1076 results about "Polymer composite materials" patented technology

The invention relates to the field of civil engineering waterproof materials, in particular to a nano bentonite-polymer composite material with high salt tolerance and a preparation method thereof, and the nano bentonite-polymer composite material is especially suitable for a sodium-based bentonite waterproof blanket in a saline soil area or a marine environment, and the preparation method comprises the following steps: (1) preparing nano bentonite lamellar colloidal dispersion liquid; (2) introducing and mixing an electrostatic screening agent and a polymerizable monomer; (3) carrying out in-situ free radical polymerization reaction; and (4) post-treatment and finished product preparation. By constructing a three-dimensional interpenetrating hierarchical structure composed of a covalent grafted polymer network, a physically anchored electrostatic screening agent and a stripped bentonite nanosheet layer, effective protection of a bentonite core anti-seepage unit is realized, so that the adaptability and long-term stability of the material under a complex water quality condition are remarkably improved.

The invention relates to an impact-resistant chlorinated polyvinyl chloride composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The composite material comprises the following components: 100 parts of CPVC resin, 6.5 to 9.5 parts of a modified impact modifier, 2.6 to 3.2 parts of a heat stabilizer, 1.5 to 2 parts of a lubricant, 1.2 to 1.6 parts of a processing aid, 0.2 to 0.25 part of a light stabilizer and 8 to 11 parts of a filler, the modified impact modifier takes a POSS cage structure as a core, a branch chain sequentially contains thioamide-secondary amine-tertiary amine structures, a polarity gradient is formed and fully extends into a macromolecular chain of CPVC to transmit and dissipate impact energy, meanwhile, the amine structure interacts with chlorine groups in a molecular chain of CPVC to form molecular anchoring, expansion of crazes is inhibited, and the impact strength of the CPVC is improved. The continuity and the stability of a bonding interface are maintained, so that the composite material keeps relatively high mechanical strength and thermal stability.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an oil-resistant interior material. The material comprises a porous base material layer, a fluorine-containing polymer and organic silicon resin blended oil-resistant functional layer and a micro-nano structure layer with a periodic micro-bulge array, surface modified nanoparticles are distributed in the functional layer in a gradient manner, and the micro-bulge surface is covered with a perfluoropolyether / fluorinated silicon dioxide composite coating; through a synergistic effect of a low-surface-energy oleophobic interface formed through chemical bonding and curing and a micro-structure capillary lifting effect, anti-permeation barrier of high-viscosity grease is realized, and meanwhile, mechanical wear resistance and thermal stability are improved by virtue of a nano-particle enhanced cross-linked network; and continuous imprinting and an ultraviolet-thermal dual-curing process are combined to achieve high-efficiency manufacturing with zero solvent residue, and finally the interior material with long-acting oil resistance, high environmental tolerance and industrial mass production feasibility is obtained.

The invention discloses a preparation process of a high-temperature-resistant and wear-resistant polymer composite material, which comprises the following preparation steps: (1) selecting polyether-ether-ketone as matrix resin, and drying the matrix resin at 150 DEG C for 4 hours; (2) preparing porous sphere-like boron carbide ceramic powder; (3) carrying out surface treatment on the prepared porous sphere-like boron carbide ceramic powder; and (4) uniformly mixing the boron carbide ceramic powder subjected to surface treatment in the step (3) and polyether-ether-ketone in a mild mixing manner, compounding with carbon fibers, and extruding and granulating by using a double-screw extruder to obtain the high-temperature-resistant and wear-resistant polymer composite material. Through the mode, the composite material prepared by the method does not contain PFAS chemical substances, is superior to the existing PTFE material in the aspects of wear resistance, environmental protection property, high temperature resistance and the like, and is an ideal reliable PTFE substitute material.

