Method for preparing composite body of metal and resin and composite body prepared by the method
A composite and metal technology, which is applied in the field of composites, can solve problems such as cracks and damage, and achieve the effect of not being easy to peel off
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[0020] A method for preparing a metal-resin composite 100, comprising the steps of:
[0021] A shaped metal substrate 10 is provided, which can be any one of aluminum, aluminum alloy, titanium alloy, aluminum-magnesium alloy and zinc alloy.
[0022] The metal substrate 10 is degreased. The metal substrate 10 is immersed in a neutral metal cleaning agent with a concentration of 5-20g / L. The metal cleaning agent can be an aluminum alloy cleaning agent, a titanium alloy cleaning agent or a zinc alloy cleaning agent, and the temperature of the metal cleaning agent is kept at Clean the metal substrate 10 for 3-10 minutes under ultrasonic conditions at 40-75° C. to remove oil stains on the surface of the metal substrate 10 .
[0023] The degreased metal substrate 10 is dipped in alkaline solution for 2-5 minutes to remove the natural oxide layer on the surface of the metal substrate 10 . The concentration of the alkaline solution is 5-40g / L, and the alkaline solution can be any on...
Embodiment 1
[0035] In this embodiment, the material of the metal substrate 10 is an aluminum alloy substrate Al5052, and the material of the resin layer 40 is PBT.
[0036] Degrease, immerse the metal substrate 10 in a neutral aluminum alloy cleaning agent with a concentration of 25 g / L, keep the temperature of the aluminum alloy cleaning agent at 60° C., and clean under ultrasonic conditions for 6 minutes.
[0037] The degreased metal substrate 10 was immersed in an alkaline solution of NaOH with a concentration of 50 g / L for 0.5 min.
[0038] The metal substrate 10 bitten by the alkali is immersed in a nitric acid solution with a concentration of 150 g / L to peel off the black film, and the time for peeling off the black film is 60 seconds.
[0039] The metal substrate 10 that has been stripped of the black film is subjected to anodic oxidation treatment. The electrolytic solution for anodic oxidation is 300g / L sulfuric acid solution, the voltage is 13V, the temperature is 20°C, and the ...
Embodiment 2
[0044] In this embodiment, the material of the metal substrate 10 is aluminum-magnesium alloy, and the material of the resin layer 40 is PPS.
[0045] Degrease, immerse in a neutral aluminum alloy cleaning agent with a concentration of 25g / L, keep the temperature of the aluminum alloy cleaning agent at 60°C, and clean under ultrasonic conditions for 6 minutes.
[0046] The degreased metal substrate 10 was immersed in an alkaline NaOH solution with a concentration of 30 g / L for 1 min.
[0047] The metal substrate 10 bitten by the alkali is immersed in a nitric acid solution with a concentration of 150 g / L to peel off the black film, and the time for peeling off the black film is 60 seconds.
[0048]The metal substrate 10 with the black film peeled off is subjected to anodic oxidation treatment, the electrolytic solution for anodic oxidation is 100g / L sulfuric acid solution, the voltage is 13V, the temperature is 20°C, and the anodic oxidation time is 30min. The resulting anodi...
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