Hydrogenated styrene-modified dicyclopentadiene petroleum resin and preparation method thereof

A technology of dicyclopentadiene and petroleum resin, applied in the petrochemical field, can solve the problems of reduced hydrotreating effect, influence of product chromaticity and stability, etc., and achieves the effect of reducing quantity, improving hue and stability, and ensuring effect

Active Publication Date: 2015-09-30
安徽同心新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This application is a solution for modifying dicyclopentadiene petroleum resin by mixing styrene and dicyclopentadiene monomers and performing thermal polymerization together. However, due to the above analysis, the modified The chromaticity and stability of the product after curing are affected, thereby reducing the effect of subsequent hydrogenation treatment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A kind of preparation method of hydrogenated styrene-modified dicyclopentadiene petroleum resin of the present embodiment, its step is:

[0039] Step 1, mixing of reaction raw materials:

[0040] Mix high-purity cyclopentadiene monomer, styrene monomer and inert solvent to form a mixed solution. The mass parts of the three components in the mixed solution are: 30 parts of inert solvent, 30 parts of high-purity cyclopentadiene 60 parts of monomer, 25 parts of styrene monomer. The high-purity cyclopentadiene monomer in this embodiment is based on commercially available dicyclopentadiene industrial products with a mass percentage of about 80% as a raw material, and it is added to an atmospheric rectification tower with a theoretical plate number of 15 In the kettle, and the temperature of the tower kettle is heated to 200°C, and the fraction of 41-44°C collected from the top of the tower at a reflux ratio of 2. The finally obtained high-purity cyclopentadiene monomer inc...

Embodiment 2

[0049] A kind of preparation method of hydrogenated styrene-modified dicyclopentadiene petroleum resin of the present embodiment, its step is:

[0050] Step 1, mixing of reaction raw materials:

[0051] Mix high-purity cyclopentadiene monomer, styrene-based monomer and inert solvent to form a mixed solution. The mass parts of the three components in the mixed solution are respectively: 46 parts of inert solvent, 46 parts of high-purity cyclopentadiene 45 parts of monomers, 18 parts of styrene monomers. The high-purity cyclopentadiene monomer in this example is based on the commercially available C9 industrial product as a raw material, which is added to an atmospheric rectification column with a theoretical plate number of 15, and the application number is CN200510025319 prepared by the process in the Chinese patent. The finally obtained high-purity cyclopentadiene monomer includes the following components in mass percentage: 99.2% cyclopentadiene, 0.71% dicyclopentadiene, a...

Embodiment 3

[0059] A kind of preparation method of hydrogenated styrene-modified dicyclopentadiene petroleum resin of the present embodiment, its step is:

[0060] Step 1, mixing of reaction raw materials:

[0061] Mix high-purity cyclopentadiene monomer, styrene-based monomer and inert solvent to form a mixed solution. The mass parts of the three components in the mixed solution are: 60 parts of inert solvent, 60 parts of high-purity cyclopentadiene 40 parts of monomers, 30 parts of styrene monomers. The high-purity cyclopentadiene monomer in this example is based on the commercially available C10 industrial product as raw material, which is added to an atmospheric rectification column with a theoretical plate number of 15, and the application number is CN200510025319 prepared by the process in the Chinese patent. The finally obtained high-purity cyclopentadiene monomer includes the following components in mass percentage: 99.2% cyclopentadiene, 0.76% dicyclopentadiene, and 0.04% other...

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Abstract

The invention discloses hydrogenated styrene-modified dicyclopentadiene petroleum resin and a preparation method thereof, and belongs to the technical field of petrochemical engineering. The hydrogenated styrene-modified dicyclopentadiene petroleum resin disclosed by the invention has a softening point of 90-130 DEG C, a Gardner chromaticity of 0-1, a weight-average molecular weight of 400-1000 and a molecular weight distribution index of 1.5-2.5. A method for preparing the hydrogenated styrene-modified dicyclopentadiene petroleum resin disclosed by the invention comprises the following steps: reaction raw material mixing, reaction raw material thermal polymerization reaction, purification and hydrogenation reaction. According to the method disclosed by the invention, a high-purity cyclopentadiene monomer and a styrene monomer are used as raw materials and mixed, and the various process parameters of the thermal polymerization reaction are strictly controlled by adjusting the proportion of the various components, thus the occurrence of cross-linking during the thermal polymerization process can be prevented, and favourable conditions are provided for the subsequent hydrogenation reaction, so that the performances of solubility, chromaticity, stability and the like of the hydrogenated resin are remarkably improved.

Description

technical field [0001] The invention belongs to the technical field of petrochemical industry, and more specifically relates to a hydrogenated styrene-modified dicyclopentadiene petroleum resin and a preparation method thereof. Background technique [0002] Petroleum resin is a kind of thermoplastic resin polymerized from C5 and C9 fractions produced in the cracking process of ethylene as the main raw material. Among them, dicyclopentadiene petroleum resin is a resin made of dicyclopentadiene in the carbon five fraction as the main raw material. It has the advantages of cheap and easy-to-obtain raw materials, high softening point, strong rigidity, and high brightness, so it is widely used in Rubber mixing, ink additives, paint coatings and adhesives, etc., but its use is limited due to its shortcomings such as deep hue, poor adhesion, and poor compatibility with elastomer materials. scope. Therefore, the modification of dicyclopentadiene petroleum resin has become the focu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F240/00C08F8/04
Inventor 郭书成张元张素芳陈洁张泽
Owner 安徽同心新材料科技有限公司
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