993 results about "Alkyl substitution" patented technology

The invention belongs to the technical field of OLEDs, and provides a polycyclic compound containing triphenyl silicon and a polyalkyl substituent group and an organic electroluminescent device containing the polycyclic compound. The structural general formula of the polycyclic compound is as shown in formula I in the specification. Benzofuran with higher electronegativity is introduced to a ring structure composed of nitrogen atoms and boron atoms, triphenyl silicon is introduced to the para-position of boron, and the synergistic effect of benzofuran and triphenyl silicon can significantly enhance the multiple resonance of a light-emitting core and reduce vibration relaxation. Due to simultaneous use of the benzofuran and the triphenyl silicon, the problems of vibration relaxation increase, spectrum widening and the like caused by introduction of the polyalkyl substituent are remarkably improved, the luminous efficiency of the material is remarkably improved, and the color purity is improved, so that the requirement of BT.2020 wide color gamut display standard on a luminescent spectrum is met. I

The invention relates to a compound, a composition, an organic optoelectronic device, and a display device. The compound is represented by Chemical Formula 1, where X1 and X2 are each independently NRa, O, S, Se, or Te, any one of R1 to R10 is a group represented by Chemical Formula A, the remaining ones of R1 to R10 and Ra are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heterocyclic group, a substituted or unsubstituted amine group, a substituted or unsubstituted silyl group, a cyano group, or a halogen, and R1 to R10 and Ra are each independently present, or adjacent two of R1 to R10 and Ra are linked to form a ring.

The invention relates to the technical field of chemical synthesis, and particularly discloses an alpha methyl beta phosphonate compound and a synthesis method thereof.The alpha methyl beta phosphonate compound is obtained by directly oxidizing the alpha position of aryl ketone into carbon positive and combining the carbon positive with diethyl phosphite anions under the alkaline condition by using hydrogen peroxide and iodine as oxidizing agents. The alpha methyl substituted beta phosphate ester compound can be generated by a one-step method. The method is suitable for synthesizing compounds of phosphoric acid (methyl, ethyl, propyl and the like) with different alkyl substitutes (methyl, ethyl, propyl and the like) at carbonyl alpha positions. According to the method, the alpha-methyl substituted beta phosphate compound can be synthesized only by using commercial cheap and easily available aryl ketone as a raw material, using hydrogen peroxide and iodine as oxidants and using diethyl hypophosphite as a phosphine source, and reacting in the DMSO solvent at 100 DEG C for 12 hours, so that the target product can be obtained, and the yield is excellent. Compared with previously reported methods, the method does not need low-temperature operation, is simple to operate, adopts a one-pot method, does not need a metal catalyst, and all raw materials are common bulk chemicals.

The invention relates to the technical field of adsorption materials, and discloses a post-modified imine-COF adsorbent and a preparation method and application thereof, the adsorbent comprises the following structural units: a COF skeleton, which is a two-dimensional or three-dimensional porous skeleton formed by an aromatic aldehyde monomer and an amino monomer through a Schiff base reaction; the imine group is formed in a COF skeleton through a post-modification reaction, and the imine group is-C = NR, r is selected from one or more of a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted heterocyclic group and a hydrogen atom. The adsorbent retains excellent structural characteristics of the COF material, realizes high density and uniform distribution of functional groups, and avoids interference of functional monomers on crystal nucleation and growth, so that the adsorption performance of the adsorbent is improved, and the adsorbent can efficiently capture rare earth when being applied to a rare earth-containing solution.

The invention relates to a compound of formula (I) wherein X is selected from the group consisting of-O-(CH2) n-wherein n is 0 to 4, R1 and R2 are independently selected from the group consisting of C11-C25 alkyl groups, SP is a spacer, in particular selected from the group consisting of saturated C4-C8 alkyl groups, unsaturated C4-C8 alkyl groups and substituted or unsubstituted C6 aromatic compounds, in particular substituted C6 aromatic compounds are alkyl substituted C6 aromatic compounds, Y is a heteroatom, n is 0 to 4, and R1 and R2 are independently selected from the group consisting of C11-C25 alkyl groups, SP is a spacer, in particular selected from the group consisting of saturated C4-C8 alkyl groups, unsaturated C4-C8 alkyl groups, and substituted or unsubstituted C6 aromatic compounds, in particular substituted C6 aromatic compounds are alkyl substituted C6 aromatic compounds. L is a peptide synthesis linker, in particular selected from the group consisting of-O-and-NH-, L is a peptide synthesis linker, and m is 0 or 1, in particular m is 1.