The invention discloses a fluoride-free reinforced wear-resistant polyketone composite material as well as a preparation method and application thereof, and relates to the technical field of polymer composite materials. The fluoride-free reinforced wear-resistant polyketone composite material comprises polyketone resin, glass fibers, modified ultra-high molecular weight polyethylene, an antioxidant and a lubricant, wherein the modified ultra-high molecular weight polyethylene is obtained by modifying branched-chain-free linear polyethylene with the molecular weight of 2 million or more, and the dosage of the modifier is 1%-5% of that of the ultra-high molecular weight polyethylene. The modified ultra-high molecular weight polyethylene, the glass fiber and the polyketone resin are subjected to blending modification, and the characteristics of good wear resistance of the polyketone resin and high strength of the glass fiber are combined; meanwhile, the friction coefficient is low after the ultra-high molecular weight polyethylene is modified, the compatibility with the polyketone resin is enhanced, the dispersion is more uniform, and the heat resistance and friction performance of the polyketone resin are comprehensively improved. In addition, due to the use of fluorine-free, the safety of the polyketone composite material is improved, and meanwhile, the application market of the polyketone composite material is expanded.

The invention relates to the technical field of functional polymer composite materials, and provides diatomite modified composite super absorbent and rapid absorbent resin and a preparation method thereof. The preparation raw materials of the diatomite modified composite high-water-absorption and rapid-water-absorption resin provided by the invention comprise acrylic acid, acrylamide, sodium hydroxide, N, N '-methylene bisacrylamide, ammonium persulfate and modified diatomite. The diatomite is modified by the silane coupling agent, the agglomeration problem of the diatomite is solved, the compatibility with organic monomers is improved, and the modified diatomite, acrylic acid and acrylamide are utilized to construct an organic-inorganic synergistic three-dimensional porous network structure, so that the resin has ultrahigh water absorption rate, rapid water absorption performance and good water retention stability. Meanwhile, the preparation method disclosed by the invention does not need nitrogen protection, has the advantages of simple process, controllable raw material cost and easiness in industrial mass production, and is suitable for multiple fields such as water-saving agriculture, soil moisturizing, landscaping and the like.

The invention discloses a tough full-bio-based polylactic acid / polyamide composite material and a preparation method thereof, and belongs to the technical field of polymer composite material preparation. The tough polylactic acid / polyamide composite material comprises polylactic acid, bio-based polyamide, a core-shell amide modified material, a hydrolysis stabilizer, an antioxidant and a chain extender. The core-shell amide modified material is prepared by filling a functional elastomer copolymer with amino nanoparticles. The core-shell amide modified material formed on the basis of the amino nanoparticle reactive filling functional elastomer copolymer has a micro core-shell structure formed in situ and a large number of amido bonds, so that the number of hydrogen bonds between molecular chains of a blend system is increased, and entanglement and intermolecular acting force between micro molecular chains of the blend material are improved; therefore, the system compatibility is improved, the absorption of the material on external stress and energy is enhanced, more obvious plastic deformation is generated when the material is stressed and deformed, and the material is endowed with better mechanical properties.

The invention belongs to the technical field of composite material design, and discloses a polymer composite material design method based on LLM knowledge database construction and reasoning optimization, and the method comprises the following steps: S1, target performance setting; s2, constructing a knowledge database; s3, constructing a reverse design model; s4, constructing a performance verification module; and S5, performing multi-round test-verification design loop optimization. According to the method, an intelligent design method integrating target setting, semantic knowledge database construction, a design assistant, a performance verifier, a prompt engineering module and a language model material knowledge system is provided, closed-loop reasoning and feedback of structure-mechanism-performance are achieved through multiple rounds of DA-VM collaborative optimization, and the design efficiency is improved. The method has the advantages of high design efficiency, strong structure generation rationality, accurate performance prediction, knowledge evolvable and the like, and is suitable for intelligent rapid development of the high thermal conductivity-wave absorbing-shielding-mechanical integrated functional polymer composite material.

The invention discloses a wide-temperature energy storage aerogel / polymer composite material and a preparation method thereof.The preparation method comprises the steps that oxide aerogel with a three-dimensional skeleton structure is subjected to silanization treatment to obtain hydrophobic oxide aerogel, then the hydrophobic oxide aerogel is dispersed into a solvent to obtain dispersion liquid, and then the dispersion liquid is subjected to ultrasonic treatment to obtain the wide-temperature energy storage aerogel / polymer composite material. The preparation method comprises the following steps: sequentially adding a diamine monomer and an anhydride monomer into a dispersion liquid, reacting under stirring to obtain a polyamide acid precursor solution dispersed with hydrophobic oxide aerogel, carrying out film casting on the polyamide acid precursor solution to obtain a dry film, and carrying out imidization treatment on the dry film to obtain the aerogel / polymer composite material. The obtained aerogel / polymer composite material can still maintain high energy storage performance and stability even at extreme ambient temperature.

