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Carbonization straw/kieselguhr molecular sieve manganese-removing filtering material doped with nanometer hydroxy manganese oxide

A technology of manganese oxyhydroxide and carbonized straw, which is applied in the direction of filtration separation, membrane filter, filtration treatment, etc., can solve the problems of not being suitable for large-scale use, effective adsorption capacity, and changing the system, so as to achieve high catalytic adsorption rate and reduce production Cost, the effect of fast maturation process

Inactive Publication Date: 2016-10-26
ANHUI UNIVERSITY OF ARCHITECTURE
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Problems solved by technology

The article "Research on the Adsorption and Removal of Manganese Ions in Water by Nano Molecular Sieve and Diatomite" explores the use of nano molecular sieve and diatomite as filter materials to achieve a relatively ideal manganese removal effect, but its removal effect is greatly affected by the pH value of the system , will also change the pH value of the system, a large amount of use will cause the pH of drinking water to not meet the standard, and its adsorption capacity is effective, so it is not suitable for large-scale use

Method used

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Embodiment Construction

[0013] The filter material of this embodiment is made from the raw material of following parts by weight: straw 12, diatomite 55, 1mol / L manganese sulfate solution 12, 1mol / L potassium permanganate solution 0.4, cerium oxide 0.01, mass fraction of 30% hydrogen peroxide solution 6, sodium hydroxide 45, sodium aluminate 1.5, an appropriate amount of deionized water, and an appropriate amount of ammonia solution with a pH value of 8.

[0014] The preparation method is:

[0015] (1) The straw is cleaned, dehydrated, dried and pulverized, and the treated material is carbonized at 350°C to obtain carbonized straw powder for later use;

[0016] (2) Roast the diatomite at 500°C for 2.5 hours, take it out and cool it, then put it into a sulfuric acid solution with a concentration of 2mol / L, mix and react at 80°C for 8 hours, filter, wash with water, and dry after the reaction is completed. Obtain purified diatomite powder for subsequent use;

[0017] (3) Take 4.5 parts by weight of s...

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Abstract

The invention discloses a carbonization straw / kieselguhr molecular sieve manganese-removing filtering material doped with nanometer hydroxy manganese oxide. Straw and kieselguhr are taken as base stock of the filtering material, so that the production cost is lowered; the nanometer hydroxy manganese oxide loaded and modified with rare earth cerium oxide is mixed with the base stock, so that the nanometer molecular sieve structural filtering material with high specific surface area and high adsorption capacity is prepared; compared with the traditional manganese oxide, the nanometer hydroxy manganese oxide contained in the filtering material has the advantages of higher activity, quicker maturation process and higher catalyzed sorption rate; long-lasting active filtering membrane can be quickly formed; the filtering material is reusable, does not pollute water and especially is fit for the treatment of drinking water with slight manganese exceeding the standard.

Description

technical field [0001] The invention relates to the technical field of water treatment materials, in particular to a carbonized straw / diatomite molecular sieve manganese removal filter material mixed with nano manganese hydroxide oxide. Background technique [0002] At present, most cities in my country have or gradually use reservoirs and lakes as the main source of urban water supply. Therefore, reservoirs and lakes play an important role in water source cities. Reservoirs and lakes are closely related to human life and production. The source of water and production water, lake water also plays a significant role in regulating the natural environment. However, in summer, with the occurrence of reservoir stratification events and hypoxia at the bottom of the reservoir, manganese in the pore water migrates to the overlying lake water, redox The boundary layer moves up into the reservoir, causing a large amount of manganese in the sediment to be released to the overlying water ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/30B01D39/06C02F1/28C02F1/00
CPCB01D39/06B01D2239/10B01J20/06B01J20/14B01J20/18B01J20/20B01J2220/42B01J2220/4806C02F1/001C02F1/281C02F1/283C02F1/288C02F2101/206
Inventor 黄显怀唐玉朝
Owner ANHUI UNIVERSITY OF ARCHITECTURE
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