The invention relates to the technical field of organic electroluminescent devices, in particular to an organic metal iridium complex, a preparation method of the organic metal iridium complex, a luminescent material and an organic electroluminescent device. The organic metal iridium complex is selected from a compound shown in the following structural formula: # imgabs0 #, wherein R1 to R14 are respectively and independently selected from any one of hydrogen, deuterium, tritium, halogen, cyano, trimethyl silicon, trimethyl germanium, substituted or unsubstituted C1-C10 alkyl, substituted or unsubstituted C3-C8 cycloalkyl, substituted or unsubstituted C6-C20 aryl and substituted or unsubstituted 4-membered to 8-membered heterocyclic radical; the number of R10 on a benzene ring of dibenzofuran in the formula 1 is 1 or 2; s1 is selected from substituted or unsubstituted dibenzofuran, and S1 is fused with any position on a benzene ring of adjacent dibenzofuran. The organic metal iridium complex is low in synthesis cost, simple in synthesis process and difficult to purify, and an organic electroluminescent device formed by the organic metal iridium complex is high in luminous efficiency, long in service life and low in driving voltage.

The invention discloses a synthesis method of 2, 4, 5-trifluorophenylacetic acid, which comprises the following steps: by taking cheap and easily available o-chloronitrobenzene as a raw material, reacting with sodium nitrate in a sulfuric acid and trifluoroacetic acid system, separating generated 2, 4-dinitrochlorobenzene through melt crystallization, and continuing to synthesize 2, 4-dinitrochlorobenzene in methyl chloroacetate to obtain 2, 4, 5-trifluorophenylacetic acid. The method comprises the following steps: carrying out indirect aromatic nucleophilic substitution reaction on 2, 4-dinitrophenylacetic acid under the condition of sodium hydride to generate 5-chloro-2, 4-dinitrophenylacetic acid methyl ester, separating, carrying out fluorination reaction on the 5-chloro-2, 4-dinitrophenylacetic acid methyl ester and potassium fluoride under the action of a phase transfer catalyst, carrying out rectification separation to obtain 2, 4, 5-trifluorophenylacetic acid, and carrying out hydrolytic acidification on the 2, 4, 5-trifluorophenylacetic acid in a sodium hydroxide aqueous solution to obtain 2, 4, 5-trifluorophenylacetic acid. And the process route is safer, more environment-friendly, more efficient and lower in cost.

This invention belongs to the field of veterinary drug technology, specifically relating to a 2,3-disubstituted naphthoquinone compound, its uses, and a preparation method. The 2,3-disubstituted naphthoquinone compound has the general formula: where X is selected from C, NH, O, and S; where X is selected from C, the X-R1 substituent represents an aryl substituent; when X is selected from NH, R1 is selected from hydrogen atom, C1-6 alkyl, C3-6 cycloalkyl, substituted aryl, substituted benzyl, or substituted acyl; when X is selected from O, R1 is selected from hydrogen atom, C1-6 alkyl, C3-6 cycloalkyl, C4-6 cycloalkyl, C5-6 cycloalkyl, C6-6 cyclo ... 3-6 cycloalkyl, substituted benzyl, substituted acyl; when X is selected from S, R1 is selected from C1-6 alkyl, substituted aryl, substituted benzyl; R2 is selected from C1-16 alkyl, substituted aryl, Ra-(CH2)n-, Ra-CO-(CH2)n-; This series of compounds has novel structures, excellent antiparasitic activity, and has been successfully applied in the field of veterinary drugs, solving long-standing safety and toxicity problems; its synthesis process is simple, the conditions are mild, and it can efficiently prepare a variety of 2,3-disubstituted naphthoquinone compounds.