The invention relates to the technical field of polymer composite materials, and discloses a nano-ceramic-based composite insulating coating and a preparation method thereof, and the coating is prepared from a composite resin matrix, a composite functional ceramic filler, a double-reactivity organosilicon linker and an initiator. Wherein the composite resin matrix is composed of vinyl-terminated polydimethylsiloxane and a vinyl ether functionalized fluorocarbon copolymer, and a soft and rigid interpenetrating network structure is formed. The composite functional ceramic filler is prepared from needle-shaped silicon nitride, flaky hexagonal boron nitride, nano silicon dioxide, nano cerium oxide and nano barium titanate. According to the invention, a chemical bonding interface is constructed between the inorganic filler and the organic resin, and the synergistic effect of the composite matrix and the multifunctional filler is optimized, so that the coating has excellent adhesive force, flexibility and thermal shock resistance, obtains high volume resistivity and breakdown strength, and meets the insulation protection requirements under harsh working conditions.

The invention provides an antistatic talcum powder and graphene composite reinforced material and an in-situ polymerization process thereof, and belongs to the technical field of polymer composite materials. According to the antistatic talcum powder and graphene composite reinforced material and the in-situ polymerization process thereof, the antistatic talcum powder and graphene composite reinforced material is prepared from the following raw materials in parts by weight: 100 parts of matrix resin, 5-30 parts of modified talcum powder, 0.5-5 parts of functionalized graphene and 0.1-2 parts of an antistatic synergist, the modified talcum powder is subjected to surface treatment by a silane coupling agent, the particle size range is 1-10 [mu] m, and the functionalized graphene is graphene oxide or reduced graphene oxide. Through the synergistic effect of the silane coupling agent modified talcum powder and the functionalized graphene and in combination with the ionic liquid antistatic agent, the surface resistance of the material is remarkably reduced. Nanoscale dispersion is realized by adopting an in-situ polymerization process, and the method is suitable for the field of high-performance engineering plastics.

The invention relates to the technical field of polymer composite materials, in particular to a carbon fiber reinforced nylon 66 / polyphenylene sulfide composite material and a preparation method thereof.The carbon fiber reinforced nylon 66 / polyphenylene sulfide composite material is prepared from, by weight, 40-55 parts of nylon 66, 30-45 parts of polyphenylene sulfide, 15-30 parts of carbon fibers, 5-6 parts of compatilizer, 0.8-1.2 parts of antioxidant and 3-4 parts of flexibilizer, the flexibilizer is ethylene-octylene copolymer grafted maleic anhydride, the grafting rate is 1.2-1.5%, the flexibilizer is ethylene-octylene copolymer grafted maleic anhydride, the grafting rate is 0.8-1.0%, and the antioxidant is a mixture of an antioxidant 1010 and an antioxidant 168 according to a mass ratio of 1: 1. The composite material prepared by the invention is suitable for medium-high temperature scenes, not only solves the problems of insufficient high temperature resistance and poor mechanical properties of traditional materials, but also has good processability and environmental tolerance.

The invention belongs to the technical field of polymer composite materials, and discloses a carbon fiber interface modifier aided design method and system based on collaborative optimization, and the method is used for designing a carbon fiber interface modifier based on collaborative optimization of machine learning and molecular dynamics simulation. By constructing a closed loop iteration process of generation-prediction-verification-learning, interfacial modifier molecules meeting multi-target performance requirements are quickly and accurately obtained under the condition that a large amount of early-stage chemical synthesis and experimental screening are not needed. According to the method, through deep combination of high-throughput prediction of machine learning and virtual experiment verification of molecular dynamics, efficient and automatic design of the interface modifier molecules is achieved, experimental synthesis and trial and error links are greatly reduced, the research and development efficiency is improved, and the method is widely suitable for design and optimization of the interface modifier molecules of the carbon fiber / resin-based composite material.

