Preparation method of lithium ion phosphate power battery cathode plate

A lithium iron phosphate, power battery technology, applied in battery electrodes, secondary batteries, circuits, etc., can solve the problems of reducing the gram capacity of positive active materials, increasing battery production costs, and high NMP costs, reducing surface energy, improving The effect of powder drop phenomenon and low treatment cost

Inactive Publication Date: 2016-06-29
HUBEI YUNENG POWER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, during the coating process, a large amount of gas containing NMP is discharged into the air, polluting the environment, and at the same time, the cost of NMP is high, which increases the production cost of the battery
Therefore, the formulation of the water-based system can avoid environmental pollution and reduce production costs and has been widely used. However, since the positive electrode sheet made of LA series water-based adhesives such as LA132 in the water-based system is relatively hard, it is very easy to process in the cutting process. There is a phenomenon of powder falling, and the gram capacity of the positive active material is also lower than that of the oily system

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Mix 10% ethanol, 10% N-methylpyrrolidone and 80% ethylene carbonate to make an additive by weight percentage; (2) Add the binder (LA132) for preparing the positive electrode material to the solvent (3) Add conductive carbon black, additives and lithium iron phosphate respectively to the solution prepared in step (2), and stir evenly at high speed to obtain positive electrode slurry, wherein the proportion of additives to solvent 5% by weight;

[0023] 4) Coating the slurry prepared in step (3) on the positive electrode current collector to form a positive electrode material layer;

[0024] 5) Coating a coating layer to improve the safety of the positive electrode sheet on the positive electrode material layer, and then drying, rolling, and slitting to make the lithium ion battery positive electrode sheet.

[0025] The lithium iron phosphate lithium ion battery positive plate produced in this embodiment is assembled with the negative electrode plate, diaphragm, elec...

Embodiment 2

[0027] (1) Mix 5% ethanol, 10% N-methylpyrrolidone and 85% ethylene carbonate to make an additive by weight percentage; body) into the solvent and stirred to fully dissolve to form a solution; (3) Add conductive graphite, additives and lithium iron phosphate to the solution prepared in step (2), and stir at a high speed to obtain a positive electrode slurry, in which the additive Accounting for the proportion of solvent is 3% by weight percentage;

[0028] 4) Coating the slurry prepared in step (3) on the positive electrode current collector to form a positive electrode material layer;

[0029] 5) Coating a coating layer to improve the safety of the positive electrode sheet on the positive electrode material layer, and then drying, rolling, and slitting to make the lithium ion battery positive electrode sheet.

[0030] The lithium iron phosphate lithium ion battery positive plate produced in this embodiment is assembled with the negative electrode plate, diaphragm, electrolyt...

Embodiment 3

[0032] (1) Mix 20% ethanol, 30% N-methylpyrrolidone and 50% ethylene carbonate to make an additive by weight percentage; (2) Add the binder (LA135) for preparing the positive electrode material to the solvent (3) Add conductive graphite, additives and lithium iron phosphate respectively to the solution prepared in step (2), and stir evenly at a high speed to obtain positive electrode slurry, wherein the proportion of additives in the solvent is as follows: The weight percentage is counted as 20%;

[0033] 4) Coating the slurry prepared in step (3) on the positive electrode current collector to form a positive electrode material layer;

[0034] 5) Coating a coating layer to improve the safety of the positive electrode sheet on the positive electrode material layer, and then drying, rolling, and slitting to make the lithium ion battery positive electrode sheet.

[0035] The lithium iron phosphate lithium ion battery positive plate produced in this embodiment is assembled with t...

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PUM

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Abstract

The invention provides a preparation method of a lithium ion phosphate power battery cathode plate. The method comprises the following steps: (1) adding an adhesive for preparing a cathode material to a solvent, and stirring and fully dissolving the adhesive to prepare a solution; (2) adding a conductive agent, an additive and lithium ion phosphate to the solution prepared in the step (1) respectively, and stirring the conductive agent, the additive and the lithium ion phosphate evenly at a high speed to prepare cathode slurry; (3) coating a cathode current collector with the slurry prepared in the step (2) to form a cathode material layer; and (4) coating the cathode material layer with a coating layer for improving the safety of the cathode plate, and carrying out drying, rolling and slitting to prepare the lithium-ion battery cathode plate. The additive is prepared from the following raw materials in percentage by weight: 1%-20% of ethanol, 10%-30% of N-methylpyrrolidone and 50%-85% of ethylene carbonate. The preparation method can obviously improve dusting of the lithium ion phosphate cathode plate and improves gram volume development of the lithium iron phosphate; the cost is low; and the operation is simple and easy.

Description

technical field [0001] The invention relates to the technical field of lithium batteries, in particular to a method for preparing a positive electrode sheet of a lithium iron phosphate power battery. Background technique [0002] At present, with the rapid development of portable electronic devices such as mobile phones, digital cameras, and notebook computers, the market demand for high-power, high-energy-density batteries is increasing. Lithium-ion battery is the battery with the highest voltage and the largest energy density among the batteries that have been practical so far, and has a good development prospect. [0003] Lithium iron phosphate battery is a new type of lithium ion battery that has attracted widespread attention in recent years. Because lithium iron phosphate (LiFePO4) material has high specific energy, long cycle life, stable structure, good safety performance, and low cost, it has high quality as a power battery. High specific energy, low unit price / lif...

Claims

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Application Information

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IPC IPC(8): H01M4/58H01M4/139H01M10/0525H01M4/62
CPCH01M4/139H01M4/5825H01M4/62H01M4/621H01M10/0525Y02E60/10
Inventor 肖琼李连烘王先友
Owner HUBEI YUNENG POWER CO LTD
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