The present application belongs to the technical field of flame-retardant materials, and specifically relates to a halogen-free flame retardant containing a Schiff base structure, a preparation method thereof, and application of the halogen-free flame retardant in epoxy resin. The halogen-free flame retardant containing phosphorus, nitrogen elements and a Schiff base structure is obtained through a Schiff base reaction between an intermediate and 1,3-bis(3-aminopropyl)-1,1,3,3-tetramethyldisiloxane, wherein the intermediate is prepared through a nucleophilic substitution reaction between an aldehyde group-containing phenolic compound and an acyl chloride compound. The flame retardant has good thermal stability, significantly improved char yield, excellent flame-retardant effect, and significantly improved mechanical properties due to the combination of the Schiff base structure and phosphorus and silicon elements. The halogen-free flame retardant is further used to modify epoxy resin to prepare a flame-retardant epoxy resin, which can significantly improve the char performance and mechanical properties of the epoxy resin with little influence on the thermal performance of the epoxy resin cured product, and has excellent flame-retardant efficiency.

The invention belongs to the field of flame-retardant composite materials, and particularly relates to a multifunctional flame retardant and application thereof in epoxy resin. The method comprises the following steps: firstly, carrying out nucleophilic substitution reaction on tert-butyldimethylsilyl chloride and syringaldehyde to obtain a primary intermediate product; carrying out condensation reaction on the primary intermediate product and an amino-containing compound to form a secondary intermediate product with a Schiff base structure; and finally, carrying out addition reaction on the secondary intermediate product and a specific phosphorus-containing reagent to successfully prepare the target flame retardant. Researches show that the flame retardant is remarkable in efficiency, can effectively improve the limit oxygen index (LOI value) and the vertical combustion test (such as UL-94) grade of a material after being applied to an epoxy resin system, and endows the composite material with excellent light transmission, anti-dripping performance and good ultraviolet shielding characteristic.

The invention provides a light conversion adhesive film composition, a light conversion adhesive film and a photovoltaic module. The light conversion adhesive film composition comprises the following components in parts by weight: 100 parts of matrix resin, 0.01-10 parts of an organic polymer light conversion agent and 0.01-10 parts of an auxiliary agent, the organic polymer light conversion agent is formed by copolymerization of a light conversion agent monomer shown in a formula I and a silane coupling agent containing a carbon-carbon double bond, # imgabs0, R1 is substituted or non-substituted C2-C30 alkyl, and R1 at least comprises a terminal carbon-carbon double bond; r < 2 > and R < 3 > are respectively and independently selected from any one of substituted or non-substituted alkyl of C1 to C30, substituted or non-substituted alkoxy of C1 to C30, substituted or non-substituted aryl of C6 to C30, substituted or non-substituted heteroaryl of C4 to C30, amido, carboxyl and hydroxyl; according to the technical scheme, the problems that a preparation method of the high-stability light conversion agent is complex in preparation process and high in cost are solved.

The invention relates to the technical field of chemical synthesis, and discloses a preparation method of anhydrous N, N-dimethyl amino sulfuryl fluoride, which comprises the following steps: (1) introducing sulfuryl fluoride gas into a dimethylamine organic solution to carry out nucleophilic substitution reaction, and then adding triethylamine to obtain a mixed solution containing N, N-dimethyl amino sulfuryl fluoride; and (2) sequentially carrying out normal-pressure rectification and reduced-pressure rectification on the mixed solution containing the N, N-dimethyl amino sulfonyl fluoride to obtain the N, N-dimethyl amino sulfonyl fluoride. According to the method, water is not introduced in the whole process, the risk of water residue is avoided, and the prepared product is high in yield and purity.