The invention relates to the technical field of polymer composite materials, and discloses a refining treatment method of a bamboo fiber ultra-nano micro powder and natural polymer blended material, which comprises the following steps: (a) premixing bamboo fiber ultra-nano micro powder and a deep eutectic solvent to obtain a premix and realize in-situ activation; (b) adding the premix and a natural polymer matrix from a main feed port of a double-screw extruder; and (c) in the melt blending process, adding a dynamic interface locking agent through a side feeding port arranged at the downstream of the main feeding port, and then extruding and granulating. A staged dynamic compatibilization process is adopted, a hydrogen bond network of bamboo fibers is destroyed by using a deep eutectic solvent to promote shearing dispersion of the bamboo fibers in the front section, and stable interface bonding is constructed in the rear section through a dynamic interface locking agent after dispersion is completed. The method synergistically solves the conflict between dispersion and interfacial compatibilization, so that the composite material has good comprehensive performance.

The invention relates to a glass fiber reinforced polyurethane composite material and a preparation process thereof, and belongs to the technical field of polymer composite materials. The formula of the glass fiber reinforced polyurethane composite material comprises the following components in parts by weight: 60-80 parts of thermoplastic polyurethane, 15-25 parts of modified glass fiber, 2-5 parts of an interface modifier, 1-2 parts of an antioxidant and 1-3 parts of a lubricant. A covalently bonded silane coupling agent-nano silicon dioxide composite transition layer is formed by mixing chopped glass fibers and continuous glass fibers to construct a synergistic enhancement system and combining argon-oxygen plasma activation and nano silicon dioxide sol coating processes, so that the interfacial shear strength is remarkably improved, the stress concentration is effectively relieved, and the service life is prolonged. The tensile strength and the impact strength of the material are obviously improved.

The invention relates to the technical field of polymer composite materials, in particular to a polycaprolactone-based composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: carrying out surface grafting treatment on nano cellulose to obtain modified nano cellulose; mixing the modified nanocellulose, polycaprolactone and a solvent to obtain slurry; carrying out melt blending and granulation on the slurry to obtain composite granules; and carrying out melt blending and granulation on the composite granules, a metal soap stabilizer and a natural resin derivative to obtain the polycaprolactone-based composite material. The polycaprolactone-based composite material prepared by a novel composite process of nano cellulose graft modification-solvent replacement synergetic melt co-extrusion has the core advantages of high mechanical strength, excellent light transmittance, long-acting weather resistance and the like, is good in processing adaptability and simple and convenient to operate, can realize continuous large-scale production, and remarkably reduces energy consumption and raw material cost.

The invention relates to the technical field of polymer composite materials, in particular to an explosion-proof and impact-resistant polymer coating material for an aircraft shell. The coating is prepared from aliphatic polyurethane acrylate, cycloaliphatic epoxy resin, nano silicon dioxide, polyethylene glycol, polyurea microcapsules, dicyclopentadiene resin, a Grubb catalyst, graphene oxide, polysulfide rubber and the balance of auxiliary materials. According to the invention, aliphatic polyurethane acrylate is used as a flexible matrix, so that the risk of hydrolysis of aromatic isocyanate is avoided. The dicyclopentadiene resin is subjected to in-situ ring opening polymerization in the presence of a Grubbs catalyst and cooperates with the hydrophobic nano silicon dioxide to block water. The polyurea microcapsules are broken by impact to release silicone oil, and cracks are filled immediately to reduce friction. And a water molecule permeation path is prolonged by the mica powder sheet layer. And the epoxy-polyurethane network realizes micro-crack self-repairing through dynamic ester bond exchange, so that the anti-explosion and anti-impact functions of the coating and the structural stability of an aircraft shell in an extreme environment are guaranteed.

The invention discloses a halogen-free compound flame retardant and application thereof in an antistatic nylon 66 composite material, and belongs to the technical field of polymer composite materials. The halogen-free compound flame retardant is prepared by compounding 68 parts of an organic aluminum hypophosphite flame retardant, 20 parts of a nitrogen-phosphorus intumescent flame retardant, 10 parts of a two-dimensional layered inorganic substance and 2 parts of a coupling agent through a high-speed mixing and drying process. The halogen-free compound flame retardant is blended with nylon 66, reinforced fibers, an antioxidant and the like, and the composite material is prepared through melt extrusion. According to the compound system, the total dosage of the flame retardant is remarkably reduced, the V-0 flame retardant grade is still achieved under the condition that the thickness is 0.8 mm, and the limit oxygen index exceeds 32%. The composite material has excellent flame retardancy and antistatic property while maintaining good mechanical properties, is suitable for a high glass fiber content system, effectively solves the problems of high flame retardant addition amount, difficult processing, high cost and the like in the prior art, and has the advantages of simple process and excellent comprehensive performance.

The invention discloses a high-conductivity porous polymer composite material and a preparation method thereof, and relates to the technical field of conductive composite materials. The high-conductivity porous polymer composite material is prepared by mixing polyether-ether-ketone, amino-functionalized graphene, a silver nanowire / carbon nanotube hybrid filler, a porous polyimide microsphere carrier, an ionic liquid and an antioxidant. The preparation method comprises the following steps: preparing amino-functionalized graphene; preparing a hybrid filler microsphere complex; performing mixing; preparing a porous prefabricated body; and carrying out mould pressing and shaping. According to the composite material disclosed by the invention, through multi-scale structural design and environment-friendly process innovation, high conductivity, high-strength mechanical properties and light weight are realized under the condition of low filler addition amount.

The invention provides a composite solid electrolyte film and a preparation method thereof, a battery and electric equipment, and relates to the field of lithium batteries. The composite solid electrolyte film comprises a polymer composite material and a base film with pores, the polymer composite material fills part or all of the pores and covers part or all of the surface of the base film; the base membrane comprises the following raw materials: an inorganic ceramic solid electrolyte material and a binder. The preparation method of the composite solid electrolyte film comprises the following steps: providing a base film; mixing a lithium salt, an ionic liquid, a cross-linking agent and an initiator to obtain a polymer composite material precursor solution; the polymer composite material precursor solution is arranged on part or all of the pores and part or all of the surface of the base membrane; and performing in-situ curing to obtain the composite solid electrolyte film. The composite solid electrolyte thin film provided by the invention is high in ionic conductivity, high in ionic migration coefficient, high in tensile strength and good in matching contact with a positive electrode and a negative electrode.

The invention belongs to the technical field of polymer composite materials, and particularly relates to an efficient flame-retardant low-toxic-gas-release silicone rubber composite material and a preparation method thereof. The high-efficiency flame-retardant low-toxic-gas-release silicone rubber composite material comprises the following components in parts by weight: 100 parts of methyl vinyl silicone rubber; 10 to 20 parts of ZIF-67 modified by polysiloxane; 5-10 parts of modified nano molybdenum oxide; 5 to 10 parts of melamine cyanurate; 40 to 50 parts of mesoporous SiO2 aerogel; 1-3 parts of hydroxyl silicone oil; 0.5 to 1.5 parts of a vulcanizing agent; and 0-5 parts of an auxiliary agent. The flame-retardant and smoke-suppression performance of the silicone rubber composite material is remarkably improved through material technology innovation, and meanwhile, the mechanical property and the high temperature resistance are improved.

The present invention belongs to the technical field of polymer composite material preparation and discloses a double-layer hollow structure photonic gel film with controllable water permeation and color change, as well as its preparation method and application. The method comprises the following steps: preparing a three-dimensional PS-SiO2 photonic crystal and a three-dimensional SiO2 photonic crystal; calcining the three-dimensional PS-SiO2 photonic crystal at high temperature, filling the crystal with a polymer, and curing the crystal with ultraviolet light to obtain a hollow SiO2 structural color gel; curing the three-dimensional SiO2 photonic crystal with a polymer, and then etching the crystal with hydrofluoric acid to obtain an inverse opal gel; and bonding the hollow SiO2 structural color gel and the inverse opal gel to form a double-layer hollow structure photonic gel film with controllable water permeation and color change. The photonic gel film can be used in snowmelt warning indicators at large ski resorts, portable alcohol solubility detectors, or anti-counterfeiting identification labels for small commercial packaging.

