An in-situ and ex-situ coupling detoxification method for CD in heavily polluted sites based on biogas residues
A heavy pollution, site technology, applied in the restoration of polluted soil and other directions, can solve the problems of secondary pollution, high cost, high energy consumption, etc., to achieve the effect of strong natural tolerance, lasting and effective fixation, and cost reduction
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Embodiment 1
[0017] (1) Mix sodium sulfate, biogas residue or carbon source solution according to a certain ratio, so that the dry biogas residue content of the mixed solution is 0.1-5%, the solid content is 0.5-5%, the organic carbon content is 0.5-5%, and the sulfate (in SO4 record) / organic carbon mass ratio is 0.7: 1, and the solution reaction after mixing is 2 days, obtains Cd soil remediation agent;
[0018] (2) Excavate 10m of soil on the surface of the Cd-containing site, then lay a geomembrane with mesh at the bottom of the excavated site, and lay anti-seepage materials around the excavated site to build a semi-closed storage yard;
[0019] (3) The soil in step (2) is crushed to below 5mm, then mixed with the medicament described in step (1), the mixing ratio is that the mass ratio of Cd-containing soil to medicament is 1:0.5, and then placed in step (2) Closed storage in the semi-enclosed yard;
[0020] (4) During the stockpiling period, keep the soil moisture content in the rang...
Embodiment 2
[0022] (1) Mix sodium sulfate, biogas residue or carbon source solution according to a certain ratio, so that the dry biogas residue content of the mixed solution is 5-15%, the solid content is 5-15%, the organic carbon content is 5-15%, and the sulfate (in SO4 record) / organic carbon mass ratio is 0.5: 1, and the solution reaction after mixing is 1 day, obtains Cd soil remediation agent;
[0023] (2) Excavate the 5m soil of the surface layer of the Cd-containing site, then lay a geomembrane with mesh at the bottom of the excavated site, and lay anti-seepage materials around the excavated site to build a semi-closed storage yard;
[0024] (3) The soil in step (2) is crushed to below 5mm, then mixed with the agent described in step (1), the mixing ratio is that the mass ratio of Cd-containing soil to agent is 1:0.5, and then placed in step (2) Closed storage in the semi-enclosed yard;
[0025] (4) During the stockpiling period, keep the soil water content in the range of 5-60% ...
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