mol / L phosphoric acid solution, where the mass ratio of the glass fiber to the phosphoric acid solution is 1:26, and stir for 6min at room temperature;

[0055] S2: Filter the treated glass fiber fro...

Example Embodiment

[0063] Example 3:

[0064] A glass fiber reinforced NPG-PETG transparent composite material. Each component in the raw material is calculated in parts by weight, including 75 parts of NPG-PETG, 30 parts of modified glass fibers, 1.8 parts of antioxidants, and 0.5 parts of lubricants.

[0065] The above NPG-PETG is formed by esterification and condensation polymerization of three monomers: neopentyl glycol, ethylene glycol and terephthalic acid.

[0066] The above-mentioned lubricants are stearic acid esters and fatty alcohol diacid esters, and the ratio of the two is 1:1.

[0067] The above-mentioned antioxidants are phenolic antioxidants 1010 and phosphite antioxidants 168, where 1010 and 168 are 1:2.

[0068] The preparation method of the above modified glass fiber includes the following steps:

[0069] S1: Take an appropriate amount of glass fiber with a length of 3-4.5mm and a monofilament diameter of 8-17μm into a 9.5mol / L phosphoric acid solution, where the mass ratio of the glass ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to the technical field of high polymer materials, in particular to a glass fiber reinforced NPG-PETG transparent composite material and a preparation method thereof. The glass fiber reinforced NPG-PETG transparent composite material is prepared from, by weight, 50-95 parts of NPG-PETG, 5-50 parts of modified glass fiber, 0.1-3 parts of an antioxidant and 0.3-2 parts of a lubricant; the NPG-PETG used in the invention is prepared by esterification and polycondensation of three monomers of neopentyl glycol (NPG), ethylene glycol and terephthalic acid, and has good fluidity and high gloss. The modified glass fiber is blended into the NPG-PETG, so that the prepared glass fiber reinforced NPG-PETG composite material keeps transparent while having high impact strength, heatresistance, high modulus, high rigidity and high surface gloss.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a glass fiber reinforced NPG-PETG transparent composite material and a preparation method thereof. Background technique [0002] Glass fiber is often used in composite materials to strengthen and toughen, improve the strength, heat insulation and other properties of composite materials. When glass fiber is applied to PETG composite material, due to the smooth surface of glass fiber, the adhesion with the base material is weak, the compatibility is poor, and it is easy to appear floating fibers and other undesirable phenomena, which is not conducive to the strengthening and toughening of PETG composite material , which greatly limits its application. [0003] PETG is a transparent resin, which is an amorphous copolyester. The comonomer commonly used in PETG is 1,4-cyclohexanedimethanol (CHDM), which is called polyethylene terephthalate-1,4- Cyclohexane dimethanol ester...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08L67/02C08K13/06C08K9/06C08K9/02C08K7/14C08K5/103C08J5/08
CPCC08J5/08C08J2367/02C08J2467/02C08K5/103C08K7/14C08K9/02C08K9/06C08K13/06C08K2201/003C08K2201/004
Inventor 王惠武曾晓强梁腾辉刘虎杨立清赵铁侠黄耀智吴荣汉
Owner 腾龙特种树脂(厦门)有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap