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Method for preparing high-strength polymer composite material

A composite material and polymer technology, which is used in the field of preparing high-strength polymer composite materials, can solve problems affecting the performance of composite materials, and achieve the effects of improving bearing capacity, reducing chain end defects, and promoting orderly dispersion.

Active Publication Date: 2011-09-14
SUN YAT SEN UNIV +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Because when the oriented material is used to prepare the applied material, the processing process inevitably has the existence of disorientation of the molecular chain, which will eventually affect the performance of the composite material.

Method used

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  • Method for preparing high-strength polymer composite material
  • Method for preparing high-strength polymer composite material

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Embodiment Construction

[0026] Table 1 shows the dosage ratio of each component of the reinforced phase embodiment of the present invention. The specific steps are as follows: the nano-inorganic particles are firstly modified by chemical grafting, and the graft monomer is butyl acrylate. The dosage ratio is shown in Table 1. The grafted modified nanoparticles and high melting point polypropylene were melt-blended in the mixer of Hakke torque rheometer to prepare masterbatch, and then the masterbatch and polypropylene were diluted in proportion. The oriented reinforcing phase (labeled A) was obtained by a solid-state drawing process. Table 2 is the formulation of comparative examples for injection molding.

[0027] A film with a thickness of 0.05mm~0.15mm is made into a film with a thickness of 0.05mm~0.15mm from the low melting point co-PP (marked as B) as the matrix phase.

[0028] Finally, we make composite material by reinforcing phase A and matrix phase B through thin layer laying-hot pressing. ...

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Abstract

The invention discloses a method for preparing a high-strength polymer composite material. The method comprises the following steps of: S1: modifying a monomer into nano inorganic particles by chemical graft polymerization, and melting, blending and extruding the modified nano particles and a thermoplastic polymer to manufacture a rod-like preformed blank, or melting, blending and stamping the modified nano particles and the thermoplastic polymer to manufacture a flaky preformed blank, wherein the molar amount of the monomer is same as that of nano inorganic particles, the consumption of the nano inorganic particles is 1 to 3 weight percent of the thermoplastic polymer; S2: stretching the preformed blank at a temperature of between 130 and 150 DEG C and at a speed of 10 to 50 millimeters per minute, and cooling to obtain a fiber-like or flaky reinforced phase; and S3: preparing a film from a copolymer with melting point of 140 to 150 DEG C by a film blowing method, and preparing the composite material from the oriented reinforced phase and a matrix phase with low melting point through a tensile force self-adjusting die by a thin layer bedding-hot pressing method. By combining a self-reinforcing technology and an inorganic particle filling modified polymer composite material, the polymer composite material with remarkably improved tensile strength and tensile modulus can be obtained.

Description

technical field [0001] The invention relates to a method for preparing high-strength polymer composite materials by combining nanometer reinforcement and self-reinforcement technologies. Background technique [0002] The development of some special fields such as aviation industry, military industry and other fields put forward higher requirements for the performance of polymer materials, such as high strength, high modulus, light weight and so on. To improve the mechanical strength of polymer materials, the traditional modification method of using fibers (such as glass fibers or carbon fibers) to reinforce and increase the molecular weight of polymer materials can improve the mechanical strength of polymers to a certain extent, but brings material Increased specific gravity and increased viscosity make processing difficult, which cannot meet the urgent needs of current high-end products for transparent, lightweight and high-performance materials. [0003] The theoretically...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C49/04C08L23/06C08L23/12C08L51/10C08F292/00
Inventor 阮文红章明秋王明辉容敏智汪加胜宁凯军李白千
Owner SUN YAT SEN UNIV
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