The application relates to a multi-phase synergic high-strength high-elasticity
polyester elastomer and a preparation method and application thereof, and belongs to the technical field of
high polymer material synthesis. The application comprises the following steps: weighing
binary acid I, binary
alcohol and a hydroxyl-terminated polyether, and performing
esterification reaction on terminal carboxyl groups and terminal hydroxyl groups to form an esterification product;
polyester oligomers are prepared by performing ester exchange reaction between the terminal hydroxyl groups of the esterification product;
caprolactam is added to generate
aminocaproic acid by ring-opening reaction, and meanwhile, the
aminocaproic acid and part of the
polyester oligomers perform
esterification reaction to form a multi-component
oligomer with terminal amino groups and terminal hydroxyl groups;
binary acid II and a
solvent are added, and
salt formation reaction is performed on the terminal carboxyl groups and the terminal amino groups at low temperature; at high temperature, three forms of polycondensation reactions, i.e.,
amide bond formation by
dehydration of the
ammonium salt,
ester bond formation by
dehydration of the terminal carboxyl groups and the terminal hydroxyl groups, and
ester bond formation by
dehydration of the binary
alcohol between the terminal hydroxyl groups, are synchronously performed to prepare a multi-block polyester
elastomer. The
hydrogen bond interaction is strengthened, and the tensile strength, tensile modulus and elastic
recovery capacity of the
elastomer are improved.