Processing technique of liquid carbon dioxide by decarbonizing and resolving synthetic ammonia

Abstract

The invention discloses a processing technique of liquid carbon dioxide by decarbonizing and resolving synthetic ammonia, relating to the technical field of synthetic ammonia production and processing. The technique comprises the following steps: desulfurization, drying and dewatering, condensation, purification, dealkylation and rectification purification. According to the technique disclosed by the invention, the liquid carbon dioxide recovery integrates the characteristics of carbon dioxide low-pressure deep freezing and rectification; and a medium-pressure process is utilized to produce the liquid carbon dioxide and separate the impurities with lower boiling point than the carbon dioxide, and impurities which have higher boiling point than the carbon dioxide and can not be separated by rectification are specifically removed. The synthetic ammonia PSA decarbonization CO2-containing bleed air is recovered to prepare the high-purity liquid industrial-grade carbon dioxide and liquid food-grade carbon dioxide, thereby reducing the emission of greenhouse gases, enhancing the productivity of industrial gases of the local area, greatly lowering the energy consumption and cost of the synthetic ammonia product, and enhancing the economic benefits of the enterprises and the environmental protection of the local area.

Description

technical field [0001] The invention relates to the technical field of synthetic ammonia production and processing, in particular to a processing technology for decarburization and analysis of liquid carbon dioxide in synthetic ammonia. Background technique [0002] The raw material gas purification and decarbonization of ammonia synthesis enterprises all adopt pressure swing adsorption (PSA) decarbonization technology, and the decarbonized gas contains about 86% CO 2 The gas is directly vented, which has a certain impact on the environment. Although carbon dioxide is the chief culprit of the atmospheric greenhouse effect that warms the earth's climate, liquid carbon dioxide has a wide range of uses in fields such as machinery manufacturing, beverages, food, and oil field flooding. Tens of millions of tons of carbon dioxide for industrial use. At present, the total amount of liquid carbon in the country does not exceed 3 million tons per year, and the oil industry needs li...

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