The invention discloses a tubular continuous flow preparation process and a tubular continuous flow preparation device for (R)-(+)-2-(4-hydroxyphenoxy) propionic acid. A hydroquinone aqueous solution and a sodium hydroxide solution are respectively preheated and mixed, and then enter a tubular reactor I for reaction to obtain a hydroquinone sodium alkaline solution. And pumping (S)-(-)-2-methyl chloropropionate into a reaction system, respectively preheating the (S)-(-)-2-methyl chloropropionate and the hydroquinone sodium alkaline solution obtained in the previous step, mixing the (S)-(-)-2-methyl chloropropionate and the hydroquinone sodium alkaline solution, carrying out nucleophilic substitution reaction in a tubular reactor II, and carrying out post-treatment on the reaction completion solution to obtain the high-purity (R)-(+)-2-(4-hydroxyphenoxy) propionic acid. According to the method, an optimization method combining a tubular reaction technology and kinetic research is adopted, and MATLAB simulation and experimental verification are combined, so that the reaction yield reaches 95% or above, and the purity reaches 99% or above; the method is high in reaction controllability, fully continuous in reaction process, convenient to operate, low in cost and suitable for industrial production, and the use amount of hydroquinone is greatly reduced.

The invention relates to a novel organic electroluminescent material, which ingeniously combines deuterated modification and alkyl substitution through the elaborate design of the molecular structure, and realizes the synergistic improvement of various excellent properties. By introducing deuterium, the chemical stability and thermal stability of the material and a doped material are improved, the luminous efficiency and stability of a device are further greatly improved, and energy loss caused by vibration relaxation can be reduced by performing deuteration on phenyl on a 9, 9-diphenylfluorene unit, so that the efficiency of the device is improved. Alkyl substitution can optimize the energy level structure of the material and promote carrier injection and transmission, thereby improving the current efficiency of the device.

The invention relates to the technical field of organic dyes, in particular to a novel xanthene dye for blue photoresist color paste and a synthesis method of the novel xanthene dye. The invention relates to a synthesis method of a novel xanthene dye for blue photoresist color paste, which comprises the following steps: 1) taking rigid cyclic amine as a nucleophilic reagent, and carrying out aromatic nucleophilic substitution reaction on a chlorinated xanthene compound to obtain a xanthene intermediate; 2) performing chlorination reaction on the xanthene intermediate by using a chlorination reagent to obtain a chlorinated xanthene intermediate; 3) mixing active amine and the chlorinated xanthene intermediate, and performing substitution reaction under the action of alkali to obtain the novel xanthene dye for the blue photoresist color paste.The novel xanthene dye for the blue photoresist color paste.The novel xanthene dye for the blue photoresist color paste.The novel xanthene dye for the blue photoresist color paste.The novel xanthene dye for the blue photoresist color paste has the advantages of being high in solubility, good in thermal stability and high in contrast ratio.

The invention discloses a conjugated polymer photocatalyst, a preparation method thereof and application of the conjugated polymer photocatalyst in photocatalytic synthesis of nitric acid, and belongs to the technical field of polymer materials and photocatalysis. The preparation method of the catalyst mainly comprises the following steps: synthesizing an intermediate 2CzTPN-Br through a nucleophilic substitution reaction, then synthesizing an intermediate TBBA through an esterification reaction, and finally copolymerizing the intermediate 2CzTPN-Br and the intermediate TBBA through a coupling polymerization reaction to obtain the target catalyst. The preparation method disclosed by the invention is controllable in process, and the obtained catalyst does not need to participate in noble metal and has wide light absorption, high specific surface area and excellent carrier separation efficiency; when being applied to photocatalytic synthesis of nitric acid, nitrogen in air can be directly and efficiently converted into nitric acid under the mild conditions of room temperature, air atmosphere and water serving as a solvent, excellent durability is shown, the yield of nitric acid can reach 4466.2 mol g <-1 > cat after 324-hour continuous illumination, and wide application prospects are achieved in the field of green synthesis.

A compound, and a preparation method therefor and the use thereof. The compound has a structure as represented by formula (I). In formula (I), R1 is selected from H and a substituted or unsubstituted C1-C6 alkyl; R2, R3, R4 and R5 are each independently selected from H, a substituted or unsubstituted C1-C6 alkyl and a substituted or unsubstituted C6-C12 aryl; R6 is selected from a substituted or unsubstituted C1-C4 alkylene; and M is selected from H or an alkali metal. The compound can be used as a viscosity reducer applied to thickened oil exploitation, and has the effects of strong high-temperature resistance and a good viscosity reduction effect.

