A high weather resistance PBT/ASA wire for 3D printing and its preparation method
A 3D printing, high weather resistance technology, applied in the direction of additive processing, etc., can solve the problems that are not suitable for 3D printing process, not mentioned, etc., to achieve the effect of reducing damage, improving stability, and strongly scattering ultraviolet rays
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Embodiment 1
[0055] 1. A high weather resistance PBT / ASA wire for 3D printing, characterized in that:
[0056] (1) formula according to weight percentage:
[0057] PBT 70
[0058] ASA 20
[0059] ABS-g-MAH 7.5
[0060]Lanthanum stearate 0.5
[0061] UV-P 0.2
[0062] Nano-TiO 2 1.3
[0063] 1076 / 168 0.3
[0064] White oil 0.2
[0065] (2) Preparation method:
[0066] A. PBT and ASA are vacuum-dried respectively;
[0067] B. According to the weight percentage formula, weigh the dried PBT, ASA, ABS-g-MAH, lanthanum stearate, UV-P, nano-TiO 2 , 1076 / 168, white oil;
[0068] C. Place the weighed components in a high-speed kneader, keep the speed at 3000 rpm / min, and stir at high speed for 30 minutes;
[0069] D. Mix uniformly PBT, ASA, ABS-g-MAH, lanthanum stearate, UV-P, nano-TiO 2 , 1076 / 168, and white oil are added to the feeding port of the twin-screw extruder. The temperature in zone 245°C, the temperature in zone 6 is 235°C, the temperature in zone 7 is 235°C, the temperat...
Embodiment 2
[0075] 1. A high weather resistance PBT / ASA wire for 3D printing according to the present invention, characterized in that:
[0076] (1) formula according to weight percentage:
[0077] PBT80
[0078] ASA 12
[0079] ABS-g-GMA 4.4
[0080] Isooctyl tin dimethyl dimercaptoacetate 0.2
[0081] UV-327 0.1
[0082] Nano ZnO 3
[0083] 1010 / 168 0.2
[0084] White oil 0.1
[0085] (2) Preparation method:
[0086] A. PBT and ASA are vacuum-dried respectively;
[0087] B. According to the weight percentage formula, weigh the dried PBT, ASA, ABS-g-GMA, isooctyltin dimethyl dimercaptoacetate, UV-327, nano ZnO, 1010 / 168, white oil;
[0088] C. Place the weighed components in a high-speed kneader, keep the speed at 4000 rpm / min, and stir at high speed for 25 minutes;
[0089] D. Add uniformly mixed PBT, ASA, ABS-g-GMA, isooctyl tin dimethyldithioglycolate, UV-327, nano-ZnO, 1010 / 168, and white oil to the feed port of the twin-screw extruder, The parameters of the twin-screw ext...
Embodiment 3
[0095] 1. A high weather resistance PBT / ASA wire for 3D printing according to the present invention, characterized in that:
[0096] (1) formula according to weight percentage:
[0097] PBT60
[0098] ASA 32
[0099] SAG 7
[0100] Isooctyl tin dimethyl dimercaptoacetate 0.3
[0101] UV-770 0.2
[0102] Nano MgO 0.2
[0103] 1076 / 168 0.2
[0104] White oil 0.1
[0105] (2) Preparation method:
[0106] A. PBT and ASA are vacuum-dried respectively;
[0107] B. According to the weight percentage formula, take the dried PBT, ASA, SAG, isooctyl tin dimethyl dimercaptoacetate, UV-770, MgO, 1076 / 168, white oil;
[0108] C. Place the weighed components in a high-speed kneader, keep the speed at 2500 rpm / min, and stir at high speed for 40 minutes;
[0109] D. Add uniformly mixed PBT, ASA, SAG, isooctyl tin dimethyldithioglycolate, UV-770, MgO, 1076 / 168, and white oil to the feeding port of the twin-screw extruder, and the twin-screw extruder The parameters are: zone 1 temper...
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