Stable electroluminescent red luminescent material and its prepared organic electroluminescent device
A technology for electroluminescent devices and organic light-emitting devices, which can be applied in the fields of light-emitting materials, electro-solid devices, organic chemistry, etc., and can solve the problems that light-emitting metal iridium complexes cannot reach deep red.
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Embodiment 1
[0074] Embodiment 1: the synthesis of compound A7
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[0076] Two: synthesis process:
[0077] STEP1:; Synthesis of Intermediate C
[0078] 1: See Table 1 for feed ratio
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[0080] 2: Experimental steps:
[0081] 1: Weigh 10 grams of 2-amino-5-bromoacetophenone into a 250mL round bottom flask, add 7.7 grams of 2,3-dihydrochromen-4-one and 20 grams of trimethylchlorosilane, Finally, measure 100 mL of DMF in the flask with a graduated cylinder, N 2 Warm up to 100°C under protection and stir overnight.
[0082] 2: stop the reaction and cool down to room temperature, a large amount of brown precipitate is produced, vacuum filtration to obtain a solid, then pour the solid into distilled water and stir for 30min, vacuum filtration, ethanol washing to obtain the final product, put into an oven and dry to obtain 12 grams of product, yield = 80%, purity 99.19%.
[0083] STEP2: Synthesis of Intermediate D
[0084] 1: Feed Ratio Table 2
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[0086] ...
Embodiment 2
[0108] Embodiment 2: According to the synthesis principle similar to Example 1, other compounds listed in the following table are obtained and are characterized in the following table 5:
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Embodiment 3
[0112] Embodiment 3. OLED device application example:
[0113] Device structure see attached figure 1As shown, 107 is a conductive lead cathode (cathode), 106 is an EIL electron injection layer, 105 is an EIL electron transport layer, and 104 is an EML light-emitting layer; 103 is a HIL hole transport layer; 102 is a HIL hole injection layer; 101 is ITO substrate anode (anode);
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