The invention discloses a synthesis method of 5-bromoindole-2-carboxylic acid methyl ester, and the synthesis route comprises the following steps: S1, taking 2-iodo-4-broronitrobenzene and dimethyl malonate as raw materials, and under the catalysis of a solid sulfonic acid resin catalyst, carrying out nucleophilic substitution reaction to prepare 2-(5-bromo-2-nitrophenyl) dimethyl malonate; s2, taking the dimethyl 2-(5-bromo-2-nitrophenyl) malonate prepared in the step S1 as a raw material, taking a ZSM-5 molecular sieve loaded with cobalt acetate as a catalyst, and introducing hydrogen for reduction reaction to prepare a 5-bromoindole-2-carboxylic acid methyl ester crude product; and S3, carrying out recrystallization on the 5-bromoindole-2-carboxylic acid methyl ester crude product prepared in the step S3 by using ethanol, so as to prepare a 5-bromoindole-2-carboxylic acid methyl ester pure product. The synthesis yield is relatively high, the environmental protection property is relatively good, and the prepared 5-bromoindole-2-carboxylic acid methyl ester is relatively excellent in quality and relatively low in cost.

The invention discloses a nano titanium dioxide composite resin material and a preparation method thereof, and belongs to the technical field of composite materials. The material is composed of an epoxy resin material, nano titanium dioxide, a dispersing agent, a coupling agent, rubber powder, calcium carbonate, a specific structure stabilizer and a curing agent, the stabilizer comprises aromatic rings and alkyl / deuterated alkyl substituent groups, interface bonding force is enhanced through pi-pi accumulation, hydrogen bonds and a dynamic stabilization effect, agglomeration of nano particles is inhibited, and the stability of the material is improved. The thermal stability and the ultraviolet aging resistance of the material are synergistically improved. The preparation method comprises the following steps: pretreating the raw materials, modifying the surface of the nano titanium dioxide through a coupling agent, uniformly dispersing all the components by adopting shear emulsification and vacuum stirring, and performing staged curing molding. By optimizing the component synergistic effect and process parameters, the mechanical strength, impact resistance and weather resistance of the material are remarkably improved, the curing efficiency is high, the process stability is high, and the method is suitable for large-scale production.

The invention discloses a synthesis method of helicid, and relates to the technical field of compound synthesis, glucose is taken as an initial raw material, allose is obtained through a series of reactions, pentaacetyl allose is prepared from allose through acetylation reaction, tetraacetyl alloside is prepared through selective deacetylation reaction, substitution reaction and nucleophilic substitution reaction, and the helicid is synthesized through a one-step method. And finally, carrying out a deacetylation reaction on the tetraacetyl alloside to prepare helicid. Helicid has the effects of calming, sleeping, easing pain and resisting inflammation, and can be applied to preparation of medicaments with corresponding effects. The preparation method of the helicid provided by the invention is simple to operate, can be used for large-scale industrial production, and overcomes the defect of insufficient yield of naturally extracted helicid.

The invention discloses imprinted resin, a preparation method thereof and application of the imprinted resin in platinum recovery. The preparation method of the imprinted resin comprises the following steps: S1, carrying out nucleophilic substitution reaction on chloromethyl polystyrene resin and N-(2-mercaptoethyl) acrylamide in a solvent, and collecting the resin after the reaction is finished; s2, adding a chloroplatinic acid solution into the resin obtained in the step S1, and carrying out a coordination reaction; s3, adding a cross-linking agent and an initiator into the system obtained in the step S2, carrying out polymerization reaction, and collecting resin after the reaction is finished; and S4, adding an eluent into the resin obtained in the step S3, and desorbing chloroplatinic acid radical ions to obtain the imprinted resin. The imprinted resin provided by the invention has high selectivity, high adsorption capacity and good regeneration performance on chloroplatinic acid radical ions, and is suitable for efficient recovery and resource utilization of platinum.