The invention belongs to the technical field of polymer composite materials, and particularly relates to a high-strength bismaleimide resin material and a preparation method thereof. The bismaleimide resin composition comprises the following components in parts by weight: 50-60 parts of bismaleimide resin, 40-50 parts of an allyl compound, 1-3 parts of modified graphene and 0.1-0.5 part of a dispersing filler, the dispersing filler is prepared from modified inorganic nanoparticles and modified tetrapod-like zinc oxide whiskers in a mass ratio of (0.1-1): 1. Wherein the tetrapod-like zinc oxide whiskers can promote the dispersion of the graphene with a large lamellar structure from the macroscopic aspect, so that the graphene is uniformly dispersed in a bismaleimide resin matrix, and the inorganic nanoparticles can play a role in lubrication and isolation, so that the agglomeration among graphene lamellas in a small range is prevented. By adding the graphene composite reinforcing filler, the rigidity of the bismaleimide resin material is improved, and the toughness of the composite material can be improved at the same time.

The invention belongs to the technical field of polymer composite materials, and particularly relates to a polycarbonate modified composite material as well as a preparation method and application thereof, and the polycarbonate modified composite material comprises 60-85 parts of a PC base material, 10-30 parts of a bio-based monomer, 1-8 parts of surface modified nano cellulose and 0.1-2 parts of a transesterification catalyst. According to the polycarbonate modified composite material as well as the preparation method and the application thereof provided by the invention, chemical bonding of a bio-based monomer and a PC main chain is realized through transesterification, phase separation is avoided, and the core pain point of traditional blending modification is solved; the biodegradation rate is increased by 30% or above compared with pure PC, and meanwhile, the excellent mechanical properties (the tensile strength is larger than or equal to 60 MPa, and the notch impact strength is larger than or equal to 5 kJ / m) of PC are reserved; the melt flow rate is increased by more than 25%, the processing energy consumption is reduced, and the application scene is widened; the carboxylic acid modified nano cellulose and the block copolymer form a synergistic network, so that the mechanical property, the thermal stability and the degradation uniformity are synchronously improved.

The invention discloses a polyphenol modified carbon fiber reinforced sulfonated polyetheretherketone composite material and a preparation method thereof, and belongs to the field of polymer composites.The preparation method comprises the steps that a resin matrix and filler are filled into a mold to be sintered, the resin matrix is sulfonated polyetheretherketone, the filler comprises modified carbon fibers and nano-silicon dioxide, and the modified carbon fibers and the nano-silicon dioxide are sintered to obtain the polyphenol modified carbon fiber reinforced sulfonated polyetheretherketone composite material; the modified carbon fiber is prepared by taking carbon fiber, catechol and polyethyleneimine as raw materials in a Tris buffer solution. The hydration lubrication performance of a resin matrix is improved through sulfonated polyetheretherketone, the hydrophilic property is enhanced, a polyphenol coating is formed through self-polymerization reaction on the surfaces of the carbon fibers, the adhesion performance of the surfaces of the fibers is improved through the pi-pi stacking effect, and the interface bonding force between the carbon fibers and the modified resin matrix is enhanced; the nano silicon dioxide is introduced to modify the matrix of the composite material, so that not only is the overall wettability of the material optimized, but also the mechanical property and the wear resistance are effectively improved, and the final composite material has the characteristics of high strength and low friction.

The application discloses a kind of nanocellulose modified acrylic water-based emulsion and its preparation method and application, it is related to the technical field of polymer composite.A kind of modified acrylic water-based emulsion includes 180-220 parts of acrylate monomer, 45-60 parts of functional monomer, 3-5 parts of nanocellulose liquid, 4-6 parts of emulsifier, 1.5-2 parts of initiator, 2-3 parts of sodium bicarbonate and 275-300 parts of deionized water, wherein functional monomer includes hydroxy acrylate, acrylonitrile and fluorine-containing acrylate.By using fluorine-containing acrylate with nanocellulose to modify acrylic emulsion, water-based emulsion with good film-forming performance can be prepared, and the formed coating has good adhesion, stain resistance, heat oil resistance and mechanical strength, if the water-based emulsion is applied to the surface modification of filter material, not only can improve the hand feeling of filter material, but also can improve the stain resistance and service life of filter material surface.