The application provides a preparation method of finerenone and intermediates thereof. The application discloses a preparation method of a finerenone intermediate 5, which comprises the following steps: step 1: in an organic solvent, a resolution reaction is carried out between a finerenone intermediate 2 and D-tartaric acid diphenyl ester to obtain a resolution salt, then an acid-base reaction is carried out between the resolution salt and a base to obtain the finerenone intermediate 3; step 2: in an organic solvent, a nucleophilic substitution reaction is carried out between the finerenone intermediate 3 and triethyl orthoformate in the presence of an acid to obtain a finerenone intermediate 4; step 3: in a solvent, a hydrolysis reaction is carried out between the finerenone intermediate 4 to obtain the finerenone intermediate 5. The preparation method has the advantages of short reaction steps, high total reaction yield, simple and safe operation, simple post-treatment steps, high product purity, low production cost and suitability for industrial production.

The present invention provides a high dielectric constant, low modulus, room temperature self-healing dielectric elastomer, comprising the following components: a hydroxyl-terminated polysiloxane, an organic compound containing a disulfide bond, and a silane coupling agent; the hydroxyl-terminated polysiloxane has the following structural formula I: wherein R1 and R2 are independently selected from C 1‑12 Alkyl, C 6‑24 Aryl, C 6‑24 Aryl-substituted C 1‑12 Alkyl, at least one C 1‑12 Alkyl substituted C 6‑24 Aryl; R3 and R4 are independently selected from C 1‑12 Alkyl; each R5 is the same or different and is independently selected from C 0‑12 Alkylene; n is any integer between 4 and 100. The present invention discloses a high-dielectric-constant, low-modulus, room-temperature self-healing dielectric elastomer and a method for preparing the same. The resulting dielectric elastomer has a high dielectric constant, room-temperature self-healing properties, and a low modulus. The preparation method is simple, requires no catalyst or solvent, and is easily controllable, low-cost, and readily industrially scalable. The elastomer is suitable for use in various fields, including artificial muscles, sensors, supercapacitors, polymer generators, and tactile feedback devices.

Provided is a compound represented by formula (1). In formula (1), R1 and R2 each independently represent an (un)substituted C1-C20 alkyl group, an (un)substituted cycloalkyl group in which the number of ring-forming carbon atoms is 3-20, an (un)substituted C1-C20 heteroalkyl group, an (un)substituted C7-C30 aralkyl group, an (un)substituted C6-C30 aryl group, an (un)substituted C3-C30 heteroaryl group, or a combination of these, and X represents an oxygen atom or a sulfur atom.

A borate compound-containing composition soluble in hydrocarbon solvents. A composition containing base A, or a compound having a total carbon number of not less than 8 and represented by the formula (5):wherein R and R′ are each independently an optionally substituted C1-30 alkyl group, an optionally substituted C3-15 cycloalkyl group, or an optionally substituted C6-14 aryl group; anda borate compound represented by the following formula (1):wherein R1, R2, R3 and R4 are each independently a C6-14 aryl group substituted by one or more fluorine atoms or fluoro C1-4 alkyl groups; and[A-H]+ is a base A-derived cation. A method for producing a polymer, by polymerizing at least one kind of monomer selected from the group consisting of olefins and dienes by using the composition A as a cocatalyst.

The invention relates to the field of polymer functional membrane materials, and particularly provides a composite sulfonated polyarylene ether nitrile sulfone proton exchange membrane and a preparation method thereof. Sulfonated poly (arylene ether nitrile sulfone) is synthesized through nucleophilic substitution reaction, and the sulfonated poly (arylene ether nitrile sulfone) and sulfonated cobalt phthalocyanine are subjected to blending and casting to form a membrane, so that the provided composite sulfonated poly (arylene ether nitrile sulfone) proton exchange resin contains a sulfonic acid structural unit, a sulfone structural unit, a polar cyano group and a phthalocyanine structural unit; the problem that an existing proton exchange membrane is low in sulfonation degree and proton conductivity can be solved, and the proton exchange membrane has the advantages of being high in structural stability, good in mechanical property, excellent in thermal stability and high in safety. The introduction of sulfonated cobalt phthalocyanine can effectively improve the internal structure of the sulfonated polyarylene ether nitrile sulfone proton exchange membrane, promote the conduction rate of water molecules in the membrane, and further improve the proton conductivity of the sulfonated polyarylene ether nitrile sulfone proton exchange membrane. In addition, the manufacturing process is green and simple, the compounding cost is low, and the application prospect is very wide.