The invention discloses a multi-component liquid metal alloy coordinated polymer composite material and a preparation method and application thereof, and the preparation method comprises the following steps: mixing and heating liquid metal and active metal to melt the liquid metal and the active metal to form a melt; and cooling the melt to obtain the active multi-component liquid metal alloy. And mixing the active multi-element liquid metal alloy with the polymer matrix and the functional additive, and processing and forming. The heat conductivity coefficient of the polymer composite material coordinated by the multi-element liquid metal alloy prepared by the preparation method is 0.15-100W / m.K, and the heat conductivity coefficient retention rate is greater than or equal to 98%; the polymer composite coordinated by the multi-element liquid metal alloy can be self-healed at room temperature, and the tensile elongation after healing can reach more than 60% of that before damage; the invention also discloses application of the composite material in a thermal interface management film on the surface of a chip. The polymer composite material with excellent heat dissipation performance and reliable self-repairing capability can be obtained.

The invention belongs to the technical field of polymer composite materials, and relates to a multilayer solar interface evaporator and a preparation method thereof. The evaporator comprises a photo-thermal layer, a connecting layer and a supporting layer, the photo-thermal layer combines biomass material-carbonized loofah powder with high polymer material polyacrylonitrile, a photo-thermal film with photo-thermal conversion capacity is prepared through the electrostatic spinning technology, and polyaniline grows on the surface of the photo-thermal film in situ so as to improve the photo-thermal efficiency; the connecting layer adopts a loofah sponge fiber skeleton, so that the layers are tightly combined; the supporting layer selects polyamide 6 as a foaming material and bamboo charcoal powder as a functional filler, and the polyamide 6-bamboo charcoal powder foam supporting layer is prepared by utilizing a solution foaming technology and has the functions of heat insulation, water delivery and dye adsorption. The photo-thermal layer and the supporting layer are integrated through the connecting layer to prepare the multi-layer solar interface evaporator, efficient photo-thermal evaporation, high dye adsorption rate and long cycle life are achieved, and the multi-layer solar interface evaporator has the advantages of being environmentally friendly, low in cost and stable in performance and has application prospects in the fields of seawater desalination and industrial wastewater treatment.

The invention discloses a self-repairing polyurethane-boron nitride composite heat conduction material and a preparation method thereof, an electronic device heat dissipation material and a flexible sensor, and relates to the technical field of polymer composite materials. The preparation method of the self-repairing polyurethane-boron nitride composite heat conduction material comprises the following steps: carrying out a first polycondensation reaction on polydihydric alcohol and a diisocyanate monomer to obtain an intermediate, and carrying out a second polycondensation reaction on the intermediate and an aromatic amino compound containing disulfide bonds to obtain a polyurethane matrix; and mixing the polyurethane matrix and the zinc ion-tannic acid co-modified boron nitride to obtain a mixture, casting the mixture into a mold, and curing to obtain the self-repairing polyurethane-boron nitride composite heat-conducting material. The heat conductivity coefficient of the self-repairing polyurethane-boron nitride composite heat conduction material reaches 4.8 W.m <-1 >. K <-1 >, the material can be self-repaired at normal temperature after being broken, the repairing efficiency reaches up to 96%, and the problem that self-healing performance and heat conductivity of an existing polyurethane material are difficult to consider at the same time can be effectively solved.

The invention relates to the technical field of polymer composite materials, in particular to a degradable PPC-based composite film as well as a preparation method and application thereof. The degradable PPC-based composite film is prepared from polypropylene carbonate, bamboo powder and vinyl trimethoxy silane. Polypropylene carbonate (PPC) is adopted as a base material, bamboo powder is combined for filling, the prepared composite film can be completely degraded after being buried in natural soil for 5 months, and degradation products of the composite film do not pollute the environment; the bamboo powder is adopted as a reinforcing filler, has a certain bacteriostatic effect, and can be used for delaying the growth of microorganisms on the surface of food and improving the food safety and the fresh-keeping effect if being applied to the food fresh-keeping film. Compared with a pure PPC film, the composite film disclosed by the invention is improved in the aspects of mechanical property, thermal stability and glass transition temperature, and shows more excellent comprehensive performance.