The invention discloses a silicon spiro compound as well as a preparation method and application thereof. The silicon spiro compound has the following structural formula, the X group and the Y group are respectively and independently selected from any one of an oxygen atom, a carbonyl group, a sulfinyl group, a sulfuryl group, a substituted or unsubstituted C1-C6 alkylene group, a substituted or unsubstituted C2-C10 alkenyl group, a substituted or unsubstituted C2-C10 alkynyl group, a substituted or unsubstituted C2-C10 cyano group and an aryl group; the silicon spiro compound provided by the invention is suitable for being used as an additive of a lithium ion battery electrolyte, the stability and cycle life of a lithium ion battery can be obviously improved, the reaction condition is mild, and the product purity and yield are high.

The application discloses a preparation method of perfluoroalkyl aryl sulfide, and a structural formula of the perfluoroalkyl aryl sulfide is shown as formula (I); the method comprises the following steps: firstly, obtaining corresponding aryl sulphenyl chloride by chlorination of thiophenol; under the condition that fluoride and crown ether exist, obtaining perfluoro-1,1-dimethylbutyl negative ion by addition of D-2 ‑ And the aryl sulphenyl chloride added is subjected to a nucleophilic substitution reaction to synthesize a product (1,1,1,3,3,4,4,5,5,5-decafluoro-2-trifluoromethylpent-2-yl)(aryl)sulfide. The application adopts a reaction strategy of efficient coupling of thiophenol and perfluoroalkyl, and can be used for preparing various fluorine-containing benzene sulfide compounds.

The invention provides a battery monomer, a power utilization device, a binder and a preparation method of the binder. Each battery monomer comprises a positive pole piece, a negative pole piece and a diaphragm arranged between the positive pole piece and the negative pole piece; the diaphragm comprises a base membrane and a surface coating located on at least one side of the base membrane, the surface coating comprises a binder, and the binder comprises a first polymer; the first polymer comprises a structural unit derived from a first monomer and a structural unit derived from a second monomer, the general formula of the first monomer comprises a structure as shown in a formula I, R1 and R2 independently comprise hydrogen atoms and substituted or unsubstituted alkyl containing 1-3 carbon atoms, substituent groups comprise one or more of carboxyl, amido and hydroxyl, and the structural unit of the first monomer comprises one or more of hydrogen atoms, substituted or unsubstituted alkyl containing 1-3 carbon atoms. The general formula of the second monomer comprises a structure as shown in a formula II, and R3 and R4 respectively and independently comprise a single bond and substituted or unsubstituted alkyl containing 1-10 carbon atoms.

The invention relates to a resin composition, a prepreg, a circuit substrate and a printed circuit board. The resin composition at least comprises: (1) functionalized modified polyphenyl ether resin; (2) hydrocarbon resin, wherein the Vicat softening point of the hydrocarbon resin is 80 DEG C to 240 DEG C; the structural formula of the silicon-nitrogen resin is shown in the formula (1), n is a natural number ranging from 10 to 200, R1, R2, R3, R4 and R5 are independently selected from-H,-OH, amino, C1-C6 alkyl, C1-C6 alkenyl, C6-C12 aryl, C1-C6 alkyl substituted C6-C12 aryl, acrylate or C1-C6 alkyl substituted acrylate, and a molecular chain of the silicon-nitrogen resin at least comprises Si-H groups and Si-vinyl groups. The circuit substrate prepared from the resin composition has high peel strength, high modulus strength, excellent electrical properties and high heat resistance, and has a wide application prospect.